ࡱ> GJFY :bjbj:&:& 0DXLbXLb-FFFFFZZZZLZt$R!$6uFFF.oooFFooooSD!mwoD0to>%v>%o>%Fooot>%B : AP Chem Unit 4: Intermolecular Forces (Tro Chapters 9-12) Key Concepts and Definitions Types of bonds, valence e-, ionic Lewis models, lattice E, covalent bonding, bond strength, bond length, electronegativity and covalent bonds, dipole moment, % ionic character, resonance, resonance structures, resonance hybrid, formal charge, exceptions to Lewis model, using FC to determine stability, bond E (breaking +, forming -), VSEPR, e- group, electron geo. vs molecular geo., effect of lone pairs on geo., bond angles, polarity, hybridization, molecular orbital theory, solid, liquid, gas, intermolecular forces (dispersion/dipole-diploe/H-bonding/ion-dipole), vapor pressure, dynamic equilibrium, volatile v. nonvolatile, boiling pt, normal boiling pt, soln, solute, solvent, entropy, miscibility, soln equil., saturate/unsaturated/supersaturated, soln conc, dilute/concentrated Be able to Determine/Calculate/Know FC=#val e- - (#nonbond e- + # bond e-) Hrxn=(H all bonds broken) + (H all bonds formed) Polarity of molecular shape IMF v. surface tension/viscosity/capillary action(cohesion/adhesion)/boiling pt/solubility Rate of evap v. temp/surface area/IMF Change in phase v. endo/exo H Heating curves Soln formation v endo/exo H Like dissolves like, Hsoln = Hsolute + Hsolvent + Hmix Hhydration (it s in the book, you read about it) Solubility v. temp/ Molarity/mol fraction/mol % Problems Ch 9 RQ #3, 6, 11-15, 19-22, 26-28, 31-39, 43-45, 48-60, 63-65, 72, 75, 78, 82, 85-87, 91, 98-99, 114, 119 pg 418 - 423 Ch 10 RQ #3-9, 15-17, 27, 30, 33-35, 43-44, 47-48, 51, 67, 77, 80, 87-92, 109-111 pg 474-480 Ch 11 RQ #10, 15-19, 22-32, 49, 54, 60-62, 67, 72, 79-80, 84, 94 pg 535-539 Ch 12 RQ #5, 7, 10-14, 26, 29, 33, 35, 43, 46, 48, 61a, 134-135 pg 588-594 AP Chem Unit 1: General Chemistry (Tro Chapters 1 5) Key Concepts and Definitions Physical change vs. Chemical change sigfigs accuracy vs. precsision error subatomic part. chem. symbols isotope mass # vs. ave. atomic mass ion mol Avogadros # molar mass ionic vs covalent nomenclature percent comp. types of rxn chemical formula/empirical form./molec. form./ structural form. balancing eqns stoich. LR/% Yield/Actual Yield soln molarity electrolyte vs nonelectrolyte solubility ppt rxn molec. eqn/complete ionic eqn/net ionic eqn spectator ion acid-base rxn gas-evol rxn polyprotic acid salt titration equivalence pt indicator redox rxn oxidation vs reduction oxidation state pressure Boyle/Charless/Avogadros/Daltons ideal gas law molar vol. STP vapor pressure kinetic molec. theory mean free path diffusion vs. effusion Grahams Law van der Waals Be able to Determine/Calculate/Know density, K (( C, metric conv., mass #, complete chem. symb, #e-, p+, no, predict ion, ave atom. mass, % abund., molar mass, molar conv, chem. form. (( name, emp. form., molec. form., predict rxn prod., LR, stoich., % yield, M, M1V1=M2V2, solubility, ox. state w/in cmpd, redox rxn, P conv, use gas laws, root mean sq veloc., rate of effusion Problems Ch 1. Review Questions 35-36, 41-60, 68, 73-88 pg 37-40 Ch 2. Review Questions 41-42, 47-48, 51-54, 57-58, 71-86 pg 80-82 Ch 3. Review Questions 23-32, 37-54, 59-62, 65-66, 71-72, 79-84, 87-88, 99-110, 125-126, 131-132 pg 130-135 Ch 4. Review Questions 25-30, 35-44, 49-98, 101-102, 108, 116, 119-120, 136-138 pg 186-192 Ch 5. Review Questions 29-38, 43-46, 48-54, 57-58, 61-62, 65-68, 71-72, 77-78, 81-82, 85-90, 97, 102, 107, 139, 143-145 pg 238-244 AP Chem Unit 2: Thermochemistry (Tro Chapters 6 and 17) Key Concepts and Definitions energy, work, heat, KE, PE, chemical energy, conservation of energy, system, surroundings, units of E, state function, Esys=-Esurr., sign convention for q w and E, identify change in q w and E relative to a system, heat capacity (C), specific heat capacity (Cs), calorimetry, pressure-vol. work, enthalpy (H), endothermic rxn vs. exothermic rxn, intensive properties vs. extensive properties, constant-P calorimetry, Hess s Law, standard heat of formation, enthalpy (H), entropy (S), entropy v. phases, Gibbs free energy (G), spontaneous = -G, effect of H/S, and T on spontaneity, standard state (S/G), Be able to Determine/Calculate/Know KE=mv2'589:KVW7 k l y  ) M k ʾʯththt\PhDPhhCJOJQJaJhCJOJQJaJh ICJOJQJaJhy,CJOJQJaJhpYCJOJQJaJhDYWh&PCJOJQJaJhDYWh&P>*CJOJQJaJhDYWhQ9>*CJOJQJaJhDYWhpCJOJQJaJhZ%CJOJQJaJh1CJOJQJaJhDYWh5CJOJQJaJh3CJOJQJaJhDYWhXYCJOJQJaJ:Wl l Z >@x?567 $`a$gdm$gd`zwm$gdm$gdDYWm$ $`a$gd m$k l  , . B D r  <>lt~>ȼuhh6CJOJQJaJ"hh6CJH*OJQJaJhh6CJOJQJaJhCJH*OJQJaJhCJOJQJaJhCJOJQJaJh ICJOJQJaJhZ%hZ%CJOJQJaJhZ%CJH*OJQJaJhDYWh&P>*CJOJQJaJhZ%CJOJQJaJ">@vx=BEF34567EƷ~rrfZNBh\CJOJQJaJhCJOJQJaJhCJOJQJaJhF|9CJOJQJaJhnCJOJQJaJhDYWhbOCJOJQJaJhDYWh`zwCJOJQJaJh`zwCJOJQJaJh`zwh&PCJOJQJaJh`zwhy,CJOJQJaJh`zwhF|9>*CJOJQJaJhhCJOJQJaJhy,CJOJQJaJhhCJOJQJaJEFGmnNQ#xbdjlrt̼嬟嬼{nnn\J" jhgNh\CJOJQJaJ" jhgNh\CJOJQJaJh\CJH*OJQJaJ" jhc3h\CJOJQJaJ" jhc3h\CJOJQJaJh\5CJOJQJaJhR h\5CJOJQJaJh h\>*CJOJQJaJh\>*CJOJQJaJh1CJOJQJaJh\CJOJQJaJh h\CJOJQJaJ7nIR8,2223$4444 $`a$gdm$gd\m$ $`a$gd\m$ #HIQRV_<E,Lnѓѓѓѓѓфxlx\hDYWh\>*CJOJQJaJh`zwCJOJQJaJh1CJOJQJaJhDYWh\CJOJQJaJh h\CJOJQJaJh h\>*CJOJQJaJhih\CJOJQJaJhkgh\5CJOJQJaJh\CJOJQJaJ"hih\5CJH*OJQJaJhih\5CJOJQJaJ *l0 000$000:0>0L0j0l0t0v0~0000000Ĵp[p[p[p[(hDYWh\B*CJH*OJQJaJph%hDYWh\B*CJOJQJaJphUh h\CJH*OJQJaJh h\CJOJQJaJhDYWh\>*CJOJQJaJhDYWh\5CJOJQJaJh\CJOJQJaJhDYWh\CJH*OJQJaJhDYWh\CJOJQJaJhDYWh\CJH*OJQJaJ#, E=Eprod-Ereact. (E=Efinal-Einitial), E=q+w, q=mCsT, qsoln=msolnCs,solnT, qmet.