ࡱ> rtabcdefghijklmnopqZ g i a Sbjbj  xJ\xJ\N 8#8#00111X2X2X2838X2 `?TFFFFP Vq\ z$A1,N\P@,,00FFŽ,0F`1RF,~Q 1@1"F`3v&BXv۽0 V0h1b 0<0bbbbBbbb ,,,,bbbbbbbbb8# F/:  ______________________________________________________________________________________ Visual Arts Safety Plan: Visual Arts Safety Manual Unit Specific Plan ______________________________________________________________________________________ The Pennsylvania State University  TABLE OF CONTENTSPRIVATE  1.0 INTRODUCTION 2.0 RESPONSIBILITIES 2.1 Penn State Leadership 2.2 Senior Vice President for Finance and Business 2.3 Associate Vice President of Office of Physical Plant 2.4 Environmental Health and Safety 2.5 Budget Executives and Budget Administrators 2.6 University Safety Council 2.7 The Institutional Biosafety Committee 2.8 Department Heads, Center Directors, and Other Facility Directors 2.9 Principal Investigators and Supervisors 2.10 The Individual 2.11 Laws and Regulations 2.12 Students 3.0 THE VISUAL ARTS SAFETY PROGRAM 3.1 Visual Arts Safety Plan 3.2 Unit Specific Plan 3.2.1 Initial Preparation 3.2.2 Change of Facility 3.2.3 Addition of or Change to a Specific Project 3.3 Inspections 4.0 UNIVERSITY EMERGENCY INFORMATION 4.1 Where to Find Specific Information 4.2 University Emergency Response Plan 4.3 Building Emergency and Evacuation Plans 4.4 Power Failure 4.5 Incident (Accident) Reporting 4.6 EHS Assistance 4.7 Personal Injury 4.7.1 Burn 4.7.2 Inhalation 4.7.3 Ingestion 4.7.4 Puncture or Cut 4.7.5 Needle stick 5.0 VISUAL ARTS SAFETY MANUAL 6.0 APPENDICIES 6.1 Fact Sheets 6.2 Waste Management Logbook 6.3 Unit specific Plan GENERAL SAFETY PLANPRIVATE  INTRODUCTION The Pennsylvania State University Visual Arts Safety Plan is made up of two sections, the Visual Arts Safety Manual and the Unit Specific section. The Visual Arts Safety Plan provides information and guidance to help you conduct your work safely and in compliance with environmental health and safety regulations and University policy. It is also a useful training resource for principal investigators and other supervisory personnel. The Visual Arts Safety Manual serves as a reference source for a broad range of general safety issues. Your facility's Unit Specific Plan is the portion of the plan that addresses hazards specific to your area. These two sections should provide comprehensive information to address hazards in your area. It is recommended that you also maintain emergency plans; medical surveillance and scheduling information; and fit test reports and training documents; with your Visual Arts Safety Plan. The Visual Arts Safety plan should be made available to all workers and all persons in your area who work with hazardous chemicals. Although the information in this document is compiled from sources believed to be reliable, it is not all-encompassing and is intended only to serve as a starting point for good safety practices. The area manager or supervisor is responsible for adding specific information, for developing and maintaining a safe workplace, and for complying with federal, state, and local laws and University policy. Whenever used, the word shall indicates required procedures. The word should indicates a recommendation for good practice. The requirements for working with Lasers can be found in  HYPERLINK "http://guru.psu.edu/policies/SY17.html" SY-17. This Penn State Safety Policy has specific registration, general training, laser specific training, and self inspection requirements. In addition, the policy requires the issuance and required use of laser specific safety materials. The requirements for working with radiation producing equipment (x-rays) can be found in  HYPERLINK "http://guru.psu.edu/policies/SY15.html" SY-15. This Penn State Safety Policy has specific registration, general training, and device specific training, PRIVATE  EMERGENCY NUMBERS EHS 814-865-6391 FIRE, POLICE, AMBULANCE 911 UNIVERSITY POLICE, UP 814-863-1111  2.0 RESPONSIBILITIESPRIVATE  This section describes and assigns responsibilities associated with safety practices. 2.1 Penn State Leadership The university president endorses the Penn States Environmental Health and Safety Policy  HYPERLINK "http://guru.psu.edu/policies/SY01.html" SY01 requiring that the University leadership maintain a safe work environment within their jurisdiction, by monitoring and exercising control over their assigned areas. 2.2 Senior Vice President for Finance and Business Penn State University Safety policy  HYPERLINK "http://guru.psu.edu/policies/SY01.html" SY01 includes the Presidents statement to the entire PSU leadership of his commitment to the Universitys Environmental Health and Safety Policy. He has delegated administrative responsibility for the safety programs to the Senior Vice President for Finance and Business 2.3 Associate Vice President of Office of Physical Plant The Associate Vice President of the Office of Physical Plant reports to the Senior Vice President for Finance and Business and oversees the activities of EHS. 2.4 Environmental Health and Safety The director of EHS reports to the Associate Vice President of Office of Physical Plant. EHS has overall responsibility for the administration of the Universitys environmental health and safety programs. Our mission is to work with the campus community to develop and implement efficient, comprehensive and pro-active health and safety programs. EHS responsibilities include: Developing safety programs that protect the health and safety of students, faculty, staff, visitors and the environment. Assisting the campus community in complying with federal, state, and local regulations. Providing oversight to ensure conformance with these programs. EHS representatives are authorized to enter University facilities within their jurisdiction at any time to observe working conditions, monitor equipment, and sample for contaminants. EHS is authorized to close a facility or stop a process or procedure that poses an imminent danger to life or property. 2.5 Budget Executives and Budget Administrators (Chancellors, Deans, Associate Deans, Division Heads, etc.): These functions have the primary responsibility to maintain a safe work environment within their jurisdiction, by monitoring and exercising control over their assigned areas. S/He must assign a representative from each academic and administrative unit to the University Safety Council. This representative must be selected to ensure compliance with University safety policies, rules, procedures and practices. This is often the individual designated to act on behalf of the budget executive or budget administrator. S/He must communicate to all faculty, employees and students that health and safety of persons in the workplace and environment are of the highest priority at Penn State University. S/He must ensure that health and safety responsibilities are carried out in the academic departments or administrative units for which they are responsible. S/He must ensure that environmental health and safety obligations established by this program applicable to their areas of jurisdiction are carried out. This includes assuring compliance with applicable state and federal health and safety rules, regulations, standards and procedures. Included, for example, are regulations of the Pennsylvania Department of Environmental Protection (PADEP), and Nuclear Regulatory Commission (NRC), and policies and procedures established by the Office of Environmental Health and Safety. S/He must monitor implementation of programs designed to protect the health and safety of faculty, staff, students and visitors: a. Consult with their University Safety Council representative and/or the Office of Environmental Health and Safety with respect to new, existing or planned facilities or equipment that may present a health or safety hazard to determine specific measures that may need to be implemented to control these hazards before exposure to these hazards may occur. b. Support measures such as training, use of protective devices, and resources to control and prevent hazards. 2.6 University Safety Council The University Safety Council is comprised of members representing academic colleges and administrative units, as appointed by their respective budget executives. University Safety Council representatives are commonly referred to as "Safety Officers." The duties of the University Safety Council are to develop and implement, under the guidance of the Office of Environmental Health and Safety, a comprehensive and practical occupational health and safety program, and to maintain an environment that is conducive to the safety, health and well-being of the University community. Each member of the University Safety Council shall attend the regularly scheduled meetings and special meetings of the University Safety Council, and report Council activities to the appropriate budget executive. S/He must establish and maintain, as chairperson, a Safety Committee within the member's area of responsibility. The size and structure of this Committee shall be dictated by the types of activities, the potential hazards inherent to those activities, and the number of persons who may be exposed. S/He must accompany insurance company loss prevention representatives on inspections of areas under the Safety Officer's jurisdiction. S/He must review all  HYPERLINK "http://guru.psu.edu/forms/4-19Employer%27sReportofOccupationalInjuryorDisease.html" Employer's Reports of Occupational Injury or Illness for employee accidents, or the  HYPERLINK "http://guru.psu.edu/formpublic/8-05IncidentForm.html" Incident Report for non-employees or employees not engaged in normal employment activities, whichever report is appropriate for the accident/illness, and any other associated accident/illness reports. S/He must assist in the investigation of all serious accidents, and all other accidents when requested by the supervisor. S/He must initiate proper follow-up measures and ensure corrective actions are implemented when unsafe conditions, practices or equipment are reported or observed. 2.7 Department Heads, Center Directors, and Other Facility Directors The term department head will be used in this text to include center directors and other facility directors. The Senior Vice President for Finance and Business and the Vice President for Research have assigned direct responsibility for compliance with the University's safety and health programs to department heads. This means that the department head shall provide a safe workplace and shall implement the safety and health programs. This includes ensuring that personnel are adequately trained, and overseeing the preparation and submission of annual safety self-audits. Department heads shall appoint building safety officers and alternates. The department head shall maintain discipline, enforce rules and regulations, and take prompt, effective corrective action when necessary. The department head shall also provide assistance to EHS staff when situations arise involving investigators and other personnel in the department. The department head shall be familiar with and understand the federal, state, and local regulations and University policies applicable to the department's work and shall ensure compliance through principal investigators and other supervisory personnel. Regulatory and policy documents are available on the EHS website,  HYPERLINK "http://www.ehs.psu.edu" www.ehs.psu.edu and from EHS. The department head may delegate safety and health-related tasks to principal investigators or other supervisors, but ultimately compliance is the department head's responsibility 2.9 Principal Investigators and Supervisors The PI or supervisor is responsible to the department head for the safe and legal conduct of work under his or her purview. This responsibility shall not be delegated. The supervisor shall be aware of the physical and health hazards associated with all materials present in their work areas. In the event of an accident, the principal investigator shall initiate appropriate emergency procedures. All supervisors (department chairs, faculty, and other employees with direct oversight of University activities and employees or students) have specific responsibilities to provide for the health and safety of those supervised. They are in a key position in the organizational structure to carry out the department's safety policies and to prevent injuries to their employees. S/He must be thoroughly informed of appropriate University and Departmental safety policies, rules and procedures and how they specifically apply to their responsibilities and authority. S/He must inform all new and current employees and students that safety and health, and concern for the environment, are priorities at Penn State and to inform them about safety and health policies, rules, regulations and procedures, as well as their specific responsibilities (the next Section,  HYPERLINK "http://guru.psu.edu/policies/SY01.html" \l "H" below). S/He must ensure that required safety equipment, devices and personal protective equipment and apparel are provided and maintained, and are properly used by individuals working in their operations. S/He must provide employees and students with instruction and assistance in the proper operation of equipment or materials involved in any operation which may be potentially hazardous. S/He must take prompt corrective action when unsafe conditions, practices or equipment are reported or observed. S/He must encourage prompt reporting of health and safety concerns. S/He must promptly conduct a thorough investigation in all work-related injuries, illnesses and accidents, submit appropriate recommendations on all accident reports, including the  HYPERLINK "http://guru.psu.edu/forms/4-19Employer%27sReportofOccupationalInjuryorDisease.html" Employer's Reports of Occupational Injury or Illness or the  HYPERLINK "http://guru.psu.edu/formpublic/8-05IncidentForm.html" Incident Report , as appropriate, and follow through to ensure corrective measures have been implemented. S/He must coordinate or conduct inspections to maintain safe and healthful conditions, and address any deficiencies that are identified. S/He must provide for health and safety training. S/He must provide financial support for health and safety improvements, or request assistance from the next higher level of supervision regarding these requests. The supervisor shall prepare a Unit Specific Plan and shall make all personnel aware of the plan. The principal investigator shall be familiar with and understand the rules, regulations, and University policies pertaining to the workplace. These encompass but are not limited to the following items: training, record keeping, labeling of chemicals, labeling and proper disposal of surplus and waste chemicals and biological materials, posting of warnings, medical surveillance, inventory reporting, engineering controls, safe work practices, provision of personal protective clothing and equipment, and access restrictions. 2.10 The Individual Each individual working where hazardous materials are used shall know and comply with the University's safety policies and rules and shall follow both oral and written instructions from the principal investigator or supervisor. The individual shall report to the principal investigator any unsafe conditions and any accident or exposure to chemicals or biological agents. If the individual receives no response or an unsatisfactory response, he or she shall contact the department head or EHS. All University employees and students have specific responsibilities to comply with established health and safety policies, standards, rules, procedures and regulations. Compliance with these is essential to create and maintain a healthy and safe environment at all University locations. S/He must comply with applicable environmental health and safety policies, standards, rules, regulations and procedures. These include safety-related signs, posters, warnings and written/oral directions when performing tasks. S/He must not perform any function or operation which is considered hazardous, or is known to be hazardous without proper instructions and authorization. S/He must only use equipment and materials approved or provided by the supervisor or instructor and for which instruction has been provided by this or other experience. S/He must become thoroughly knowledgeable about potential hazards associated with the work area; knowing where information on these hazards is maintained and how to use this information when needed. S/He must wear or use prescribed protective equipment. S/He must report all unsafe conditions, practices, or equipment to the supervisor, instructor or safety officer whenever deficiencies are observed. S/He must inform the supervisor or instructor immediately of all work-related injuries or accidents and obtain prompt medical attention when necessary. S/He must provide information necessary for the supervisor or safety officer to adequately and thoroughly complete the Employer's Report of Occupational Injury and Illness and any other associated accident/illness reports. 