ࡱ>  e>bjbj lJ60 0 $P:   >#7 E:G:G:G:G:G:G:<P?G:CCCG:  \:&&&C  E:&CE:&&:+,[, 6I+ 1:r:0: ,R6@gX6@[,[,R6@/ CC&CCCCCG:G:"XCCC:CCCC6@CCCCCCCCC0 P:  CHEM:2210 (4:121) ORGANIC CHEMISTRY I SPRING, 2015 PRIMARY INSTRUCTOR: Prof. Dan Quinn; Office W333 CB;  HYPERLINK "mailto:daniel-quinn@uiowa.edu" daniel-quinn@uiowa.edu; Phone 335-1335 TEAM TEACHER: Dr. Rebecca Laird; Office W315 CB;  HYPERLINK "mailto:rebecca-laird@uiowa.edu" rebecca-laird@uiowa.edu; Phone 335-2717 TEXTBOOK: "Organic Chemistry" 4th Edition, by Janice G. Smith OPTIONAL MATERIALS: A "Student Study Guide/Solutions Manual" for the textbook is also available which contains answers to the problems in the text. LECTURES: TTh 11:00 a.m. to 12:15 p.m. in W290 CB. WEB SITE: Online content for the course will be managed using the ICON (Iowa Courses Online) system (http://icon.uiowa.edu/index.shtml). The site will be used to post copies of the slides used in class, practice exams, exam keys, and occasional announcements. OFFICE HOURS: Quinn, Monday and Wednesday, 1:30 3:00 p.m. Laird, Tuesday and Thursday, 1:30 3:00 p.m. Questions on course material will be answered during review sessions, during office hours, or by appointment. REVIEW SESSIONS: Review sessions will be held before each exam; 4:30 6:30 p.m.; Feb 16, March 23, April 20; W290 CB. EXAM SCHEDULE: Exams dates, times and places are given below. ExamDateTimeLocations1February 188:45-10:15 pmMH Auditorium2March 258:45-10:15 pmMH Auditorium3April 228:45-10:15 pmMH AuditoriumFinalTBATBATBA EXAMINATIONS: Exams are closed-book. Leave textbooks, notes, etc., at home or in the front of the room before the start of the exam. No electronic devices are allowed during exams, including cell phones. There will be three exams of 90 minutes each and a two hour final. EXAMS MUST BE WRITTEN IN INK, BUT NOT RED OR ERASABLE INK. EXAMS ON WHICH WHITE-OUT WAS USED OR WHICH WERE WRITTEN IN PENCIL, RED OR ERASABLE INK WILL NOT BE REGRADED. Exams will be graded and returned through the Chemistry Center (E225 CB) as soon as possible. MAKE-UP EXAMS: Make-up exams will be given under exceptional circumstances only. You must sign up for the make-up and give an acceptable reason before the regular exam is given. Under no circumstances will a make-up be given to take the place of a regular exam taken earlier. Go to the Chemistry Center (E225 CB) to sign up for a makeup exam, or sign up online at  HYPERLINK "https://uiowa.qualtrics.com/SE/?SID=SV_ebbpDYzM8MA4hEN" https://uiowa.qualtrics.com/SE/?SID=SV_ebbpDYzM8MA4hEN. If clicking on the link does not work, copy and paste the link into the address line of our web browser. MAKE-UP EXAM DATES: Make-up exams are 6:30-8:00 p.m. on the following dates. Make-up Exam 1: Friday, February 27, W290 CB Make-up Exam 2: Friday, April 3, W290 CB Make-up Exam 3: Friday, May 1, W290 CB FINAL EXAMINATIONS: No student is required to take more than two examinations in one day. A potential problem may be eased by students closely checking the exam schedule. An undergraduate student who has (a) two examinations scheduled for the same period or (b) more than two examinations scheduled for the same day may schedule an alternate time for the final exam. Contact the instructor no later than March 1, 2015. DEPARTMENTAL HOME: Department of Chemistry DEPARTMENTAL CONTACT INFORMATION: Sarah Larsen, DEO, E331 CB; Lindsay Elliott, Secretary to the Chair, E331 CB, 319-335-0200. REGRADING OF EXAMS: If you feel that a mistake has been made in grading your exam, turn it in at the Chemistry Center (E225 CB) for regrading. Write on the cover the question to be regraded, with a one sentence explanation of what you believe was incorrectly graded. The entire exam will be regraded. Exams for regrading must be turned in within one week of the time they are first returned to you. No regrades after one week. This regrading policy will be strictly enforced. It is the only way that you can get consideration for regrading. COURSE GRADES: The maximum possible score is 430 points, 100 points apiece for each hour exam and 130 points for the final. The grade ranges follow: 95 - 100% A+ 75 - 79% B+ 60 - 64% C+ 45 - 49% D+ 86 - 94% A 70 - 74% B 55 - 59% C 40 - 44% D 80 - 85% A- 65 - 69% B- 50 - 54% C- 35 - 39% D- < 35% F DROP-ADD SLIPS: Drop and add slips will be signed by Ellie Keuter