=-qH2O, mmetalCs,metalTmetal=-mH20Cs,H2OTH2O, w=-PV, H as conv. factor, qsoln=msolnCs,solnT, qrxn=-qsoln, H/n, Hrxn=H1+H2+H3, Hrxn=npHf(prod)-nrHf(react), G=H-TS Srxn=nprodSprod - nreactSreact, Grxn=Hrxn-TSrxn, Grxn=nprodGprod - nreactGreact Problems Ch 6 RQ #8, 10, 11, 12, 14, 15, 21, 23, 25, 33-34, 37-38, 41-42, 45-50, 55-60, 65-66, 75-84, 87-88, 99-100, 113-114, 123, 128, 131, 136, 138 pg 287-293 Ch 17 RQ #6, 13, 16, 27-32, 37-38, 43-44, 49-50, 57-58, 67-68, 79-84, 107-113 pg 852-858 AP Chem Unit 3: Quatum # s and Periodicity (Tro Chapters 7-8) Key Concepts and Definitions electromagnetic radiation, photon, pulse, photoelectric effect, EMS, Bohr model of an atom, Heisenburg uncertainty principle, Coulombic force, 4 quantum numbers, e- config., aufbau Pauli Hund s, Coulomb s Law, shielding, effective nuclear charge, valence e-, periodic trends in atomic radius effective nuc. charge ionization E electronegativity e-affinity Be able to Determine/Calculate/Know E=(hc)/, E=hv, #photons=Epulse/Ephoton, n ! m! ms, Problems Ch 7 Rev Quest #6, 7, 10, 11, 14, 23, 45, 51, 57, 69, 70, 80, 85, 103, 104 pg 329-333 Ch 8 Rev Quest #8, 9, 17, 20, 21, 25, 27, 28, 30, 31, 35, 36, 41, 42, 50, 55, 65, 67, 78, 85, 87-91, 131 pg 374-379 0000000000000000011111D1L1P1X1Z1f1p1v1x1z1|111111111111111111111112쳣hDYWh\CJH*OJQJaJhDYWh\CJH*OJQJaJhDYWh\CJOJQJaJ(hDYWh\B*CJH*OJQJaJph(hDYWh\B*CJH*OJQJaJph%hDYWh\B*CJOJQJaJph7222$2*22262>2H2R2V2d2j2p2x2~222222222222222222 44 4$4444444425N5R5T5V5Ʒ㷫h`zwCJOJQJaJhDYWh`zwCJOJQJaJh1CJOJQJaJhCJOJQJaJhDYWh\CJOJQJaJhDYWh\>*CJOJQJaJh\CJH*OJQJaJh\CJOJQJaJh\B*CJOJQJaJph04V557Z889"99::gd`zwm$ $`a$gd`zwm$ V555X8Z888888999 999 9*999:::ԷԷԷԷԨheCJOJQJaJhk Ah`zwCJOJQJaJh`zwCJH*OJQJaJhDYWh`zw5CJOJQJaJh`zwCJOJQJaJhDYWh`zwCJOJQJaJhDYWh`zw>*CJOJQJaJ.:p&P/ =!"#$%  s 0@ 0@ 0@ 0@ 0@ 0@ 0@ 0@ 0@ 0@ 0@ 0@ 0@ 0@ OJPJQJ_HmH nH sH tH D`D ]ONormalCJ_HaJmH sH tH DA D Default Paragraph FontRiR Table Normal4 l4a (k ( No List LL  Balloon TextCJOJQJ^JaJN/N Balloon Text CharCJOJQJ^JaJPK![Content_Types].xmlN0EH-J@%ǎǢ|ș$زULTB l,3;rØJB+$G]7O٭Vc:E3v@P~Ds |w<v -Dk >E02V5:!74: 8@0(  B S  ?'* %MQRVXZnr  JLUWipCFhm       $ ' 2 5 M Q R U \ ` a d f p J O   ! 0 5 J N q v    ' ) V X _ a    ] _ h j   !%.Crwx   !-0>HJ13NTjmw{ >DGM%'.0;ABJTVbd!#/apbhoua p , 6 >|/333333333'89%& "<=Njz{/>=MR }4gN}aqegS#c3b6*9Q9F|9Ak A$xAO%WordDocument 0DSummaryInformation(6DocumentSummaryInformation8>MsoDataStore@SRD!mSD!mSLSVSG4NUNV==2 @SRD!mSD!mItem <PropertiesJL4QC43WK13==2 @SRD!mSD!mItem  2PropertiesU AAEAAAD/////AQAAAAAAAAAMAgAAAEVDaGVtNFdvcmQuQ29yZSwgVmVyc2lvbj0xLjAuMC4wLCBDdWx0dXJlPW5ldXRyYWwsIFB1YmxpY0tleVRva2VuPW51bGwHAQAAAAABAAAAAAAAAAQgQ2hlbTRXb3JkLkNvcmUuQ29udHJvbFByb3BlcnRpZXMCAAAACw==   F Microsoft Word 97-2003 Document MSWordDocWord.Document.89qCompObjr