2.11 Laws and Regulations Numerous laws and regulations govern work with chemicals and biological materials and the responsibilities of employers and employees. A list of the major regulatory acts follows. FEDERAL LAWS Occupational Safety and Health Act of 1970 (OSHA Act). Contains the general industry regulations. OSHA Hazard Communication Standard. Governs the use of hazardous chemicals in nonlaboratory locations. OSHA Occupational Exposure to Hazardous Chemicals in Laboratories Standard. Governs the use of chemicals in laboratories. In general, the Laboratory Standard adopts the guidelines found in Prudent Practices for Handling Hazardous Chemicals in Laboratories (published by the National Research Council) and incorporates some elements of the Hazard Communication Standard. EPA Superfund Amendments and Reauthorization Act (SARA), Title III: Emergency Preparedness and Community Right-to-Know Act. Establishes responsibilities for chemical reporting to the community. EPA Worker Protection Standard (WPS). Protects farm workers from pesticide exposure. EPA Clean Water Act. Provides for surface water protection and results in many environmental regulations. EPA Spill Prevention, Control, and Countermeasures Rule. Provides requirements for oil storage and spill plans Resource Conservation and Recovery Act of 1976. Governs hazardous waste disposal. Other regulations of the U.S. Environmental Protection Agency. Regulations of the U.S. Department of Transportation. STATE LAW Pennsylvania Community Right to Know Act. Governs the use of hazardous chemicals in non-laboratory locations. Pennsylvania Pesticide Control Act of 1973. Governs the licensing of applicators and the application of pesticides 2.12 Students Although the Pennsylvania laws apply only to employees (including student employees), it is the policy of the Pennsylvania State University to ensure that all students who might be exposed to hazardous materials in the course of their activities at the University are also adequately protected and trained. Students shall receive instruction in the appropriate safety precautions for their specific work areas and will be expected to follow the given rules. 3.0 THE VISUAL ARTS SAFETY PLANPRIVATE  3.1 Visual Arts Safety Plan The Visual Arts Safety Plan is intended to be a central safety resource. The complete Safety Plan includes: Visual Arts Safety Manual Unit Specific Plan Recommended documents included with Plan: Emergency Plans Annual Reviews Respirator Records: Medical Examinations and Fit Test Reports Training Documentation The Plan should be located in the work area preferably in a holder on the back of the rooms entrance door or to either side of the door inside the room. The department-level safety records, including accumulation area locations, self audits, training records and a list of overseers, shall be maintained by the head of each department (or designee) where hazardous materials are used. 3.2 Unit Specific Plan The Unit Specific Plan is the area-specific section of the Visual Arts Safety Plan. See Unit Specific Plan Form in Appendix B. In the case of shared facilities, the director, coordinator, or designated facility supervisor for the center shall compile the Unit Specific Plan. 3.2.1 Initial Preparation If chemical, biological or radioactive materials or reactive processes are used, the principal investigator/supervisor shall prepare a Unit Specific Plan available for review by EHS. The Unit Specific Plan contains the following sections, only sections that are appropriate need be completed. Research Overview Chemical Safety Physical Hazards Safety Precautions in Place Certification Agreement Appendix 3.2.2 Change of Facility A new Unit Specific Plan shall be prepared when new facilities are opened. The original Unit Specific Plan will not be considered valid for the new space. 3.2.3 Addition of or Change to a Specific Project A Unit Specific Plan shall be prepared or modified for new projects not covered by the original Unit Specific Plan. 3.3 Inspections The University has an inspection program for all areas. Self audits are conducted annually by work area personnel. Inspections are also conducted by the EHS staff annually. Investigators may be asked to update the Unit Specific Plan and other information. The inspector may examine general conditions, engineering controls, work practices, chemical storage, use of personal protective clothing and equipment, signs and postings, and records. Workers may be interviewed. Inspection findings are provided to the principal investigator/supervisor, department head and safety officer. 4.0 UNIVERSITY EMERGENCY INFORMATIONPRIVATE  4.1 Where to Find Specific Information This section provides general information about the University's emergency response programs. For detailed emergency notification procedures and other general emergency information, including fire safety, see the EHS website, www.ehs.psu.edu. Call for assistance when needed. Always call the University Police 911 if there is an explosion, fire, injury, or spill-related evacuation. If there is a chemical or biological spill, call EHS, 814-865-6391 during business hours and 863-1111 at University Park at other times. 4.2 University Emergency Response Plan Police Services maintains the University's Emergency Response Plan and an Operation Plan for emergencies. The Emergency Response Plan formalizes responses to all classes of emergencies, from small events to catastrophes. In emergency situations, the role of University Police (UP) is to investigate the situation, provide site security, implement the emergency plan, and establish communications. EHS will advise and assist with hazardous-material spill control and cleanup. When the ability to respond adequately to an emergency is beyond the capability of University personnel, UP will call the local fire department or local hazardous materials response team. Building Emergency and Evacuation Plans In the event of a fire, hazardous material release, or other hazardous situation requiring emergency response the first responder will: Activate the fire alarm, if needed Call 911 Evacuate the zone Assist emergency personnel by providing information regarding location of the incident, origin, and persons involved 4.4 Power Failure In the event of a power failure when there is adequate emergency lighting, cap any open chemical containers and close gas cylinders, perform an orderly shutdown of equipment and processes, and close the fume hood sash. Leave immediately when the area has been secured and can be left unattended. Contact EHS or UP if there is a possibility of an uncontrolled reaction in a process that cannot be shut down. 4.5 Incident (Accident) Reporting All emergency incidents shall be reported to EHS, including spills, fires, or injuries. Incidents shall be investigated. The supervisor shall be responsible for providing a written report of investigation findings and corrective actions to EHS and ensuring that corrective actions to prevent repeat incidents are undertaken. EHS may also prepare an investigation report, as follow-up for the incident. Investigations are made and reports written to learn the cause of the problem and what changes in procedures, equipment, or training should be made to avoid other accidents. 4.6 EHS Assistance EHS will respond to chemical spills. However, if the spilled material is not volatile and there is no immediate fire or toxic hazard, cleanup may be done by area employees (under direction of the principal investigator/supervisor or EHS). In situations involving a fire or toxic hazard, EHS will advise on evacuation or other precautions to protect persons or property in the immediate area. 4.7 Personal Injury 4.7.1. Burn If your clothing catches fire, decide very quickly how to put out the fire and minimize burns. The following methods are in order of preference: 1. Get under a safety shower or other water source if one is immediately at hand. 2. If a safety shower is not immediately available, stop, drop, and roll to extinguish the fire, holding your hands over your face to shield your face and eyes. Assess the condition of the skin's burn area. If skin is not broken, run water over the burn area to remove heat. If skin is broken, apply a dry, sterile dressing over the wound. Seek medical attention as soon as possible. 4.7.2 Inhalation Call 911 to solicit trained emergency medical personnel in the event of an emergency. A person exposed to smoke or fumes shall be removed to uncontaminated air. Any victim overcome by smoke or fumes shall be treated for shock. Give cardiopulmonary resuscitation (CPR) if necessary and if trained personnel are available. If a person needs to be rescued from a contaminated area, evaluate the possibility of harm to the rescuer before anyone enters or remains in the contaminated area without proper protective equipment. The SDS should accompany the victim to the medical treatment facility. 4.7.3 Ingestion If a person ingests a toxic chemical, determine, if possible, what was ingested and notify the emergency medical personnel by calling 911. The SDS should accompany the victim to the medical treatment facility. 4.7.4 Puncture or Cut When treating a victim with a puncture wound or cut, wear personal protective equipment (e.g., gloves) to minimize exposure to human blood, body fluids, or other chemical or biological contamination. Apply a pressure pad or clean cloth firmly to the wound. Raise the wounded area above the level of the heart to slow the bleeding. For severe bleeding or spurting, very firmly press the pressure pad directly on the wound and apply pressure at the applicable body pressure point above the wound to stop the flow of blood. In a severe injury, keep the victim warm, calm, and oriented to prevent shock. Seek medical attention as soon as possible. 4.7.5 Needlestick Needlesticks or other accidents involving skin punctures by a chemical or biological agent shall be reported to the supervisor immediately and EHS as soon as possible. Appropriate medical testing, treatment, and follow-up may be indicated and shall be provided as appropriate. When a needlestick occurs, do not wait to report the incident and obtain medical attention. FIG. 4.1 MEDICAL EMERGENCY PROCEDURES In the event you are injured or exposed to a hazardous substance, follow these procedures to obtain medical care and establish any Workers' Compensation benefits to which you may be entitled. All work-related injuries and illnesses must be reported to your supervisor. Medical services are provided to Penn State University employees at Occupational Medicine, (814) 863-8492, and Mount Nittany Medical Center, (814) 234-6110. PROCEDURES I. Ambulatory victims (able to walk) Inform your supervisor or designated departmental employee of your injury or illness. Proceed to Occupational Medicine or Mount Nittany Medical Center to secure treatment. II. Nonambulatory victims (unconscious or unable to walk) A. Call 911. B. Report the injury, victim's name, and location (building, floor). C. Ask for an ambulance. FIG. 4.2 MEDICAL EMERGENCY PROCEDURES, STUDENTS Students in need of emergency medical assistance should call 911. For other, less severe medical emergencies, call University Health Services, 863-0774 or local health care panel provider. Extreme caution should be taken when determining whether to transport an injured employee to medical care in your personal vehicle. It is better to call for an ambulance if there is any chance complications could arise during transport. PENN STATE  Visual Arts Safety Manual First Edition June 2000 Organized by: Environmental Health and Safetyxe "Environmental Health and Safety" (EHSxe "EHS") PENNSTATE IMPORTANT PHONE NUMBERSxe "PHONE NUMBERS" EMERGENCYxe "EMERGENCY PHONE NUMBERS" 911 (MEDICAL, POLICE, OR FIRE) Policexe "Police" - Non Emergency 3-1111 Safety Information/Assistance Environmental Health and Safetyxe "Environmental Health and Safety" 5-6391 6 Eisenhower Parking Deck College Safety Officerxe "College Safety Officer"xe "Safety Officer" Lisa Faust 5-4727 Dave Will (alternate) 3-5733 Departmental Safety Officexe "Departmental Safety Officer"r Jerry Bierly 5-3962 Office of Physical Plantxe "Physical Plant"xe "Office of Physical Plant" Water leaks, facility problems, etc. 5-4731 TABLE OF CONTENTS  TOC \t "Heading 1,1,Heading 2,2" PREFACE  PAGEREF _Toc490556978 \h 26 INTRODUCTION  PAGEREF _Toc490556979 \h 26 FIVE PRINCIPLES OF SAFETY  PAGEREF _Toc490556980 \h 27 I. GENERAL SAFETY INFORMATION  PAGEREF _Toc490556981 \h 29 EMERGENCIES AND FIRST AID  PAGEREF _Toc490556982 \h 29 CHEMICAL HAZARDS AND SAFETY PROCEDURES  PAGEREF _Toc490556995 \h 35 CHEMICAL WASTE DISPOSAL  PAGEREF _Toc490557003 \h 37 ELECTRICAL HAZARDS AND SAFETY PROCEDURES  PAGEREF _Toc490557010 \h 39 FIRE SAFETY  PAGEREF _Toc490557011 \h 40 SAFETY AND EMERGENCY RELATED REFERENCES  PAGEREF _Toc490557015 \h 43 II. SPECIFIC HAZARDS IN THE SCHOOL OF VISUAL ARTS  PAGEREF _Toc490557016 \h 44 Ceramic Art and Pottery  PAGEREF _Toc490557017 \h 44 Clay  PAGEREF _Toc490557018 \h 44 Glazes  PAGEREF _Toc490557021 \h 46 Kilns  PAGEREF _Toc490557024 \h 49 Special Processes  PAGEREF _Toc490557027 \h 52 Salt Glazing  PAGEREF _Toc490557028 \h 52 Raku Firing  PAGEREF _Toc490557031 \h 53 Leaching of Finished Ceramic Ware  PAGEREF _Toc490557034 \h 53 Lead Leaching  PAGEREF _Toc490557035 \h 53 Other Leachable Metals  PAGEREF _Toc490557036 \h 54 Painting and Drawing Hazards  PAGEREF _Toc490557037 \h 54 Oil Painting  PAGEREF _Toc490557038 \h 54 Basic Oil Painting  PAGEREF _Toc490557039 \h 54 Advanced Oil Painting  PAGEREF _Toc490557040 \h 55 Airbrush, Spray Cans and Spray Guns  PAGEREF _Toc490557043 \h 56 Pigments  PAGEREF _Toc490557046 \h 58 Water-Based Paints  PAGEREF _Toc490557049 \h 60 Drawing  PAGEREF _Toc490557053 \h 61 Dry Drawing Media  PAGEREF _Toc490557054 \h 61 Liquid Drawing Media  PAGEREF _Toc490557057 \h 62 Sculpture Hazards  PAGEREF _Toc490557060 \h 63 Plaster  PAGEREF _Toc490557062 \h 63 Plaster Molds  PAGEREF _Toc490557065 \h 65 Plaster Finishing  PAGEREF _Toc490557068 \h 65 Stones and Lapidary  PAGEREF _Toc490557071 \h 66 Soft Stones  PAGEREF _Toc490557072 \h 66 Hard Stones  PAGEREF _Toc490557073 \h 66 Casting Stones  PAGEREF _Toc490557074 \h 66 Lapidary  PAGEREF _Toc490557077 \h 69 Finishing Stone  PAGEREF _Toc490557080 \h 69 Wax  PAGEREF _Toc490557083 \h 70 Metal Jewelry  PAGEREF _Toc490557086 \h 71 Soldering  PAGEREF _Toc490557087 \h 71 Silver Soldering  PAGEREF _Toc490557088 \h 71 Soft Soldering  PAGEREF _Toc490557091 \h 73 Lost Wax Casting  PAGEREF _Toc490557094 \h 75 Electroplating and Electroforming  PAGEREF _Toc490557097 \h 76 Anodizing  PAGEREF _Toc490557100 \h 78 Surface Working, Polishing and Finishing  PAGEREF _Toc490557103 \h 80 Lithography, Intaglio and Relief Printing Hazards  PAGEREF _Toc490557106 \h 81 Inks  PAGEREF _Toc490557108 \h 81 Pigments  PAGEREF _Toc490557111 \h 82 Solvents  PAGEREF _Toc490557114 \h 83 Acids  PAGEREF _Toc490557117 \h 85 Lithography  PAGEREF _Toc490557120 \h 86 Plate and Stone Preparation  PAGEREF _Toc490557121 \h 86 Printing and Cleanup  PAGEREF _Toc490557124 \h 88 Intaglio  PAGEREF _Toc490557127 \h 89 Etching  PAGEREF _Toc490557128 \h 89 Other Techniques  PAGEREF _Toc490557131 \h 91 Printing and Cleanup  PAGEREF _Toc490557134 \h 91 Relief and Other Printing Processes  PAGEREF _Toc490557137 \h 92 Relief Printing  PAGEREF _Toc490557138 \h 92 Collagraphs  PAGEREF _Toc490557141 \h 93 Plastic Prints  PAGEREF _Toc490557144 \h 94 Monoprints  PAGEREF _Toc490557147 \h 95 Photoprintmaking  PAGEREF _Toc490557148 \h Error! Bookmark not defined. Photolithography  PAGEREF _Toc490557149 \h 95 Photoetching  PAGEREF _Toc490557152 \h 97 Other Photoprintmaking Techniques  PAGEREF _Toc490557155 \h 98 Photographic Processing  PAGEREF _Toc490557158 \h 99 Black-And-White Photographic Processing  PAGEREF _Toc490557159 \h 99 Mixing B&W Photographic Chemicals  PAGEREF _Toc490557160 \h 99 Developing Baths  PAGEREF _Toc490557163 \h 100 Stop Baths and Fixer  PAGEREF _Toc490557166 \h 102 Intensifiers and Reducers  PAGEREF _Toc490557169 \h 103 Toners  PAGEREF _Toc490557172 \h 104 Other Hazards  PAGEREF _Toc490557175 \h 105 Color Processing  PAGEREF _Toc490557178 \h 106 Developing Baths  PAGEREF _Toc490557179 \h 106 Bleaching, Fixing, and Other Steps  PAGEREF _Toc490557182 \h 107  ACKNOWLEDGEMENTS In the preparation of this manual, the authors have reviewed a number of publications devoted to the subject and have had numerous discussions with knowledgeable people in the department and elsewhere. Their value in identifying and providing critical elements for this manuals structure and text has been significant. We would also like to thank the faculty, students, and staff of the School of Visual Arts who have contributed their valuable input. PREFACE Most safety practice is common sense, however, when activities proceed smoothly without accidents we may become complacent and the perceived need for safeguards becomes increasingly remote. The lack of any serious injury may be a result of either good safety or just plain luck. The value of practicing good safety can be most evident when safety is not practiced. This, as well as numerous observations in the studios, is the underlying motivation for putting