in the Chemistry Center (E225 CB). COURSE INFORMATION: Inquiries about details of the course (e.g. extra copies of the syllabus, exam times and places, times and places of discussion sessions, etc.) should be taken to Ellie Keuter in the Chemistry Center (E225 CB). DROP DATES: If you are an undergraduate student you may, if approved by your advisor, drop a course through the 10th week of the term. Deadline Date: Monday, April 6, 2015. Undergraduates receive a "W" for any course dropped after the 2rd week. Deadline Date: Monday, February 2, 2015. DISCUSSION SESSIONS: Discussion sessions will be conducted by a TA. These sessions provide additional opportunities to ask questions, work on problems, and improve your understanding of the course material. The schedule for the discussion sessions follows: Discussion SectionTimePlaceTA00039:30 am 10:20 am ME203 CBGil Reynders000410:30 am 11:20 am ME203 CBGil Reynders000511:30 am 12:20 pm ME203 CBMadhur Joshi00228:30 am 9:20 am TE203 CBMadhur Joshi003012:30 pm 1:20 pm TE203 CBGil Reynders00312:00 pm 2:50 pm TE203 CBGil Reynders00439:30 am 10:20 am WE203 CBMadhur Joshi00511:30 pm 2:20 pm WE215 CBMadhur Joshi00544:30 pm 5:20 pm WE203 CBNazmul Bhuiyan00712:00 pm 2:50 pm ThE203 CBNazmul Bhuiyan00733:30 pm 4:20 pm ThE203 CBNazmul Bhuiyan00911:30 pm 2:20 pm FE203 CBNazmul Bhuiyan TA OFFICE HOURS Nazmul Bhuiyan: Thursday, 4:30-6:30 pm, Madhur Joshi: Wednesday, 10:30 am-12:30 pm, E208 CB Gil Reynders: Tuesday, 3:30-5:30 pm, E208 CB SUPPLEMENTAL INSTRUCTION SESSIONS CHEM:2210Organic Chemistry ISundays 1-1:50 pm114 BHCFischerMondays 4:30-5:20 pmC139 PCWednesdays 4:30-5:20 pmC129 PC ADMINISTRATIVE HOME The College of Liberal Arts and Sciences is the administrative home of this course and governs matters such as the add/drop deadlines, the second-grade-only option, and other related issues. Different colleges may have different policies. Questions may be addressed to 120 Schaeffer Hall, or see the CLAS Academic Policies Handbook at  HYPERLINK "http://clas.uiowa.edu/students/handbook" http://clas.uiowa.edu/students/handbook. ELECTRONIC COMMUNICATION University policy specifies that students are responsible for all official correspondences sent to their University of Iowa e-mail address (@uiowa.edu). Faculty and students should use this account for correspondences ( HYPERLINK "http://www.uiowa.edu/~our/opmanual/iii/15.htm" \l "152" Operations Manual, III.15.2, k.11). ACCOMMODATIONS FOR DISABILITIES A student seeking academic accommodations should first register with Student Disability Services and then meet with the course instructor privately in the instructor's office to make particular arrangements. See  HYPERLINK "http://sds.studentlife.uiowa.edu/" http://sds.studentlife.uiowa.edu/for more information. ACADEMIC HONESTY All CLAS students or students taking classes offered by CLAS have, in essence, agreed to the College's  HYPERLINK "http://clas.uiowa.edu/students/handbook/academic-fraud-honor-code" Code of Academic Honesty: "I pledge to do my own academic work and to excel to the best of my abilities, upholding the  HYPERLINK "http://thechallenge.uiowa.edu/" IOWA Challenge. I promise not to lie about my academic work, to cheat, or to steal the words or ideas of others; nor will I help fellow students to violate the Code of Academic Honesty." Any student committing academic misconduct is reported to the College and placed on disciplinary probation or may be suspended or expelled ( HYPERLINK "http://clas.uiowa.edu/students/handbook" CLAS Academic Policies Handbook). CLAS FINAL EXAMINATION POLICIES The final examination schedule for each class is announced by the Registrar generally by the fifth week of classes. Final exams are offered only during the official final examination period. No exams of any kind are allowed during the last week of classes. All students should plan on being at the UI through the final examination period. Once the Registrar has announced the date, time, and location of each final exam, the complete schedule will be published on the Registrar's web site and will be shared with instructors and students. It is the student's responsibility to know the date, time, and place of a final exam. MAKING A SUGGESTION OR A COMPLAINT Students with a suggestion or complaint should first visit with the instructor (and the