Organic chemistry 2 synthesis problems

• [PDF File]EXAM #3 EXTRA PROBLEMS - MIT OpenCourseWare

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  Dr. Kimberly L. Berkowski Organic Chemistry II EXAM #3 EXTRA PROBLEMS What to expect on Exam #3: 1. ~1 Labeling experiment 2. ~2 Mechanisms 3. ~2 Syntheses 4. ~5 transformations – supply missing product 5. ~5 transformations – supply missing reagents 6. ~3 General questions KEY

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• [PDF File]Undergraduate Organic Synthesis Guide

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  Undergraduate Organic Synthesis vs. “Real” Organic Synthesis The synthesis problems you encounter in undergraduate organic chemistry are usually different from those tackled by academic research groups. First of all, Chem 30 problems are designed to test your knowledge of the course material.

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• [PDF File]Review of Organic Chem II - Minnesota State University ...

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  Organic Chemistry II Review Jasperse Some Fundamental Stability/Reactivity Principles 3 2. Product Stability/Reactivity: The more stable the product, the more favorable its formation will be.In terms of rates, this means that the more stable the product, the faster the reaction.

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• [PDF File]ORGANIC CHEMISTRY I – PRACTICE EXERCISE Alkene reactions ...

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  ORGANIC CHEMISTRY I – PRACTICE EXERCISE Alkene reactions and mechanisms ... Provide the reagents necessary to convert 3-methyl-2-butanol to 2-methyl-2-butanol. The synthesis may involve more than one step. 31) Both (E)- and (Z)-hex-3-ene are subjected to a hydroboration-oxidation sequence. How are the

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• [PDF File]EXAM 4 EXTRA PROBLEMS - MIT OpenCourseWare

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  EXAM 4 EXTRA PROBLEMS 1. Provide the best mechanism for the following reaction. Br _ OH/H 2 O O O_ Figure by MIT OCW. 2. A useful diketone, dimedone, can be prepared in high yield by the synthesis below. Provide structures for the intermediate A and for dimedone, and show a mechanism for each step up to B. O O EtO OEt Me O Me + NaOH EtOH EtOH A ...

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• [PDF File]Chemistry 3720 Benzene Synthesis Problems

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  1 Chemistry 3720 Spectroscopy Problems 1. (10 pts) An unknown organic compound has the molecular formula C5H12O, in the mass spectrum, M+ = 88.09. Given the following 1H and 13C data, give the structure of the unknown and assign all of the 1H and 13C signals. 4 3 2 1 0 PPM

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• [PDF File]Some Organic Synthesis Practice Problems: Starting from 1 ...

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  Some Organic Synthesis Practice Problems: Starting from 1-hexene, 1-butyne, bromoethane, iodomethane and any reagent needed (you do not need to use all of these compounds), synthesize: 1. ClCl CHCl3, KOH Li, NH3 H3CCCCH2CH3 HCCCH2CH3 NaNH2, NH3, CH3I 2. H O 1) BH3 2) NaOH, H2O2 H2O H3CH2CH2CH2CCCH Br Br NaNH2 Br2 3. octane H3CH2CH2CH2CCCCH2CH3

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• [PDF File]Organic Chemistry II

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  H 2 and Raney nickel can convert a thioacetal or cyclic thioacetal to yield hydrocarbons 1.7 The Addition of Primary and Secondary Amines Imines have a carbon-nitrogen double bond An aldehyde or ketone can react with a primary amine to form an imine 3 Imine ormationF

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• [PDF File]Chemistry 432 – Lecture Notes

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  Chemistry 432 – Lecture Notes Updated: Spring 2016 Course Organization: Things You Need to Know 1. Named Reactions and Reagents 2. Vocabulary 3. Concepts 4. HOW TO DO SYNTHESIS Nucleophiles and Electrophiles: The Basis of Organic Chemistry

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• Multi-step Organic Synthesis

  Lecture Supplement: Multi-step Organic Synthesis 11 Ph hydroboration Ph H O oxidation Ph OH PCC 1. BH 3 2. H 2O 2, NaOH Or: Ph Ph H O Ph OH PCC 1. BH 3 2. H 2O 2, NaOH Sample Problem #2 Ph CH 3S OCH 2CH 3 from Ph HO Can the target molecule be made from the starting material in one reaction?

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