together this manual. It is often assumed that everyone is born with good common sense and therefore should practice good safety. The problem is that one cannot ask the right questions if one is not aware of the potential hazards. Accidents and exposures do not always result from ignorance of dangers but rather a diminished awareness of dangers within a familiar environment. This manual is intended to sensitize the reader to some of the more common hazards that exist in the Arts. As each person's concerns may be specific to his/her medium, this guide hopes to point the reader in the right direction to obtain an answer to specific questions. There are many excellent sources of information and contacts right on campus, unfortunately they are often not utilized because people are not aware of them. In order to keep this manual up to date and in accordance with the latest findings in safety procedures, all suggestions to improve this manual are welcome and should be directed to the department safety officer. As a final note, remember that safe practice is to our own benefit as well as our colleagues working us. As a first step to setting up any activity, individuals must take a few minutes to think through the potential hazards before proceeding. These may involve chemical, electrical or mechanical dangers. By taking a few minutes to think and ask the right questions we may prevent an unfortunate accident from happening to us, or setting a "booby trap" for our friends. INTRODUCTION Safety in the Arts requires attention and effort. The use of new and/or different techniques, chemicals, and equipment requires careful preparation. Reading, instruction, and supervision may be required, possibly in consultation with other people who have special knowledge or experience. Each individual has a responsibility to learn the health and safety hazards associated with the materials to be used or produced, and with the equipment to be employed. It is important for you to know what is expected of you and what your responsibilities are with regard to safety to yourself, your colleagues and our environment. In addition, there are safety practices and safety equipment with which you must be thoroughly familiar if you are to work safely. This manual should be used as a guide to the general types of hazards and a reference source for more specific information pertinent to each individual project. Pregnant women should be aware of potential hazards to the fetus from many of the chemicals used in these processes, and should avoid exposure to solvents, metal fumes and dusts. The Pennsylvania State University is committed to protecting the health and safety of its employees, students, visitors and the environment. The responsibility for administration of the Universitys health and safety program is assigned to xe "Environmental Health and Safety"EHSxe "EHS". Implementation of this health and safety program is the responsibility of the entire University community staff, faculty and students. To assist EHS in their efforts, the University Safety Council, with members representing the Universitys academic colleges and administrative units, helps to identify safety needs, develop and implement procedures, and provide a safe environment for teaching and research. Everyone plays a role in safety. University Safety Councilxe "Safety Council"xe "University Safety Council" members (aka safety officers) establish safety committees in their units and investigate accidents and unsafe conditions. Budget Executives and Administrators ensure that health and safety responsibilities are carried out in their units. Supervisors are responsible for the health and safety of those they supervise by ensuring the proper use of safety equipment, training of new employees and correcting unsafe conditions, practices or equipment. Employees and students must do their part by complying with safety policies, standards, rules and regulations and by conducting themselves in a safe manner. FIVE PRINCIPLES OF SAFETYxe "PRINCIPLES OF SAFETY" Our Safety Program incorporates only a few principles, but each one is essential. These principles are: 1) practice safetyxe "Safety Practices", 2) be concerned about the safety of others 3) understand and prevent the hazards associated with your particular environment, 4 responding to an emergency, and 5) report hazards or hazardous conditions. Because practicing safety may mean different things to different people, it is the purpose of the safety manual to define a standard for safe work practices. Some basic safety practices must be followed: appropriate eyexe "Eye Safety" protection shall be worn when working with any potential eyexe "Eye Safety" hazards (safety glasses and face shields are available). Hazardous, volatile, and noxious chemicals shall be used only in areas with proper ventilationxe "Ventilation". Each room shall be labeled to identify emergency contacts; (adhesive labels are available through EHSxe "EHS"). All gas cylinders must be secured and all containers must be labeled. Potential hazards shall be reviewed prior to beginning work and appropriate precautions taken. 2) Concern for safetyxe "Safety of Others" must include alerting the people around you in the event of an accident or emergency as well as pointing out unsafe behaviors. This may consist of reminding a friend to wear safety glasses or pulling the fire alarm to evacuate a building. It is your responsibility to alert personnel in the immediate vicinity of a fire or an emergency! Preventionxe "Prevention" is the key to safety. Prior to beginning any project, using a new piece of equipment, or handling materials, it is essential that the potential hazards and safety precautions necessary to perform the work be considered. Hazards may include toxic substances, electrical circuits, mechanical equipment, or waste chemicals. Safety precautions should include correct materials storage, proper ventilationxe "Ventilation", proper grounding of equipment, and training sessions when necessary. Whenever possible, information about the unique hazards and precautions necessary for any type of work should be prepared and made available to everyone working in the studio. Material Safety Data Sheetsxe "Material Safety Data Sheets - Sources"xe "Chemical Information - Material Safety Data Sheets"xe "Material Safety Data Sheets" (MSDSxe "MSDS") and equipment manuals are important sources of information. Prior to starting any work, a MSDS which includes toxicological information and special handling requirements should be reviewed for each chemical to be used. MSDSs are available through a link on the EHSxe "EHS" web page, www.ehs.psu.edu. In addition EHS maintains a file of thousands of MSDSs and is available to assist in obtaining them (5-6391). EHS staff are available to review project safety requirements and any potential hazards with you. You must be prepared to respond quickly and effectively in an emergency. Familiarize yourself with the area you are working in, exits, and associated safety equipment: eyewash stations, showers, sinks, fire extinguishers, and spill kits. Just a few moments spent learning the locations and use of these pieces of equipment prior to an emergency could save a life.xe "Repsonding to an Emergency"xe "Emergency Response" 5) In the event of a fire, large gas leak, or release of toxic fumes, the following procedures should be followed:xe "Reporting Emergencies"xe "Emergency Reporting" Alert personnel in the immediate vicinity. Confine the fire or emergency, if possible. Summon aid (Dial 911). Evacuate the building. Report pertinent information to responding emergency personnel. It is worth commenting on each of these procedures. When alerting personnel in the vicinity of a fire or emergency, assign several of them the responsibility of assisting in the remaining procedures. Especially assign someone the task of summoning aid! Confining fires or other emergencies means taking measures to prevent them from spreading. In case of fire, close doors and windows securely. If it is safe to do so, use an appropriate fire extinguisher. Do not waste valuable time trying to confine an emergency when it is beyond your control. Follow evacuation procedures. Evacuating the building means sounding the fire alarm system and going to the nearest exit without delay. The elevator should never be used during a fire! The Fire Departmentxe "Emergencies - 911 Procedures", the Police Department, and Medical Services can be contacted by dialing 911. When summoning aid, phone from a safe location. You should be prepared to state precisely the location and nature of the emergency. Do not hang up until you have given all of the pertinent information and you are instructed to do so by the dispatcher. University medical response time is within 3 minutes to anywhere on campus. Meet, or designate someone to meet, responding emergency personnel at a specific location and report pertinent information such as, personnel trapped, specific location of incident, hazardous materials or equipment involved. If the emergency involves a medical emergency, nearby personnel must be alerted and aid summoned. Following any emergency, the supervisor, EHSxe "EHS" (5-6391), and the building safety officer must be notified. The remainder of this Safety Manual presents examples of specific hazards that you are likely to encounter and what you should know about them to minimize their danger to you and to others. I. GENERAL SAFETY INFORMATIONxe "SAFETY INFORMATION - GENERAL" EMERGENCIES AND FIRST AIDxe "EMERGENCIES - FIRST AID"xe "FIRST AID" In a medical emergency such as severe bleeding or unconsciousness, summon professional medical attention immediately by dialing 911 from any university phone. Be prepared to describe accurately the nature of the accident. Ambulance services will respond within 3 minutes. Provide first aid within the scope of your training while waiting for professional help to arrive. Report all injuries to your supervisor/advisor. Use of Emergency Equipmentxe "Emergency Equipment" Everyone working in studios must know how to use emergency equipment such as fire extinguishers, spill kits, safety showers, and eyexe "Eye Safety" wash apparatus. Special training is available on the proper use of all types of emergency equipment is available by calling the Environmental Health and Safetyxe "Environmental Health and Safety" office. Know where these items are located in your area. Floor plans of the buildings are provided in this manual with the location of safety equipment labeled. First Aid There are certain serious injuries in which time is so important that treatment must be started immediately. Stoppage of Breathingxe "Breathing - First Aid" For stoppage of breathing from electrical shockxe "Shock - Electric" or asphyxiation, the mouth-to-mouth method of resuscitation is far superior to any other known. If victim is found unconscious on the floor and not breathing, rescue breathing must be started at once, seconds count. Do not waste time look around for help; yell for help while resuscitating victim. Training in the techniques of mouth-to-mouth resuscitation and Cardio-Pulmonary Resuscitation (CPRxe "CPR Training"xe "First Aid - CPR Training") is available through University Health Services and Police Services. Severe Bleedingxe "Bleeding" Severe bleeding can usually be controlled by firm, direct pressure on the wound with a pad or cloth. The cleaner the cloth, the more desirable; however, in an emergency, use part of the clothing. In addition: Wrap the injured to avoid shock, and call immediately for medical attention. Raise the bleeding part higher than the rest of the body and continue to apply direct pressure. Keep victim lying down. Never use a tourniquet. Thermal Burnsxe "Burns - Thermal" If the burn is minor, apply ice or cold water. In case of a clothing fire: The victim should drop to the floor and roll, not run to a safety shower. Keep the water running on the burn for several minutes to remove heat and wash area. Place clean, soaking wet, ice-packed cloths on burned areas, and wrap to avoid shock and exposure. Never use a fire extinguisher on a person with burning clothing. Chemical Burnsxe "Burns - Chemical" For chemical burns or splashes, immediately flush with water. Apply a stream of water while removing any clothing that may have been saturated with the chemical. If the splash is in the eyexe "Eye Safety", flush it gently for at least fifteen minutes with clear water. Wash in a direction away from the other eyexe "Eye Safety". Have aid summoned immediately! If the splash is on the body, flood it with plenty of running water for at least 15 minutes. If the exposure is over a small area, have someone drive you to University Health Services following the first aid treatment for proper medical attention. For large-scale exposures, have someone call the university ambulance (911). An emergency shower, hose or faucet should be used in an emergency. For chemicals spilled over a large area, quickly remove contaminated clothing while using the safety shower; treat as directed under the section thermal burns. Seconds count, therefore, no time should be wasted simply for modesty. If safety goggles are worn during a chemical exposure to the face, leave them on until the surrounding area is thoroughly rinsed, they may be the only thing keeping the chemical out of your eyesxe "Eye Safety". Traumatic Shockxe "Shock - Traumatic" In cases of traumatic shock, or where the nature of the injury is not clear, keep the victim warm, lying down and quiet. Wait until medical assistance arrives before moving the victim. One should treat all injuries as potential shock situations, as they may turn into one. Some common symptoms of shock are cold and clammy skin, paleness, and delirium. SAFETY RULESxe "SAFETY RULES - General Practices" General Practices Working alone is not good practice. An individual is advised to work only under conditions in which appropriate emergency aid is available when needed. In other words, try to work when others are around to provide help if it is needed. If others are working nearby let them know where you will be working so that they can occasionally check on you and you can check on them. Make sure there is a telephone nearby Do not work with powered equipment wearing loose hair, loose clothingxe "Loose Clothing Hazards" or dangling jewelry. Eye Protectionxe "Eye Protection". In all areas where chemicals are used, there is the hazard of splashes or dust particles entering the eyesxe "Eye Safety". Soldering presents hazards from molten solder and debris. These activities, and many others, require the use of safety glasses, chemical goggles or face shields. Most work may simply require the use of safety glasses, however, when any chemicals are being used at least chemical goggles should be used or in some cases a face shield is required. Hearing Protectionxe "Hearing Protection". The healthy ear can detect sounds ranging from 15 to 20,000 hertz. Temporary exposure to high noise levels will produce a temporary hearing lossxe "Hearing Loss". Long term exposure to high noise levels produces permanent hearing lossxe "Hearing Loss". There appears to be no hearing hazard (although possible psychological effects) to noise exposure below 80 dB. Exposure above 90 dB is hazardous and should be avoided. Earmuffsxe "Hearing Protection - Earmuffs" offer the highest noise attenuation, and are preferred for levels above 95 dB. Earplugsxe "Hearing Protection - Earplugs" are more comfortable and are preferred in the 80-95 dB range. If you suspect that a hearing hazard exists then notify EHSxe "EHS" xe "Environmental Health and Safety"to have the sound level measured. "Rule of Thumb"xe "Hearing Protection - \"Rule of Thumb\"" for determining the possible need for hearing protection: A good "rule of thumb" for determining if your work area or activity requires hearing protection is as follows. If you have difficulty hearing or understanding a "normal" tone of voice at a distance of about three feet (arms length), noise levels are probably exceeding safe levels and you should be using hearing protection. See the EHSxe "EHS" Hearing Conservation web page (http://www.ehs.psu.edu/hearing.html) for more information on noise exposure and hearing protection. Respiratory Protectionxe "Respiratory Protection". Use only respirators provided and/or recommended by EHSxe "Respiratory Protection - EHS Assistance" There are many shapes and sizes of respirators and in order to be effective it must be properly fitted. There are also a variety of cartridges available each having a specific application. The cloth respirators available in the stockrooms provide only minimal dust protection and no chemical protection. They should never be used with any toxic material. Respirators may only be used following proper fitting, medical evaluation and instruction by EHS personnel. Clothingxe "Clothing - Safety Precauations". In situations where splashing or spills may occur, it is wise to protect your body with lab coats, goggles or face shields; splash aprons, and gloves for chemicals that are corrosivexe "Corrosives" or easily absorbed