course supervisor), and then with the departmental DEO. Complaints must be made within six months of the incident (CLAS HYPERLINK "http://clas.uiowa.edu/students/handbook"  Academic Policies Handbook). UNDERSTANDING SEXUAL HARASSMENT Sexual harassment subverts the mission of the University and threatens the well-being of students, faculty, and staff. All members of the UI community have a responsibility to uphold this mission and to contribute to a safe environment that enhances learning. Incidents of sexual harassment should be reported immediately. See the UI  HYPERLINK "http://www.sexualharassment.uiowa.edu/" Comprehensive Guide on Sexual Harassment for assistance, definitions, and the full University policy. REACTING SAFELY TO SEVERE WEATHER In severe weather, class members should seek appropriate shelter immediately, leaving the classroom if necessary. The class will continue if possible when the event is over. For more information on Hawk Alert and the siren warning system, visit the  HYPERLINK "http://police.uiowa.edu/stay-informed/emergency-communication/" Department of Public Safety website. COURSE DESCRIPTION: This course is intended for science majors (botany, biology, or microbiology), pre-pharmacy, pre-medical, pre-dental, or pre-veterinary students, or anyone planning to take two years of chemistry. The course is the first half of a yearlong sequence which covers the chemistry of carbon-containing compounds. It begins with a review of atomic structure and covalent bonding, and continues with a sequence of topics based on the concept of functional groups, and specific groupings of atoms which serve as the site of most organic reactions. The structure, stereochemistry, physical properties, reactivity, and synthesis of different compound classes are discussed, with emphasis on alkanes, alkenes, alkynes, aromatic compounds, alkyl halides, and alcohols. Knowledge of reaction mechanisms is stressed to provide unifying principles. Grades are based on three one-hour exams, and a comprehensive final. There are two lectures each week by the professor and a number of discussion sections led by a TA. Because the chemistry of carbon is three-dimensional, students are strongly advised to buy and use a molecular models kit. SUGGESTIONS FOR SUCCESSFUL STUDY IN ORGANIC CHEMISTRY I: Learning Organic Chemistry requires commitment of time and effort on your part. This course will require at least two hours of out-of-class preparation and study for every hour that you spend in class. Reinforce the material that is presented in the lectures by reading the corresponding sections in the book. Work out the in-chapter problems as you go. Test your understanding of the material by working out the problems at the end of each chapter. Work out the problems before you check the answers in the Student Study Guide/Solutions Manual. To help you organize your study, about half of each exam will come from the suggested problems in the Course Outline on the next page. You have a wealth of opportunities to reinforce concepts and solve problems with which you may be having difficulty. Avail yourself of the instructor and TA office hours, attend the lectures and discussion sessions, and bring your questions to the review sessions. These opportunities are offered to help you learn Organic Chemistry. Use them! COURSE OUTLINE Chapter Pages Chapter Title Suggested Problems 1 7-57 Structure and Bonding 1-18, 20-37, 40-83 2 58-85 Acids and Bases 1-15, 17-25, 27-33, 35-42, 44-50, 53-69 3 86-119 Introduction to Organic Molecules and Functional Groups 1-10, 12-35, 37-41, 45-50, 52 4 120-165 Alkanes 1-39, 40 -53, 55-58, 61-70 5 166-204 Stereochemistry 2-13, 15-40, 42-48, 50, 52-63, 65-67 6 205-237 Understanding Organic Reactions 1-29, 31-51, 54, 57 7 238-287 Alkyl Halides and Nucleophilic Substitution 1-46, 48-55, 57-73, 75, 77-81, 85 8 288-323 Alkyl Halides and Elimination Reactions 1-31, 33-44, 46-52, 54-64 9 324-371 Alcohols, Ethers and Epoxides 1-41, 43-58, 60-69, 71-75, 77 10 372-415 Alkenes 1-38, 40, 41, 43-45, 47-61, 63-70 11 416-443 Alkynes 1-26, 28-38, 40-49, 51, 53-61 12 444-482 Oxidation and Reduction 1-7, 9-25, 27-36, 38-44, 46-52, 54, 55, 59-74 15 558-592 Radical Reactions 1-15, 17-37, 39-52, 54-57, 59, 61-66, 68-74     PAGE  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