through the skinxe "Skin Hazards". Shorts and open-toed shoes are not recommended when working under these conditions. Any questions regarding appropriate protective equipmentxe "Protective Equipment" can be directed to EHS.xe "Protective Equipment - EHS Assistance" Hand Protectionxe "Hand Protection". For any work requiring the use of gloves, make sure you are using gloves made of a material suitable for the operation. Gloves are made of a variety of materials and have specific uses and if used improperly they may not provide the necessary protection. The MSDSxe "MSDS" should specify the glove type and a glove selection chart is available on the EHS web pagexe "EHS - Web Page",  HYPERLINK http://www.ehs.psu.edu; www.ehs.psu.edu; but if in doubt call EHS for assistance. Consumption of food and beveragesxe "Food and Beverages - Safety Precautions" while working is not recommended. Wash hands and arms thoroughly prior to leaving the studio after working with potentially hazardous material and before eating, drinking, smoking, etc. Studio Practicesxe "SAFETY RULES - Studio Practices" All containers must be labeledxe "Container Labeling" (including such harmless items as distilled water). The label should contain the proper name of the material and, if appropriate, a statement of hazards (with the most severe first), precautions, and the name of the user. Do not use material from unlabeled containers. The need for adequate labeling extends far beyond the immediate requirements of the individual users, since they may not be present in case of fire or explosion, or when containers are broken or spilled. Also, they may no longer be associated with the studio years later when containers have deteriorated or otherwise lost their value. Prior to leaving the University each person must properly dispose of his/her waste or unwanted materials. All useful materials should be reassigned to another person who will assume responsibility. Proper labeling is important since it is difficult and costly to dispose of unlabeled chemicals. Never taste or smell any unknown material. Clean up spills immediatelyxe "Spills - Clean Up"! Someone familiar with precautions for the material may safely handle small spills. EHSxe "Spills - EHS Assistance"xe "EHS" has a special Hazardous Material Response Teamxe "Hazardous Material Response Team - EHS" and a fully equipped emergency vehicle to handle larger spills. If in doubt of your ability to handle the situation, evacuate the area, close the door, call 911 and explain the nature of the emergency. Under normal circumstances there is no charge for this service. Also, remain in a safe area near the incident after calling 911 in case EHSxe "EHS", Police Services, etc. needs information to properly address the situation. Items that might cause thermal burns, such as furnaces or hot plates should be posted with a HOT sign or other warning when in use but not attended. Transporting Chemicalsxe "Chemical Transport"xe "Transporting Chemicals" When chemicals are hand carried, they should be placed in a carrying container or (acid-carrying) bucket to protect against breakage and spillage. When they are transported on a wheeled cart, the cart should be stable under the load and have wheels large enough to negotiate uneven surfaces without tipping or stopping suddenly. Provisions for the safe transport of small quantities of flammable liquids include: the use of rugged pressure-resistant, non-venting containers, storage during transport in a well-ventilated vehicle, and elimination of potential ignition sources. Chemicals should not be carried in open containers in hallways or elevators where they may be spilled. Chemical Storagexe "Chemical Storage" Practices Every chemical should have a specific storage space. They should not be stored on counter tops where they can be knocked over or in hoods where they interfere with proper airflow. Flammable liquidsxe "Flammable liquids - Storage" should be stored in ventilated storage cabinets. Flammable liquids should not be stored near ignition sources or in areas where accidental contact with strong oxidizing agents is possible. These include chromic acid, permanganates, chlorates, perchlorates, and peroxides. All chemicals must be properly labeled giving the chemical name, name of owner, date of purchase, type of hazard and any emergency procedures. CHEMICAL HAZARDS AND SAFETY PROCEDURESxe "CHEMICAL HAZARDS"xe "CHEMICAL SAFETY PROCEDURES" The first step in using any chemical should be a review of the MSDSxe "MSDS" supplied by the manufacturer, available from the department's safety coordinator, or obtained from the EHSxe "EHS" office. Pay specific attention to the potential hazards and safety equipment required for working with the material. Be familiar with the proper emergency procedures recommended for the chemical in case of accidental exposure. Toxic Hazardsxe "Toxic Hazards"xe "CHEMICAL SAFETY - Toxic Hazards" Artists should be aware of the toxic hazards of the materials they are using, as well as those being used by others in their vicinity. Toxic materials may enter the body through the skinxe "Skin Hazards", inhalationxe "Inhalation Hazards", and/or ingestionxe "Ingestion Hazards". Care should be taken to prevent these means of exposure when handling toxic materials. A large number of common substances are acute respiratory hazards and should not be used in a confined area in large amounts. Acids and Basesxe "CHEMICAL SAFETY - Acids and Bases"xe "Acids and Bases" Acids and bases may be found in studio areas since there are a variety of applications for them. Two important hazards are associated with acids and bases: chemical burns suffered from spills, inhalationxe "Inhalation Hazards" of caustic vapors, and fires or explosions caused by strongly exothermic (heat producing) reactions occurring when strong acids are diluted rapidly. Strong bases often cause more severe burns than acids because they may not provide a warning, such as a burning sensation until damage to the skinxe "Skin Hazards" has already occurred. xe "Acids and Bases - Diluting"Always dilute acids by adding them to water and not vice versa. Use dilute acids and bases whenever possible. Keep bottles of strong acids and bases closed when not in use since they can react with moisture in the air to form caustic fumes. If acids or bases are accidentally splashed in the eyexe "Eye Safety" or on the skinxe "Skin Hazards", flush with water immediately, continue flushing for 15 minutes, and call for help. Hydrofluoric Acidxe "Hydrofluoric Acid" Hydrogen fluoridexe "Fluoride Hazards" (HF) is a very serious hazard since both its gas and solutions are extremely toxic and it is rapidly absorbed through the skinxe "Skin Hazards" without immediate warning (such as a burning sensation), but causes long term excruciating pain and burns which take a long time to heal. Prompt removal of contaminated clothing while the injured person is being flushed with water is essential. Continuous flushing with cool water is vital until any whitening of the tissue has disappeared. Cover the exposed area with wet, iced cloths and get immediate medical help. Do not apply any ointments. In all cases of contact with HF obtain medical aid. Simple flushing with water does not remove HF deep in the tissues and additional treatment is required. See appendix ## Guidelines For Working With HF Organic Solventsxe "Solvents"xe "Organic Solvents" Many organic solvents generate harmful vapors or pose health hazards because they can be easily absorbed through the skinxe "Skin Hazards". Most solvents are quite volatile and the vapors are flammable. Always refer to the MSDSxe "MSDS" of a solvent before using it to become aware of the hazards, safety precautions, and emergency procedures associated with that specific solvent. Always store them according to the guidelines for storage of flammable liquids. A few examples of the hazards of some common solvents are provided below, but this list is by no means complete. Acetonexe "Acetone": generates toxic and flammable vaporsxe "Flammable Vapors". Acetonexe "Acetone" should be used with proper ventilationxe "Ventilation", safety glasses, and neoprene gloves should be worn. Store acetonexe "Acetone" in a flammable liquids storage area. Methanolxe "Methanol": generates harmful vapors that can cause dizziness, central nervous system depression, and shortness of breath. Severe exposure can leadxe "Lead Hazards" to coma and eventually death. Less severe exposure can cause blurring of vision, conjunctivitisxe "Conjunctivitis", headaches, gastrointestinalxe "Gastrointestinal Hazards" disturbances, and definite eyexe "Eye Safety" lesions. Methanolxe "Methanol" should be used in a ventilationxe "Ventilation" hood and neoprene gloves should be worn. Powdersxe "Powders - Safety Hazards" Most ceramic materials are considered inert to the human body however submicron particles in the lungs may cause respiratory irritation. Whenever working with fine powders, some sort of protection is recommended such as capture hood ventilationxe "Ventilation". Some powders such as SiO2 (Silicaxe "Silica - Safety Hazards", Silicon Dioxide) cause lung diseases such as silicosisxe "Silicosis". PbO (Leadxe "Lead Hazards" Oxide) is considered extremely toxic and must be handled extremely carefully. If possible use powders in a hood until they are properly mixed into solution removing the dust hazard. The specific requirements for each powder are generally listed on the MSDSxe "MSDS". Some fine powders are also pyrophoric and may explode when dispersed in air. CHEMICAL WASTE DISPOSALxe "CHEMICAL WASTE DISPOSAL" Each individual has the responsibility for seeing that waste chemicals are safely collected, identified and stored for disposal, and that anyone involved is fully advised of the need for any special methods or facilities for proper disposal. Handling of Wastexe "Handling of Waste - Chemicals" Chemicals are everywhere: they can be found in animals, plants and water as well as in many commercially available products including medicines, detergents, paints and foods. The risk may be low, but present. In order to keep the risk to a minimum, all chemical waste must be disposed of properly. Once a material is declared a waste, the first responsibility for guiding its proper disposal rests with the worker. He or she is in the best position to know the degree of hazard posed by the material they have used and must provide sufficient information to fit it into the correct channel for disposal. Waste Chemicals that can be flushed down the drainxe "Chemical Disposal - Drain Disposal" Guidelines for the Drain Disposal of Chemicals (appendix l) states that small quantities of certain chemicals can be disposed of by flushing them down the drain with large amounts of water. These include: Some Acids and Bases:xe "Chemical Disposal - Acids and Bases Drain Disposal" The following acids and bases have been approved for drain disposal while flushing drain with water, if the pH range is between 3 and 11 (prior to draining). Sulfuric acid, hydrochloricxe "Hydrochloric Acid" acid, phosphoricxe "Phosphoric Acid" acid, sodium hydroxide, potassium hydroxide Some Solventsxe "Chemical Disposal - Solvent Drain Diposal": The following solvents used for rinsing glassware if they comprise less than 2 % of the final mixture may be drain disposed. Short chain alcohols (e.g., methanol, ethanol, and propanol), xylenes, hexane, toluenexe "Toluene", acetonexe "Acetone". Waste chemicals that must be collectedxe "Chemical Disposal - Collection by EHS" Any chemical which qualifies as a hazardous waste must be collected for proper disposal through EHS. xe "EHS" A waste may be designated as a hazardous waste if it meets one of the following criteria: Acute hazardous waste is a waste which has been found to be fatal in humans in low doses or, in the absence of data on humans, has been found to have, in laboratory animals: An oral LD50 (Lethal Dose of 50% of the test subjects) of less than 50 mg/kg. An inhalationxe "Inhalation Hazards" LC50 (Lethal Concentration) of less than 2 mg/l, or A dermal LD50 of less than 200 mg/kg. A waste is hazardous if it contains any of the toxic constituents listed in the regulations. A waste is hazardous if it exhibits any of the following characteristics: Ignitability Corrosivity Reactivity Toxicity * *A list is available on the EHSxe "EHS" web page,  HYPERLINK http://www.ehs.psu.edu www.ehs.psu.edu Disposalxe "Chemical Disposal - Department Procedures" Each room generating chemical waste must designate a location within the room for waste accumulation. This area should have plastic bins (supplied by EHSxe "EHS") to be used as secondary containment for waste bottles and all bottles used for waste must be tagged with red tags (also supplied by EHS). A log should be maintained documenting weekly that the area is checked to ensure that bottles are labeled, stored in the secondary containers, not leaking, segregated to prevent mixing of incompatible materials and to ensure that the total volume of waste in the area does not exceed 55 gal. There is a table for reference on compatibilites on the EHS web site,  HYPERLINK http://www.ehs.psu.edu www.ehs.psu.edu. The names of the principle investigator and the person responsible for oversight of the accumulation area should be recorded in a logbook containing the weekly checklist for the accumulation area. An audit of the studio verifying that these guidelines are being followed should be conducted annually. When waste has accumulatedxe "Chemical Waste Disposal - Request for EHS Pick-up" for disposal, a manifest (available on the EHSxe "EHS" web site) should be completed and forwarded electronically to EHS. Waste is generally picked up within a few days and under normal circumstances there is no charge for this service. ELECTRICAL HAZARDS AND SAFETY PROCEDURESxe "Shock - Electric"xe "ELECTRICAL HAZARDS AND SAFETY PROCEDURES" While electricity is in constant use by the artist, both within and outside the studio, significant physical harm or death may result from its misuse. With direct current, a person can detect a "tingling" feeling at 1 mA and the median "let-go" threshold (the current at which he cannot release the conductor) is 76 mA. For 60 Hertz alternating current, the values are 0.4 mA and 16 mA, respectively. Women are more sensitive to the effects of electrical current; approximately 2/3 of the current is needed to produce the same effect. Higher currents produce respiratory inhibition, then ventricular fibrillation, and ultimately cardiac arrest. If an electrical hazard is suspected, the device in question should be disconnected immediately and the cause ascertained by a person competent in such matters. Since malfunctioning equipment may contain shorts, merely turning off the equipment is not sufficient to prevent accidents. Equipment should be unplugged before being inspected or the circuit the equipment is wired to deactivated by putting the circuit breaker in the off position or removing the fuse. Equipment wired to a junction box should be turned off at the junction box. The following is a list of rules for working with electrical equipment: Turn off the power to equipment before inspecting it. Turn off circuit breakers or unplug the equipment All current transmitting parts of any electrical devices should be enclosed. Never plug leads into power source unless they are connected to an established circuit. Avoid contacting circuits with wet hands or wet materials. Do not insert another fuse of larger capacity if equipment keeps blowing fuses - this is a symptom requiring expert repairs. If a fuse blows, find the cause of the problem before putting in another one. Keep the use of extension cords to a minimum and cords as short as possible. Tie off excess cord out of pathways to avoid trip hazards. Do not use or store highly flammable solvents near electrical equipment. Multi-strip outlets (cube taps) should not be used in place of permanently installed receptacles. If additional outlets are required have them installed by an electrician. Keep access to electrical panels and disconnect switches clear and unobstructed. FIRE SAFETYxe "FIRE SAFETY" Fires can occur at any time so individuals must be familiar with nor only how to prevent fires but also the locations of fire exits, fire alarm pull stations, fire extinguishers and procedures to follow when a fire alarm sounds. Fire Safety and Prevention Keep fuels (paper, cardboard, cloth, solvents etc) away from potential heat sources. Do not allow combustible materials to accumulate in studios and other work areas. Dispose of all waste in approved containers. Oily rags should be disposed in approved safety cans. Do not block open fire rated doors. These doors which include the stair-tower doors need to be kept in the closed position to prevent smoke from moving throughout the building during a fire. Do not place materials in the building corridors or passageways within the studio rooms. These passageways need to be maintained free of obstructions to allow the easy passage of building occupants. Electrical extension cords are designed for temporary use only and the use of such cords should be kept to a minimum. If an extension cord is needed for temporary use it must be a heavy-duty type Underwriters Laboratory (UL) and Factory Mutual (FM) approved cord. The cord shall not be affixed to any object, located where it is exposed to physical or chemical damage or connected to other extension cords. Fire Emergency Proceduresxe "Fire Emergency Procedures" If the building fire alarm system sounds leave the building immediately using the nearest exit. If you are located on an upper floor you must use the stairways to leave the building. Do not use the elevator. Please assist any individuals who may require physical assistance to leave the building. Once you are outside of the building go to the designated gathering location for your class. Do not re-enter the building until directed to by Police Services. If a fire starts, activate the nearest fire alarm pull station and from a safe location call 9-1-1 to report the fire. If the fire is small and you have been trained in the safe operation of a fire extinguisher attempt to extinguish the fire. Never jeopardize your own safety trying to extinguish a fire. If you are not trained in the use of a fire extinguisher or the fire is too large leave the building immediately. If your clothes catch on fire, Stop, Drop and Roll" to extinguish the flames. Report all fires no matter how insignificant to PSU Police and EHSxe "EHS".xe "Environmental Health and Safety" Fire Extinguishersxe "Fire Extinguishers" Fire extinguishers are provided throughout the building and in many studio areas for use by building occupants. Fire extinguishers are designed to be used on small fires and only after the building fire alarm system has been activated. Individuals should be familiar the locations of all fire extinguishers in their areas. Access to fire extinguishers must be clear at all times. Do not place materials in f  SAFETY AND EMERGENCY RELATED REFERENCESxe "REFERENCES - Safety Related" The Merck Index, Merck Pharmaceutical Company. Dangerous Properties of Industrial Materials, 4th ed., N. Irving Sax, ed., Van Nostrand Pub. Co., New York, 1978. Toxic and Hazardous Industrial Chemicals Safety Manual, International Technical Information Institute, 1978. Prudent Practices for Handling of Hazardous Chemicals in Laboratories, National Academy Press, Washington, D.C., 1981. Prudent Practices for Disposal of Hazardous Chemicals from Laboratories, National Academy Press, Washington, D.C., 1983. Occupational Health Guidelines for Chemical Hazards, NIOSH-OSHA, Jan., 1981. Materials Safety Data Sheets published by chemical manufacturers are available through the safety office. Safety in Academic Laboratories, American Chemical Society, 1155 16th St. N.W., Washington D.C., 1979. II. SPECIFIC HAZARDS IN THE SCHOOL OF VISUAL ARTS Ceramic Art and Potteryxe "Ceramic Art and Pottery" Ceramic art and pottery has a wide variety of hazards. The specific hazards and precautions are divided into four areas: working with clay; glazing and coloring; firing in a kiln; and potential leaching of finished ware. Clayxe "Clay" Clays are minerals composed of hydrated aluminum silicates, often containing large amounts of crystalline silicaxe "Silica Hazards". Other impurities may include organic matter or sulfur compounds. Sometimes, grog (ground firebrick), sand, talc, vermiculite, perlite, and small amounts of minerals such as barium carbonate and metal oxides, are added to modify clay properties. Clays can be worked by hand or on the potters wheel, or cast as clay slurry into molds. Clay is made by mixing dry clay with water in clay mixer. Clay slip is made by adding talcs which themselves can be contaminated with fibrous asbestosxe "Asbestos" or asbestosxe "Asbestos"-like materials. Geographical sources of talcs are relevant, for example, New York State talcs are notoriously asbestosxe "Asbestos"-contaminated, while Vermont talcs are not. Pfizer has some fiber-free talcs. Hazards There have been known cases of silicosisxe "Silicosis", or potters rot, from chronic inhalationxe "Inhalation Hazards" of large amounts of free silicaxe "Silica Hazards" during clay mixing. Symptoms of silicosisxe "Silicosis" include shortness of breath, dry cough, emphysema, and high susceptibility to lung infections such as tuberculosis. The disease may take years to develop. Silicaxe "Silica - Safety Hazards" dust exposure is not hazardous by skinxe "Skin Hazards" contact or ingestionxe "Ingestion Hazards". Chronic inhalationxe "Inhalation Hazards" of kaolin is moderately hazardous, and can result in kaolinosis, a disease in which the lungs become mechanically clogged. Sand, perlite, grog, and vermiculite contain free silicaxe "Silica Hazards" and are, therefore, toxic by inhalationxe "Inhalation Hazards". Vermiculite is also frequently contaminated with asbestosxe "Asbestos". There is a danger of accidents if clay or water can be added while the mixer is in operation. Bags of clay and glaze materials can be very heavy, and improper lifting can cause backxe "Back Safety" problems. Hypersensitivity pneumonia, asthma, or other respiratory problems may occur with exposure to molds growing in wet clay that is being soured or aged in a damp place, in slips that stand for months, or with inhalationxe "Inhalation Hazards" of dry aged clay. Molds can cause or exacerbate skinxe "Skin Hazards" problems and change the workability of clay. Throwing on a potters wheel for long periods of time can result in carpel tunnel syndrome because of the awkward position of the wrists. Pain, numbness and/or pins and needles in the thumb and first three fingers, are common symptoms. Back problems can occur from bending over the potters wheel for long periods of time. Hand contact with wet clay can result in abrasion and dryness of fingertips and hands. Moving parts of kickwheels can cause cuts and abrasions. This can be especially a problem with young children. Clay scraps on the floor, bench and other surfaces can dry and pulverize, producing an inhalationxe "Inhalation Hazards" hazard due to the presence of free silicaxe "Silica Hazards". Similarly, reconditioning clay by pulverization and sanding finished greenware can create very high concentrations of hazardous silicaxe "Silica Hazards" dust. Precautions Use premixed clay to avoid exposure to large quantities of clay dust. Clay storage and mixing should take place in a separate room. Bags of clay (and other pottery materials) should be stacked on palettes or grids off the floor for easier clean-up. All clay mixers should be equipped with local exhaust ventilationxe "Ventilation" to remove fine silicaxe "Silica Hazards" dust particles from the air. Clay mixers should be equipped with proper machine guards so that they cannot be opened to add clay or water while the mixer blades are turning. Wear separate work clothes or smocks while in the studio. Choose clothes of material and design that dont trap dust. Wash these clothes weekly and separately from other laundry. Do not use asbestosxe "Asbestos" or asbestosxe "Asbestos"-contaminated talcs. Avoid contact of clay with broken skinxe "Skin Hazards". Use a skinxe "Skin Hazards" moisturizer. To prevent backxe "Back Safety" problems, always liftxe "Back Safety" with knees bent. Also, use a standup wheel (Cranbrook style treadle wheel), or elevate electric wheels to a height that doesnt require bending over. Exercise and massage may relieve minor muscular pain. Information on Back and Lifting Safety can be found on the EHSxe "EHS" Ergonomicsxe "Ergonomics" Program web page (http://www.ehs.psu.edu/ergo/index.html). Keep wrists in unflexed position as much as possible to prevent carpal tunnel syndromexe "Carpal Tunnel Syndrome". Take frequent work breaks. Information on proper wrist postures and general ergonomics can be found on the EHSxe "EHS" Ergonomicsxe "Ergonomics" Program web page (http://www.ehs.psu.edu/ergo/index.html). Be careful of the moving parts on kickwheels, and do not allow young children to use kick-style potters wheels. Recondition clay by cutting still-wet clay into small pieces, letting them air-dry, and soak in water. Finish green ware while still wet or damp with a fine sponge instead of sanding when dry. Do not sand greenware containing fibrous talc. Wet mopxe "Clean up - Wet Methods to Prevent Dust Exposure" floors and vacuum work surfaces daily to minimize dust levels and prevent dry scraps from becoming pulverized. Floors should be sealed or made of easy-cleaning material. Vacuum cleaners are useful only if equipped with high efficiency (HEPAxe "HEPA Vacuums") filters to prevent fine hazardous dusts xe "Silica Hazards" from passing through regular industrial and household vacuum cleaners. A HEPAxe "HEPA Vacuums" vacuum is available in the School of Visual Arts. It is the responsibility of the appropriate faculty member to clean work areas after each use. The vacuum is maintained in the shop located in the Visual Arts Building. Glazesxe "Glazes" Glazes used to color or finish clay pieces are a mixture of silicaxe "Silica Hazards", fluxesxe "Fluxes - Soldering" and colorants. Common fluxesxe "Fluxes - Soldering" include leadxe "Lead Hazards", barium, lithium, calcium and sodium, and are used to lower the melting point of silicaxe "Silica Hazards". The actual colorants, which are an assortment of metal oxides usually account for less than 5% of the glaze by weight. Originally, soluble raw leadxe "Lead Hazards" compounds including red leadxe "Lead Hazards", white leadxe "Lead Hazards", galena, and litharge were used as fluxesxe "Fluxes - Soldering" in low-fire glazes. In fact, over 400 cases of leadxe "Lead Hazards" poisoning were reported in British potters in 1897. Leadxe "Lead Hazards" frits and good housekeeping greatly lowered the number of potters that had been poisoned by these highly toxic leadxe "Lead Hazards" compounds. Frits are made of melted minerals and metal compounds that are sintered and ground into powder form. While leadxe "Lead Hazards" frits are sometimes assumed to be insoluble and nontoxic, leaching tests with acids have shown that many frits are as soluble as raw leadxe "Lead Hazards" compounds and, in fact, there have been cases of leadxe "Lead Hazards" poisoning from both inhalationxe "Inhalation Hazards" or ingestionxe "Ingestion Hazards" of these. High fire porcelain and stoneware techniques eliminate the need for leadxe "Lead Hazards" as a flux. Also, alkali earth or alkaline earth fluxesxe "Fluxes - Soldering" can be used for low-fire conditions instead of leadxe "Lead Hazards". Silicaxe "Silica - Safety Hazards" may also be removed from leadless type glazes. The substitution can be based on boric oxide as the glass-former, instead of silicaxe "Silica Hazards". Alkali earth fluxesxe "Fluxes - Soldering" include sodium, potassium, and lithium oxides; alkaline earth fluxesxe "Fluxes - Soldering" include calcium, magnesium, barium, and strontium oxides. Minerals containing these fluxesxe "Fluxes - Soldering" include certain feldspars, nepheline syenite, petalite, bone and plant ashes, whiting, and dolomite. An assortment of metal oxides or other metal compounds produce particular colors when fired. These are added in such small amounts to the glaze, that they arent usually a great hazard. Luster or metallic glazes are fired in a reduction atmosphere. These glazes can contain mercury, arsenic, highly toxic solvents such as aromatic and chlorinated hydrocarbonsxe "Chlorinated Hydrocarbons", and oils such as lavender oil. The common metals are often resinates of gold, platinum, silver, and copper. Some underglazes and overglazes use mineral spiritsxe "Mineral Spirits" as the vehicle instead of water. Glaze components are weighed, sorted and mixed with water. These materials are often in fine powdered form, and result in high dust exposures. Glazes can be dipped, brushed, poured, or sprayed on the ceramic piece. Hazards Leadxe "Lead Hazards" compounds are highly toxic by inhalationxe "Inhalation Hazards" or ingestionxe "Ingestion Hazards". Symptoms of leadxe "Lead Hazards" poisoning include: damage to the peripheral nervous system, brainxe "Brain Damage Hazards", kidneyxe "Kidney Hazards", or gastrointestinalxe "Gastrointestinal Hazards" system, as well as, anemiaxe "Anemia", chromosomal damage, birth defectsxe "Birth Defects" and miscarriages. All leadxe "Lead Hazards" compounds, including leadxe "Lead Hazards" frits, are regulated by the Occupational Safety and Health Administration (OSHA). Leadxe "Lead Hazards"-glazed foodware can leach leadxe "Lead Hazards" if not fired properly, or if the glaze composition is not correctly adjusted. For example, the addition of copper to leadxe "Lead Hazards" frits renders a higher solubility of leadxe "Lead Hazards" in the final fired ware. Acidic drinks and foods such as tomato juice, citric juices, sodas, tea, or coffee can increase this hazard. A glaze label marked leadxe "Lead Hazards"-safe means that the finished ware, if fired properly, will not release leadxe "Lead Hazards" into food or drink. The actual glaze is still hazardous to handle and fire and may contain leadxe "Lead Hazards". Adequate control over firing conditions is very difficult in the craft studio. Other fluxesxe "Fluxes - Soldering" such as barium and lithium are also highly toxic by inhalationxe "Inhalation Hazards", but less so than leadxe "Lead Hazards". Certain colorant compounds of particular metals are known probable human carcinogensxe "Carcinogens", including arsenic, beryllium, cadmiumxe "Cadmium", chromium (VI), nickel and uranium. Antimonyxe "Antimony Hazards", barium, cobaltxe "Cobalt", leadxe "Lead Hazards", lithium, manganesexe "Manganese", and vanadium colorant compounds are highly toxic by inhalationxe "Inhalation Hazards". Antimonyxe "Antimony Hazards", arsenic, chromium, vanadium, and nickel compounds are moderately toxic by skinxe "Skin Hazards" contact. Free silicaxe "Silica Hazards" may occur in many of the clays, plant ash, flint, quartz feldspars, talcs, etc. used in glazes. See the discussion above for the hazards of silicaxe "Silica Hazards" and the disease silicosisxe "Silicosis". Weighing and mixing glazes can result in the inhalationxe "Inhalation Hazards" of these toxic materials. Soda ash, potassium carbonate, alkaline feldspars, and fluorspar used in glazes are skinxe "Skin Hazards" irritants. Spray application of glazes is very hazardous because of the potential inhalationxe "Inhalation Hazards" of glaze mists. Dipping, pouring, and brushing certain glazes may cause skinxe "Skin Hazards" irritation and accidental ingestionxe "Ingestion Hazards" due to careless personal hygiene habits. Glazes containing solvents are both flammable and hazardous. Precautions Use leadxe "Lead Hazards"-free glazes. If the glaze does not state leadxe "Lead Hazards"-free or leadless on the label, assume it contains leadxe "Lead Hazards" until proven otherwise. Leadxe "Lead Hazards" glazes should only be used on non-foodware items. Design leadxe "Lead Hazards"-glazed pieces so that they wont be used for food or drink. Leadxe "Lead Hazards"-glazed pottery should be labeled as leadxe "Lead Hazards"-containing. If possible, dont use colorants that are known human carcinogensxe "Carcinogens" and avoid probable human carcinogensxe "Carcinogens". There is no known safe level of exposure to carcinogensxe "Carcinogens". Weigh and mix powdered glazes using an exhaust hood. Wet glazes are not an inhalationxe "Inhalation Hazards" hazard. Good housekeeping procedures and cleanup of spills reduce the risk of inhalationxe "Inhalation Hazards" or ingestionxe "Ingestion Hazards" of toxic dusts. Wet clean or HEPAxe "HEPA Vacuums" vacuum spilled powders. Gloves should be worn while handling wet or dry glazes. Barrier creams may cause glazes to creep during firing. A spraybooth that exhausts to the outside is needed for glaze spraying. Solvent-based glazes require an explosion-proof spraybooth. Good dilution ventilationxe "Ventilation" or local exhaust ventilationxe "Ventilation" should be available when applying solvent-containing glazes. Basic personal hygiene rules should be followed including restricting eating, drinking, or smoking in the studio, and wearing personal protective equipmentxe "Protective Equipment" such as gloves, and separate work clothes or coveralls. Wash hands after work and before eating, drinking, smoking, etc. Leftover glazes and glaze scrapings can be homogenized, combined, tested, and used as a glaze. Kilnsxe "Kilns" Electric and fuel-fired kilns are used to heat pottery to the desired firing temperature. The most common type is electric. Heating elements heat the kiln as electric current passes through the coils. The temperature rises until the kiln is shut off automatically. Fuel-fired kilns are heated by burning gas (natural or propane), oil, wood, coke, charcoal or other materials. Propane gas or natural gas is used most often. These kilns can be either located indoors or outdoors. The fuels produce carbon monoxide and other combustion gases. Fuel-fired kilns are usually vented from the top through a chimney. Firing temperatures can vary from as low as 1,382o F for raku and bisque wares, to as high as 2,372 oF for stoneware, and 2,642 oF for certain porcelains. The early stages of bisque firing involve the oxidization of organic clay matter to carbon monoxide and other combustion gases. Sulfur breaks down later producing highly irritating sulfur oxides. Also, nitrates and nitrogen-containing organic matter break down to nitrogen oxides. Galena, cornish stone, crude feldspars, low grade fire clays, fluorspar, gypsum, lepidolite and cryolite can release toxic gases and fumes during glaze firings. Carbonates, chlorides, and fluorides are broken down to releasing carbon dioxide, chlorine, and fluorine gases. At or above stoneware firing temperature, leadxe "Lead Hazards", antimony, cadmiumxe "Cadmium", selenium and precious metals vaporize and the metal fumes can either escape from the kiln, or settle inside the kiln or on ceramic ware in the kiln. Nitrogen oxides and ozone can be generated from oxygen and nitrogen in air. Hazards Chlorine, fluorine, sulfur dioxide, nitrogen dioxidexe "Nitrogen Dioxide", and ozone are highly toxic by inhalationxe "Inhalation Hazards". Bisque firings of high-sulfur clay have caused the production of great amounts of choking sulfur dioxide. Inhalation of large amounts of these gases can result in severe acute or chronic lung problems. Long-term inhalationxe "Inhalation Hazards" of low levels of these gases can cause chronic bronchitisxe "Bronchitis" and emphysema. Fluorine gas can also cause bone and teeth problems. Many metal fumes generated at high temperatures are highly toxic by inhalationxe "Inhalation Hazards". Since leadxe "Lead Hazards" vaporizes at a relatively low temperature, it is especially hazardous. Carbon monoxidexe "Carbon monoxide" from fuel-fired kilns or the combustion of organic matter in clays is highly toxic by inhalationxe "Inhalation Hazards" and can cause oxygen starvation. One symptom of carbon monoxide poisoning is an intense frontal headache, unrelievable by analgesics. There must be careful planning for additional exhaust systems in the gas kiln area. A lack of makeup air may result in exhaust fans actually pulling carbon monoxide-contaminated air from the gas kilns into the room. Weather conditions also effect the efficiency of kiln draft. Special effects are obtained by the addition of materials, which can generate other toxic kiln emissions. Hot kilns produce infrared radiation, which is hazardous to the eyesxe "Eye Safety". There have been reports of cataracts, from years of looking inside the hot kilns. Heat generated by the kiln can cause thermal burns. When one kiln was operated at 23700 F, the surface temperature, was at and above 5950 F, and the temperature one foot away from the peephole was 1560 F. Heat produced by even small electric kilns can cause fires in the presence of combustible materials or flammable liquids. This can include a wooden floor. If an electric kiln fails to shut off, the heating elements melt which can cause fires. Gas kilns also generate a lot of heat, and room temperatures often exceed 1000 F. Natural gas and propane are fire and explosion hazards. Since propane is heavier than air, it can collect at floor level and not disperse. Precautions Ventilate kilns with local exhaust ventilationxe "Ventilation", such as a canopy hood. Top-loading electric kilns may have to be enclosed with fireproof curtains since the canopy will be located too high from the kiln top to be effective. Curtains should be short enough to allow entry of makeup air. Ready-made, commercial canopy hoods that can be raised or lowered must be tested in actual use for effectiveness. Kilns should be kept in a separate room to reduce excess heat in the working studio. If no one works in the kiln room, electric kilns can be safely vented with a window exhaust fan placed near the kiln. Adequate makeup air should be available for any exhaust systems in the kiln area. Chimneys should have a high enough stack to prevent exhaust from re-entering the building. High-velocity stack fans may be necessary. Infrared goggles approved by the American National Standards Institute (ANSIxe "ANSI") or hand-held welding shields should be worn when looking into the operating kiln. A shade number from 1.7 to 3.0 is recommended, but a darker shade may be required if spots appear in front of ones eyesxe "Eye Safety" after looking away from the kiln. Do not use leadxe "Lead Hazards" compounds at stoneware temperatures since the leadxe "Lead Hazards" will vaporize. Lumber paper, solvents, or other combustible and flammable materials should not be stored in kiln areas. Raise electric kilns at least a foot off the floor, and place at least two feet from any wall, allowing air circulation. Wooden floors should be protected with non-asbestosxe "Asbestos" containing fireproof materials (e.g. firebrick). All electric kilns should meet local fire and electrical codes, and should be installed by a licensed electrician. Electric kilns should have two automatic shut-offs. The primary shut-off should be a cone-operated shut-off or a pyrometer. A timer backup should also be installed to ensure reliability. Always check that the kiln has shut off. A carbon monoxide alarm should be provided for the area where indoor gas kilns are located. EHS should be consulted for appropriate variety. Gas lines should be installed by qualified personnel. Regulators, to automatically shut off kilns if the air flow stops or if a negative pressure develops should be installed. If gas leaks are suspected (e.g. gas odor): shut off gas at the source; shut off power to the kiln room at the circuit breaker; and call the Office of Physical Plant (865-4731) and EHS.xe "EHS" Special Processes While most glaze firings refer to firing a glaze-coated pot in the kiln, special processes sometimes are used. Salt glazing and raku firing are two examples. Salt Glazingxe "Glazing - Salt"xe "Salt Glazing" This process involves throwing wet salt (sodium chloride) into the heated kiln while the bisque ware is being fired. Wet salt at high temperatures decomposes to sodium and chlorine. The sodium reacts with the bisque ware to form a glaze. Large amounts of hydrogen chloride gas and chlorine are also formed. Sodium carbonate (washing soda) can also be used. Carbon dioxide is generated instead of hydrogen chloride. Hazards Hydrogen chloride gas is highly toxic by inhalationxe "Inhalation Hazards". Health effects are both similar and more irritating compared with most other kiln gases. Hydrogen chloride and water vapor form hydrochloricxe "Hydrochloric Acid" acid, which can corrode metal fittings in the area, burn eyesxe "Eye Safety", skinxe "Skin Hazards", etc. Precautions Substitute safer sodium carbonatexe "Sodium Carbonate" for sodium chloride. Sodium chloride salt glazing should only be done outdoors. Kilns should be equipped with canopy hoods and chimney stacks that are tall enough to disperse the hydrogen chloride safely. All gas piping and metal fixtures should be routinely checked for corrosion. Rakuxe "Raku" Firing Raku involves first firing ware at a low temperature in a regular gas kiln, and then removing the still hot pieces and placing in them in sawdust, leaves or other organic materials for a reduction phase. Hazards See above for the hazards and safety precautions used with gas kilns. The reduction step produces large amounts of smoke and carbon monoxide. Treated wood or other materials can yield an exposure to highly toxic preservatives or pesticides, such as arsenic and chromium compounds. Precautions Raku should only be done outdoors because of smoke. Be careful to not locate raku near air intakes or open windows of buildings. Do not use materials that have been treated with preservatives or pesticides for the reduction phase. Leaching of Finished Ceramic Warexe "Leaching of Finished Ceramic Ware" Leadxe "Lead Hazards" Leaching There is a real concern about leadxe "Lead Hazards" leaching into food and drink from pottery fired with leadxe "Lead Hazards" glazes. Both the U.S. Food and Drug Administration (FDA) and the Canadian Consumer and Corporate Affairs have regulated how much leadxe "Lead Hazards" can leach from foodware into food and drink. Acidic liquids are of particular concern. Similarly, continual microwave reheating, (e.g. a coffee mug at work) can yield greater leaching of leadxe "Lead Hazards" glazes. Many cases of leadxe "Lead Hazards" poisoning, and even some fatalities, have occurred from the leaching of leadxe "Lead Hazards" from leadxe "Lead Hazards"-glazed pottery. Placing acid in the vessel for 24 hours, and then testing the liquid to see how much leadxe "Lead Hazards" has leached can test ceramic ware. 1991 FDA guidelines give the maximum amount of leadxe "Lead Hazards" that can leach from various types of ware: While commercial ceramics companies routinely test their ware for leadxe "Lead Hazards" leaching, craft potters do not have the same quality control as does the ceramics industry, and leadxe "Lead Hazards" leaching is more of a problem. According to United States regulation, ceramic ware that does not pass leadxe "Lead Hazards" leaching tests must have a permanent fired decal stating: NOT FOR FOOD USE - MAY POISON FOOD. FOR DECORATIVE PURPOSES ONLY. Drilling a hole in the pottery prevents it from being used for liquids or food. Lead glazes should be avoided in general but particularly for food and drink vessels. Other Leachable Metalsxe "Leachable Metals" Other toxic metals in glazes can leach into food and drink. Barium has been seen to leach in hazardous amounts from certain glaze formulations. If a barium glaze, or other glaze, changes color from contact with food, do not use the vessel for food. Try and use only glazes with calcium, magnesium, potassium, and sodium fluxesxe "Fluxes - Soldering" and minimize the amounts of toxic metal colorants. Routine testing for other metal leaching should be done. Painting and Drawing Hazardsxe "Painting and Drawing Hazards" This section discusses the hazards and precautions of working with paints, pastels, inks, pencils, crayons and other painting and drawing media. We hope to make readers more aware of the hazards of working with painting and drawing media and the precautions you can take to work safely. Working safely can involve changes in how you select your art materials and how you handle them. Oil Paintingxe "Oil Painting" Oil painting is regaining popularity as a medium at both the secondary school and college level. Large numbers of students painting in oils at the same time, however, can be hazardous unless careful precautions are followed. Basic Oil Painting In basic oil painting, students work with tube oil paints and use solvents for thinning the paints, in mediums and in cleanup. Many pigments are toxic, including those based on leadxe "Lead Hazards", cadmiumxe "Cadmium", mercury, chromates, manganesexe "Manganese" and cobaltxe "Cobalt". The main risk is from accidental ingestionxe "Ingestion Hazards" of the pigments due to eating while working, nail-biting, pointing your brush with your lips, and similar means of hand to mouth contact. Simple precautions and common sense can eliminate the risk. The use of solvents is a more serious hazard. Commonly, a student might have a half -cup of solvent in a container, which is normally left uncovered. Over a 3-hour class period, about one quarter to half of this might evaporate from the container or by use. All solvents can cause defatting of the skinxe "Skin Hazards" and dermatitis from prolonged or repeated exposure. Turpentine can also cause skinxe "Skin Hazards" allergies and be absorbed through the skinxe "Skin Hazards". Acute inhalationxe "Inhalation Hazards" of high concentrations of turpentinexe "Turpentine" or mineral spiritsxe "Mineral Spirits" can cause narcosis (dizziness, nausea, fatigue, loss of coordination, coma, etc.) and respiratory irritation. Chronic inhalationxe "Inhalation Hazards" of turpentinexe "Turpentine" can cause kidneyxe "Kidney Hazards" damage and possible respiratory allergies. Chronic inhalationxe "Inhalation Hazards" of large amounts of mineral spiritsxe "Mineral Spirits" could cause brainxe "Brain Damage Hazards" damage. Odorless mineral spiritsxe "Mineral Spirits" or turpenoid, which have had the aromatic hydrocarbons removed, are less hazardous. Ingestion of either turpentinexe "Turpentine" or mineral spiritsxe "Mineral Spirits" can be fatal. In the case of mineral spiritsxe "Mineral Spirits", this is usually due to chemical pneumonia caused by aspiration of the mineral spiritsxe "Mineral Spirits" into the lungs after vomiting. Advanced Oil Painting In advanced classes, students sometimes mix their own oil paints from the powdered pigment. This activity creates the additional hazard of inhalationxe "Inhalation Hazards" of the powdered pigment. In many colleges, traditional underpainting techniques using turpentinexe "Turpentine" washes are taught. This is hazardous since it involves brushing onto the canvas as much as a cup or more of turpentinexe "Turpentine" in a short period. Although this is hazardous enough when one individual does a turpentinexe "Turpentine" wash, it becomes extremely hazardous when a whole class does it due to the enormous amounts of solvent evaporation. Hazards Oil painting can involve hazards from accidental ingestionxe "Ingestion Hazards" of pigments, and from inhalationxe "Inhalation Hazards" or skinxe "Skin Hazards" contact with solvents such as turpentinexe "Turpentine", turpenoid or mineral spiritsxe "Mineral Spirits". Precautions Not eating, drinking, smoking or applying makeup while working can prevent accidental ingestionxe "Ingestion Hazards" of pigments. In addition do not point your brushes with your lips. In general we recommend against mixing your own powdered pigments. If you do mix the powdered pigment, do so inside an exhaust hood. The pigments can be ground and mixed with oil inside the hood. Recommend against and avoid the use of the most toxic pigments: leadxe "Lead Hazards" white or flake white, the arsenic variety of cobaltxe "Cobalt" violet, true vermilion (mercuric sulfide) and chromexe "Chrome" yellow (leadxe "Lead Hazards" chromatexe "Chromate Hazards"). For solvents, use an odorless paint thinner or turpenoid rather than the more toxic turpentinexe "Turpentine". The amount of ventilationxe "Ventilation" needed depends on the amount of solvent that evaporates. For an advanced class doing turpentinexe "Turpentine" washes, the amount of ventilationxe "Ventilation" needed is much greater. This amount of ventilationxe "Ventilation" is impractical and it is recommended that underpainting using turpentinexe "Turpentine" washes be avoided. Instead acrylic underpainting is suggested. Evaporation of solvent can be further reduced by: covering all open containers of solvent with aluminum foil wrapped around the brushes and top of container. placing waste solvent in approved solvent waste cans and closing all containers of waste solvents when not being used. reducing class size or number of students painting in oil. Note that once a dilution ventilationxe "Ventilation" rate is fixed for these painting classrooms, that fixes the total amount of solvent that can be evaporated in a class. Work rules would have to be established to ensure this is followed. Oil painting classrooms should have an eyewash fountain in case of solvent splashes in the eyexe "Eye Safety". Airbrush, Spray Cans and Spray Gunsxe "Airbrush, Spray Cans and Spray Guns" Artists use many products in spray form, including fixatives, retouching sprays, paint sprays, varnishes, and adhesive sprays. Airbrushes, aerosol spray cans and spray guns are used. Hazards Spray mists are particularly hazardous because they are easily inhaled. If the paint being sprayed contains solvents, you can inhale liquid droplets of the solvents. In addition, the pigments are also easily inhaled, creating a much more dangerous situation than applying paint by brush. Aerosol spray paints have an additional hazard besides pigments and solvents. They contain propellants, usually isobutanes and propane, which are extremely flammable and have been the cause of many fires. Other aerosol spray products such as retouching sprays, spray varnishes, etc. also contain solvents, propellants and particulates being sprayed. Airbrushing produces a fine mist which is a serious inhalationxe "Inhalation Hazards" hazard because artists work so close to their artwork. Airbrushing solvent-containing paints is especially dangerous. Spray guns are less common in art painting but usually involve spraying much larger quantities of paint than either spray cans or airbrush. Spraying solvent-based paints is a serious fire hazard. Precautions See section below for precautions with pigments. Try to brush items rather than spraying if possible. Use water-based airbrushing paints and inks rather than solvent-based paints. Use spray cans or an airbrush in a spray booth. If the material sprayed contains solvents, then the spray booth must be sparkproof. There should be no sources of ignition (electric switches, motors, flames etc.) within 10 feet of the spray booth opening. Also, all light fixtures within 20 feet of the spray booth should be enclosed and shatter-proof. Spray booths that recirculate air rather than exhausting air to the outside are not recommended. If ventilationxe "Ventilation" is not adequate, then work outdoors. Never try to spray paint by blowing air from your mouth through a tube. This can leadxe "Lead Hazards" to accidental ingestionxe "Ingestion Hazards" of the paint. Pigmentsxe "Pigments" Pigments are used in oil paints, acrylics, watercolors, gouache, encaustic, poster paints, casein paints and tempera. Sometimes commercial paints such as oil enamel, epoxy and automobile paints are used. Paints are pigments mixed with a vehicle or binder. Both inorganic and organic pigments are used as colorants. Dry pigments are especially hazardous because they are easily inhaled and ingested. They are used in encaustic, paper-marbleizing and in the fabrication of paint products, and will be discussed more thoroughly in the section below. Hazards Poisoning can occur if toxic pigments are inhaled or ingested. The main hazard in standard painting techniques is accidental ingestionxe "Ingestion Hazards" of pigments due to eating, drinking or smoking while working, inadvertent hand to mouth contact, or pointing the paint brush with the lips. If methods such as spraying, heating, or sanding are employed then there is an opportunity for inhalationxe "Inhalation Hazards" of toxic pigments. The classic example of a toxic inorganic pigment in painting is white leadxe "Lead Hazards", or flake white (basic leadxe "Lead Hazards" carbonate). Leadxe "Lead Hazards" pigments can cause anemiaxe "Anemia", gastrointestinalxe "Gastrointestinal Hazards" problems, peripheral nervexe "Nerve Damage Hazards" damage (and brainxe "Brain Damage Hazards" damage in children), kidneyxe "Kidney Hazards" damage and reproductivexe "Reproductive Hazards" system damage. Other inorganic pigments may be hazardous; including pigments based on cobaltxe "Cobalt", cadmiumxe "Cadmium", and manganesexe "Manganese". (See Table 1) Some of the inorganic pigments, in particular cadmiumxe "Cadmium" pigments, chromexe "Chrome" yellow and zincxe "Zinc" yellow may cause lung cancerxe "Cancer". In addition lampblack and carbon blackxe "Carbon Black" may contain impurities that can cause skinxe "Skin Hazards" cancerxe "Cancer". Chromatexe "Chromate" pigments (chromexe "Chrome" yellow and zincxe "Zinc" yellow) may cause skinxe "Skin Hazards" ulceration and allergicxe "Allergic Reactions" skinxe "Skin Hazards" reactions (such as rashes). The long-term hazards of the modern synthetic organic pigments have not been well studied. (See Table 1) Table 1 Toxic Pigmentsxe "Toxic Pigments - Table 1" Known or Probable Carcinogens/Highly Toxic Pigments antimony white (antimony trioxide) barium yellow (barium chromatexe "Chromate Hazards") burnt umber or raw umber (iron oxides, manganesexe "Manganese" silicates or dioxide) cadmiumxe "Cadmium" red or orange (cadmiumxe "Cadmium" sulfide, cadmiumxe "Cadmium" selenide) cadmiumxe "Cadmium" yellow (cadmiumxe "Cadmium" sulfide) Table 1 Toxic Pigmentsxe "Toxic Pigments - Table 1" (Continued) cadmiumxe "Cadmium" barium colors (cadmiumxe "Cadmium" colors and barium sulfate) cadmiumxe "Cadmium" barium yellow (cadmiumxe "Cadmium" sulfide, cadmiumxe "Cadmium" selenide, barium sulfate, zincxe "Zinc" sulfide) chromexe "Chrome" green (prussian blue, leadxe "Lead Hazards" chromatexe "Chromate Hazards") chromexe "Chrome" orange (basic leadxe "Lead Hazards" carbonate) chromexe "Chrome" yellow (leadxe "Lead Hazards" chromatexe "Chromate Hazards") cobaltxe "Cobalt" violet (cobaltxe "Cobalt" arsenate or cobaltxe "Cobalt" phosphate) cobaltxe "Cobalt" yellow (potassium cobaltinitrate) leadxe "Lead Hazards" or flake white (basic leadxe "Lead Hazards" carbonate) lithol red (sodium, barium and calcium salts of soluble azo pigment) manganesexe "Manganese" violet (manganesexe "Manganese" ammonium pyrophosphate) molybdate orange (leadxe "Lead Hazards" chromatexe "Chromate Hazards", leadxe "Lead Hazards" molybdate, leadxe "Lead Hazards" sulfate) naples yellow (leadxe "Lead Hazards" antimonate) strontium yellow (strontium chromatexe "Chromate Hazards" vermilion (mercuric sulfide) zincxe "Zinc" sulfide zincxe "Zinc" yellow (zincxe "Zinc" chromatexe "Chromate Hazards") Moderately Toxic Pigments/Slightly Toxic Pigments alizarin crimson (lakes of 1,2-dihydroxyanthaquinone or insoluble anthraquinone pigment) carbon blackxe "Carbon Black" (carbon) cerulean blue (cobaltxe "Cobalt" stannate) cobaltxe "Cobalt" blue (cobaltxe "Cobalt" stannate) cobaltxe "Cobalt" green (calcined cobaltxe "Cobalt", zincxe "Zinc" and aluminum oxides) chromium oxide green (chromic oxide) manganesexe "Manganese" blue (barium manganate, barium sulfate) prussian blue (ferric ferrocyanide) toluidine red (insoluble azo pigment) toluidine yellow (insoluble azo pigment) viridian (hydrated chromic oxide) zincxe "Zinc" white (zincxe "Zinc" oxide) Precautions Obtain MSDSs on your paints to find out what pigments you are using. This is especially important because the name that appears on the tube of color may or may not truly represent the pigments present. Manufacturers may keep the name of a color while reformulating the ingredients. Use the least toxic pigments possible. Do not use leadxe "Lead Hazards" or carcinogenic pigments. Avoid mixing dry pigments whenever possible. If dry pigments are mixed, do it inside a fume hood. Wet mopxe "Clean up - Wet Methods to Prevent Dust Exposure" and wipe or HEPAxe "HEPA Vacuums" vacuum and wet wipe all surfaces when using dry pigments. DO NOT use dishes, containers or utensils from the kitchen to mix and store paints and pigments. Water-Based Paintsxe "Water-Based Paints" Water-based paints include water color, acrylic, gouache, tempera and casein. Water is used for thinning and cleanup. Hazards See section above for pigment hazards. Acrylic paints contain a small amount of ammoniaxe "Ammonia". Some sensitive people may experience eyexe "Eye Safety", nose and throat irritation from the ammoniaxe "Ammonia". Acrylics and some gouaches contain a very small amount of formaldehydexe "Formaldehyde" as a preservative. Only people already sensitized to formaldehydexe "Formaldehyde" would experience allergicxe "Allergic Reactions" reactions from the trace amount of formaldehydexe "Formaldehyde" found in acrylics. The amounts can vary from manufacturer to manufacturer. Casein paints use the protein casein as a binder. While soluble forms are available, casein can be dissolved in ammonium hydroxide which is moderately irritating by skinxe "Skin Hazards" contact and highly irritating by eyexe "Eye Safety" contact, ingestionxe "Ingestion Hazards" and inhalationxe "Inhalation Hazards". All water-based paints contain a preservative to prevent mold or bacterial growth. Sometimes artists add preservatives when they make their own paints. Although present in small amounts, certain preservatives may cause allergicxe "Allergic Reactions" reactions in some people. Precautions See section above for precautions when mixing dry pigments. If you add your own preservative, avoid using sodium fluoridexe "Fluoride Hazards", phenolxe "Phenol" or mercury compounds. For tempera, a small amount of pine oil works for short periods of time. If you experience eyexe "Eye Safety", nose or throat irritation while using acrylics, opening a window is usually sufficient; if not try a window exhaust fan. If you mix casein paints using ammonium hydroxide, you will need exhaust to provide ventilationxe "Ventilation". Wear gloves, goggles and protective apron when handling ammoniaxe "Ammonia". An eyewash fountain should be available when handling ammoniaxe "Ammonia". Drawingxe "Drawing Hazards - General" Dry Drawing Mediaxe "Drawing Hazards - Dry Drawing Media" This includes dust-creating media such as charcoal and pastels which are often fixed with aerosol spray fixatives, and media such as crayons and oil pastels which do not create dust. Hazards Pencils are now made with graphite, rather than leadxe "Lead Hazards" as was true centuries ago and are not considered a hazard. Colored pencils have pigments added to the graphite, but the amounts are small so that there is no significant risk of exposure. Over 10 years ago, a significant hazard in pencils was from leadxe "Lead Hazards" chromatexe "Chromate Hazards" paint on the exterior of yellow pencils. However this has since been eliminated as a risk. Charcoal is usually made from willow or vine sticks, where wood cellulose has been heated without moisture to create the black color. Compressed charcoal sticks use various resins in a binder to create the color. Although charcoal is just considered a nuisance dust, inhalationxe "Inhalation Hazards" of large amounts of charcoal dust can create chronic lung problems through a mechanical irritation and clogging effect. A major source of charcoal inhalationxe "Inhalation Hazards" is from the habit of blowing excess charcoal dust off the drawing. Colored chalks are also considered nuisance dusts. Some chalks are dustier than others. Individuals who have asthma sometimes have problems with dusty chalks, but this is a nonspecific dust reaction, not a toxic reaction. Pastel sticks and pencils consist of pigments bound into solid form by a resin. Inhalation of pastel dusts is the major hazard. Some pastels are dustier than others. Pastels can contain toxic pigments such as chromexe "Chrome" yellow (leadxe "Lead Hazards" chromatexe "Chromate Hazards") which can cause lung cancerxe "Cancer", and cadmiumxe "Cadmium" pigments (which can cause kidneyxe "Kidney Hazards" and lung damage and are suspect human carcinogensxe "Carcinogens"). Blowing excess pastel dust off the drawing is one major source of inhalationxe "Inhalation Hazards" of pastel pigments. Pastel artists have often complained of blowing their nose different colors for days after using pastels, a clear indication of inhalationxe "Inhalation Hazards". Crayons and oil pastels do not present an inhalationxe "Inhalation Hazards" hazard, and thus are much safer than pastels. Some oil pastels can contain toxic pigments, but this is only a hazard by accidental ingestionxe "Ingestion Hazards". Both permanent and workable spray fixatives used to fix drawings contain toxic solvents. There is high exposure by inhalationxe "Inhalation Hazards" to these solvents because the products are sprayed in the air, often right on a desk or easel. In addition you can be inhaling the plastic particulates that comprise the fixative itself. Spraying fixative by blowing air from your mouth through a tube can leadxe "Lead Hazards" to accidental ingestionxe "Ingestion Hazards" of the fixative. Precautions Use the least dusty types of pastels, chalks, etc. Asthmatics in particular might want to switch to oil pastels or similar non-dusty media. Spray fixatives should be used in a spray booth that exhausts organic vapors and particulates to the outside. Dont blow off excess pastel or charcoal dust with your mouth. Instead tap off the built up dust so it falls to a plastic lined trash can. Wet-mop and wet-wipe all surfaces clean of dusts. Liquid Drawing Mediaxe "Drawing Hazards - Liquid Drawing Media" This includes both water-based and solvent-based pen and ink and felt tip markers. Hazards of dry erase or white board markers can also be considered here, although they are more used in teaching or commercial art. Hazards Drawing inks are usually water-based, but there are some solvent-based drawing inks. These usually contain toxic solvents like xylenexe "Xylene". Permanent felt tip markers used in design or graphic arts contain solvents. Xylene, which is a toxic aromatic hydrocarbon, is the most common ingredient; newer brands often contain the less toxic propyl alcohol (although it is an eyexe "Eye Safety", nose and throat irritant). The major hazard from using permanent markers results from using a number of them at the same time at close proximity. Water-based markers do not have an inhalationxe "Inhalation Hazards" hazard although there is concern about the dyes used in these (and the permanent markers). Precautions Use water-based markers and drawing inks if possible. Alcohol-based markers are less toxic than solvent-based markers. Solvent-based drawing inks and permanent markers should be used with good dilution ventilationxe "Ventilation". Never paint on the body with markers or drawing inks. Body painting should be done with cosmetic colors. Sculpture Hazardsxe "Sculpture Hazards" Introduction Many artists work with traditional sculptural materials including plaster, stone, lapidary, clay, wax and modeling materials. This section will provide hazards and safety information for certain traditional processes. Plasterxe "Plaster Hazards" Plaster can be carved, modeled, and casted. Varieties of plaster include: Plaster of Paris, casting plaster, white art plaster, molding plaster and Hydrocal. These are all varieties of calcined gypsum, composed of calcium sulfate. Plaster is mixed by sifting the plaster powder into water. Sometimes salt, potassium sulfate or potassium alum is added to speed setting; or borax, diluted acetic acidxe "Acetic Acid" or burnt lime is added to retard the setting. Silicaxe "Silica - Safety Hazards" sand, vermiculite, sand and coarse stone can be added to the plaster for textural effects. Wet or dry plaster is carved and modeled with special plaster carving chisels, knives, rasps, scrapers and other tools. Hazards Plaster dust (calcium sulfate) is slightly irritating to the eyesxe "Eye Safety" and respiratory system. In situations where there is heavy inhalationxe "Inhalation Hazards" of the dust, more severe respiratory problems can result. Potassium sulfate and potassium alum are slightly toxic by ingestionxe "Ingestion Hazards". Potassium alum is slightly toxic by skinxe "Skin Hazards" contact, and can cause mild irritation or allergies in some people. Borax is moderately toxic by ingestionxe "Ingestion Hazards", inhalationxe "Inhalation Hazards" and absorptionxe "Absorption Hazards" through burns or other skinxe "Skin Hazards" injuries. It is also slightly toxic by skinxe "Skin Hazards" contact, causing alkali burns. Concentrated acetic acidxe "Acetic Acid" is highly corrosivexe "Corrosives" by ingestionxe "Ingestion Hazards", inhalationxe "Inhalation Hazards" and skinxe "Skin Hazards" contact. Burnt lime (calcium oxide) is moderately corrosivexe "Corrosives" by skinxe "Skin Hazards" contact (especially if the skinxe "Skin Hazards" is wet) and highly toxic by inhalationxe "Inhalation Hazards" or ingestionxe "Ingestion Hazards". Many of the additives used may be hazardous. Silicaxe "Silica - Safety Hazards" and vermiculite dusts are toxic by inhalationxe "Inhalation Hazards" and may cause silicosisxe "Silicosis". Small amounts are not a major hazard. Careless use and storage of sharp tools can cause accidents. Chipping set plaster can result in eyexe "Eye Safety" injuries from flying chips. Precautions For mixing large amounts of plaster at one time, capture ventilationxe "Ventilation" is required. HEPAxe "HEPA Vacuums" vacuum and wet mop or wipe plaster dust carefully; do dry not sweep. Wear gloves and goggles when mixing acetic acidxe "Acetic Acid" and burnt lime. For large amounts of burnt lime, use capture ventilationxe "Ventilation". When adding hazardous materials to plaster, use capture ventilationxe "Ventilation" and clean up dust carefully by wet mopping and wiping and/or HEPAxe "HEPA Vacuums" vacuuming. Always carve or cut in a direction away from you and keep hands behind the tool. If the tool falls, dont try to catch it. Wear ANSIxe "ANSI"-approved safety goggles when chipping plaster. Store plaster in sealed containers or plastic sealed bags rather than paper bags, which can rip. Plaster Moldsxe "Plaster Molds" Mold releases used with plaster include vaseline, tincture of green soap, auto paste wax-benzine, silicone-grease-Solvent, and mineral oil-petroleum jelly. In waste molding, the plaster mold is chipped away. Hazards Solvents used with many mold releases are moderately toxic by skinxe "Skin Hazards" contact and inhalationxe "Inhalation Hazards" and are highly toxic by ingestionxe "Ingestion Hazards". They are also flammable. Making plaster casts of hands, legs and other body parts can be hazardous due to the heat released during the setting process. Many children and adults have been severely burned doing this. Precautions Wear gloves and goggles when pouring solvents. Store in safety containers and do not use near open flames or cigarettes. Do not use plaster for body part casts. Instead, use a plaster-impregnated bandage (such as Johnson and Johnsons Pariscraft), along with vaseline or similar mold release as protection. Plaster Finishingxe "Plaster Finishing" Plaster can be finished in many ways. It can be painted with paint or powdered pigments, or dyes can be added directly to the plaster mix. Patinas are made by sealing the plaster with shellac or acrylic sprays. They can also be made with a 50/50 mixture of water and white glue, with water-based glue mixed with a 50/50 mixture of lacquer and alcohol or with bronzing liquids. Hazards Powdered pigments and dyes are often hazardous by inhalationxe "Inhalation Hazards" or ingestionxe "Ingestion Hazards" and in some cases by skinxe "Skin Hazards" contact. Lacquers contain solvents that are toxic by inhalationxe "Inhalation Hazards" and moderately toxic by skinxe "Skin Hazards" contact. Alcohol and shellac are slightly toxic unless the shellac contains moderately toxic methyl alcoholxe "Methyl Alcohol". These solvents are also flammable. Precautions Work in an exhaust hood when using powdered pigments or dyes. Brush or dip dyes or paints rather than spraying. When using solvents, have good general ventilationxe "Ventilation" and wear gloves and goggles. Store solvents safely, and keep them away from open flames; dispose of solvent-soaked rags in approved waste disposal cans. Stones and Lapidaryxe "Stones and Lapidary" Stone carving involves chipping, scraping, fracturing, flaking, crushing and pulverizing with a wide variety of tools. Soft stones can be worked with manual tools whereas hard stones require crushing and pulverizing with electric and pneumatic tools. Crushed stone can also be used in casting procedures. Soft Stonesxe "Soft Stones" Soft stones include soapstone (steatite), serpentine, sandstone, African wonderstone, greenstone, sandstone, limestone, alabaster and several others. Hard Stonesxe "Hard Stones" Hard stones include granite and marble. Electric tools include saws, drills, grinders, and sanders. and Pneumatic tools include rotohammers, drills and other tools powered by compressed air. Casting Stonesxe "Casting Stones" Stone casts can be made using Portland cement, sand and crushed stone. Marble dust is often used with this technique. Cast concrete sculptures can also be made using sand and Portland cement. The most common mold is plaster with stearic acid/benzine as the mold release. Portland cement contains calcium, aluminum, iron and magnesium oxides and about 5% free silicaxe "Silica Hazards". Some modern cements have acrylic resins in them to give stronger bonding. Sometimes fiberglass is added as reinforcement. Hazards Sandstone, soapstone and granite are hazardous by inhalationxe "Inhalation Hazards" because they contain large amounts of free silicaxe "Silica Hazards". Limestone, containing small amounts of free silicaxe "Silica Hazards", is less hazardous. Serpentine, soapstone and greenstone may contain asbestosxe "Asbestos", which can cause asbestosis, lung cancerxe "Cancer", and mesothelioma. During chipping and other carving, flying chips and pieces of rock may cause eyexe "Eye Safety" injury. Grinding and sanding can release small pieces of stone and dust, which are hazardous to the. Lifting heavy pieces of stone may cause backxe "Back Safety" and shoulder injuries. Power tools create larger amounts of fine dust than hand tools. Pneumatic tools can create large amounts of fine silicaxe "Silica Hazards" dust. Pneumatic and electric tools and compressors can create a noise hazardxe "Noise Hazards". Temporary hearing lossxe "Hearing Loss" can become permanent with chronic exposure and noise can also adversely affect the heart, circulation, blood pressure, intestines and balance. Vibrationxe "Vibration Hazards" from pneumatic equipment can cause Raynauds phenomenon, (white fingers or dead fingers) a circulatory disease. The hazard is greater when the vibration exposure is combined with exposure to cold, (e.g. the air blast from pneumatic tools). This temporary condition can spread to the whole hand and cause permanent damage. Electrical tools create the potential hazard of electrical shockxe "Shock - Electric" from improperly grounded or faulty wiring. Calcium oxide in Portland cement is highly corrosivexe "Corrosives" to the eyesxe "Eye Safety" and respiratory tract and is moderately corrosivexe "Corrosives" to the skinxe "Skin Hazards". Allergic dermatitis can also occur due to chromium contaminants in the cement. The silicaxe "Silica Hazards" in the cement is also highly toxic by inhalationxe "Inhalation Hazards". Lung problems from inhalationxe "Inhalation Hazards" of Portland cement include emphysema, bronchitisxe "Bronchitis" and fibrosis. Acrylic resins are skinxe "Skin Hazards" irritants and sensitizers. Precautions Do not use varieties of stones, which may contain asbestosxe "Asbestos" unless you are certain that your particular pieces are asbestosxe "Asbestos" free. New York soapstones may contain asbestosxe "Asbestos", whereas Vermont soapstones are usually asbestosxe "Asbestos" free. Alabaster is a substitute. Techniques to keep down dust levels in the air include daily HEPAxe "HEPA Vacuums" vacuuming or wet mopping, and use of a water spray over your sculpture when you are carving. Do not dry sweep. Wear chipping goggles to protect against flying particles; wear protective shoes to protect against falling stones. Wear approved safety goggles when grinding, sanding, or polishing. For heavy grinding also wear a face shield. Change clothes and shower after work so as not to track the dust home. Wash your clothes regularly. When using carving tools, keep your hands behind the tools, and carve or cut in a direction away from you. Dont try to catch falling tools. Use proper lifting techniques (bent knees). Pneumatic and electric carving tools should be equipped with portable exhaust systems. All electric tools should be properly grounded and in good repair. Install ground fault circuit interrupters if machines are within 6 feet of water that can splash. Isolate the compressor far away and shield with sound-absorbing materials. Wear ear protectionxe "Ear Protection" if necessary and always when using pneumatic tools to carve stone. Protect against vibration damage from pneumatic tools by measures such as having comfortable hand grips, directing the air blast away from your hands, keeping hands warm, taking frequent work breaks and using preventive medical measures such as massage and exercises. Tie long hairxe "Long Hair Hazards" backxe "Back Safety", and dont wear ties, jewelry, or loose clothingxe "Loose Clothing Hazards", which can get caught by machinery. Equip all grinding wheels, sanding machines, and polishing wheels with local exhaust ventilationxe "Ventilation" and use wet sanding and polishing techniques whenever possible to keep down dust levels. Lapidaryxe "Lapidary" Lapidary involves cutting and carving semiprecious stones and has similar risks as hard stone carving. Stones carved include garnet, jasper, jade, agate, travertine, opal, turquoise and many others. Hazards See stone hazards above. The dust from quartz gemstones such as agate, amethyst, onyx, and jasper is highly toxic because they are made of silicaxe "Silica Hazards". Other gemstones such as turquoise and garnet may be contaminated with substantial amounts of free silicaxe "Silica Hazards". Opal is made of amorphous silicaxe "Silica Hazards", which is slightly toxic by inhalationxe "Inhalation Hazards". Gem cutting machines can create very high noise levels. Precautions See stone precautions above. Use adequate local exhaust ventilationxe "Ventilation", for sanding, grinding, or polishing operations that create dust. Use wet grinding processes and hearing protection. Finishing Stonexe "Stone Finishing"xe "Finishing Stone" Stones can be finished by grinding, sanding, and polishing, either by hand or with machines. Polishing can use a variety of materials, depending on the hardness of the stone being polished. Polishing materials include carborundum (silicon carbide), corundum (alumina), diamond dust, pumice, putty powder (tin oxide), rouge (iron oxide), tripoli (silicaxe "Silica Hazards") and cerium oxide. Hazards Grinding and sanding, especially with machines can create fine dust from the stone which is being worked. There are also inhalationxe "Inhalation Hazards" hazards from grinding wheel dust (especially sandstone wheels). Some polishing materials such as tripoli are highly toxic if inhaled in powder form. Precautions In the absence of adequate local exhaust ventilationxe "Ventilation", wear NIOSH-approved toxic dust respiratorxe "Respirators" for sanding, grinding, or polishing operations that create dust. The use of respirators may require annual fit testing/training and medial surveillance. Waxxe "Wax - Sculpture Hazards" Many different types of waxes are used for modeling, carving and casting. These include beeswax, ceresin, carnauba, tallow, paraffin and micro-crystalline wax. In addition there are the synthetic chlorinated waxes. Solvents used to dissolve various waxes include alcohol, acetonexe "Acetone", turpentinexe "Turpentine" and ether. Waxes are often softened for carving or modeling by heating in a double boiler or with a light bulb, by sculpting with tools warmed over an alcohol lamp, or by the use of soldering irons, alcohol lamps and blowpipes. Wax can be melted for casting in a double boiler. Additives used with waxes include rosinxe "Rosin", dyes, petroleum jelly, mineral oil and many solvents. Hazards Overheating wax can result in the release of flammable wax vapors. The decomposition of wax releases acrolein fumes and other decomposition products, which are highly irritating by inhalationxe "Inhalation Hazards". Explosions have occurred from heating wax that contained water. Alcohol and acetonexe "Acetone" are slightly toxic solvents by skinxe "Skin Hazards" contact and inhalationxe "Inhalation Hazards". Turpentine is moderately toxic by skinxe "Skin Hazards" contact, inhalationxe "Inhalation Hazards" and ingestionxe "Ingestion Hazards". Chlorinated synthetic waxes are toxic by skinxe "Skin Hazards" contact and skinxe "Skin Hazards" absorptionxe "Absorption Hazards". Precautions Do not overheat waxes. Use a double boiler and a temperature-controlled hot plate or a crock-pot. Do not use an open flame to melt waxes. Use the least hazardous solvent to dissolve your wax. Dispose of solvent-soaked rags in an approved waste disposal container. Do not use chlorinated synthetic waxes. Metal Jewelryxe "Jewelry Making Hazards"xe "Metal Jewelry" This section discusses the health and safety hazards involved in metal jewelry, including silver soldering, soft soldering, lost wax casting, electroforming, electroplating, anodizing, surface design and finishing. Solderingxe "Soldering" Soldering utilizes hot molten metals to join metal parts. The metals are coated with a flux to prevent the buildup of metal oxides on the surface. Soldering can be divided into hard soldering (silver or gold soldering) or brazing with a filler metal having a melting point in the range of 600o F to 1400o F (316o C to 760o C) and soft soldering with a filler metal having a melting point below 600o F (316o C). The solder can be made of many varying combinations of metals creating filler materials with different melting points. Silver Solderingxe "Soldering - Silver"xe "Silver Soldering" Silver solders are commonly used with gold and silver. The lowest melting silver or brazing solders typically contain the metal cadmiumxe "Cadmium" to lower the melting point of the solder, in addition to silver. Many manufacturers now produce low melting silver solders that do not contain cadmiumxe "Cadmium", and higher melting silver solders (hard, medium, easy) do not contain cadmiumxe "Cadmium". Fluxesxe "Soldering Flux Hazards" used with silver soldering often contain fluorides (e.g. potassium bifluoride or fluoroborate). Typically a torch is used with silver soldering. Pickling is the process of removing flux and oxide from the surface of the gold or silver. The pickling solution is either a solution of sulfuric acid or nitric acidxe "Nitric Acid" in water or the commercially prepared Sparexxe "Sparex" (sodium bisulfate). Hazards High, airborne concentrations of metal fumes, including cadmiumxe "Cadmium", can be expected with silver soldering. Cadmiumxe "Cadmium Hazards"-containing fume is extremely toxic, and acute overexposure can cause chemical pneumonia and be fatal. Chronic exposure can cause lung tissue damage, kidneyxe "Kidney Hazards" damage, lung cancerxe "Cancer" and prostate cancerxe "Cancer". Cadmiumxe "Cadmium Hazards" fume has poor warning properties and excessive exposure will occur before symptoms are noted. The fumes of other metals found in silver solders including antimony (as a cadmiumxe "Cadmium" replacement) are also toxic. Fluxesxe "Soldering Flux Hazards" used in silver soldering can also create toxic fumes, especially fluoridexe "Fluoride Hazards"-containing fluxesxe "Fluxes - Soldering". Possible decomposition products are hydrogen fluoridexe "Fluoride Hazards" gas and fluoridexe "Fluoride Hazards" fume. These materials are very toxic and highly irritating to the skinxe "Skin Hazards", eyesxe "Eye Safety" and respiratory tract. Pickling baths are all corrosivexe "Corrosives" because they are acidic. Concentrated acid solutions can cause severe burns to the skinxe "Skin Hazards" or eyesxe "Eye Safety". Gold or silver that has just been heated during the soldering process may cause splashes when put directly into a pickling bath. These acids can react violently with alkaline or basic compounds. Sparexxe "Sparex" is less hazardous since you are not working with concentrated acids, but the pickling bath is still acidic and can cause skinxe "Skin Hazards" burns, especially when hot. The sulfur oxide gases that can result from heating the pickling bath are respiratory irritants. Asthmatics may particularly be at risk. Propane tanks or other sources of liquefied gases for torches are highly flammable and explosive. Precautions Eliminate the use of cadmiumxe "Cadmium"-based solders. Use higher melting silver solders, or the new lower melting cadmiumxe "Cadmium"-free silver solders. Do not use fluoridexe "Fluoride Hazards"-based fluxesxe "Fluxes - Soldering". Use borax fluxesxe "Fluxes - Soldering" instead. All soldering should be done with local exhaust ventilationxe "Ventilation" (e.g. slot hood or window exhaust fan at work level 1-2 feet away). When soldering with a torch, wear protective goggles with a shade number of at least 4 to protect against infrared radiation. They should be approved by the American National Standards Institute (ANSIxe "ANSI"). Full-face shields are also available to protect the face. Use leather protective gloves to handle hot metals. Do not purchase concentrated pickling solutions, which must then be diluted with water. To avoid concentrated acids, purchase pickling solutions in dilute form, or use Sparexxe "Sparex". The pickling bath should also be vented to the outside. Keep the bath covered. Wear gloves, ANSIxe "ANSI"-approved chemical splash goggles, and protective apron when using pickling baths. If acid is splashed on skinxe "Skin Hazards", rinse with water; in case of eyesxe "Eye Safety", rinse for 15 minutes. An eyewash fountain connected to the plumbing should be available. If concentrated acids are used, always add the acid to the water when mixing, never the reverse. An emergency shower should be readily accessible in case of splashes of concentrated acid on the body. Frequently wet mop, wet wipe and/or HEPAxe "HEPA Vacuums" vacuum all work surfaces and floor to remove toxic dusts. Take precautions against fire and explosion when handling liquefied gas cylinders. Chain them securely, away from other flammable materials and away from sources of ignition. Do not use near flammable materials. Follow manufacturers instructions. Soft Solderingxe "Soft Soldering" Soft solders are sometimes used when making jewelry out of non-precious metals. Soft solder is commonly a mixture of 50/50 or 60/40 leadxe "Lead Hazards" and tin and is usually used with an electric soldering iron. Low-leadxe "Lead Hazards" and leadless soft solders are now available. Some of these substitutes contain antimony. Soft solder fluxesxe "Fluxes - Soldering" typically consist of an acid type, zincxe "Zinc" chloride, an alcohol rosinxe "Rosin" type or an organic non-rosinxe "Rosin" base. Hazards Because of the low melting temperatures of soft solders and the low temperature of the soldering iron, soft soldering does not usually result in significant airborne concentrations of metal fume unless a person is directly breathing in the soldering plume that is created. However, leadxe "Lead Hazards" dust collecting on work surfaces from settled soldering fumes can be a hazard due to the high toxicity of leadxe "Lead Hazards". Ingestion or inhalationxe "Inhalation Hazards" of leadxe "Lead Hazards" fume and dust can cause neurological problems, anemiaxe "Anemia", kidneyxe "Kidney Hazards" damage, reproductivexe "Reproductive Hazards" system damage, miscarriages and birth defectsxe "Birth Defects". Antimonyxe "Antimony Hazards" is also highly toxic, but is considered less of a hazard than leadxe "Lead Hazards". When fluxesxe "Fluxes - Soldering" are heated during the soldering operation, fumes and mist can be generated. The zincxe "Zinc" chloride fumes have acidic properties and may cause chronic bronchitisxe "Bronchitis". Zinc oxide fumes are also generated and may cause metal fume fever if there is sufficient exposure. The alcohol rosinxe "Rosin" type flux is flammable and should not be stored near open flames. The fumes from the rosinxe "Rosin" and non-rosinxe "Rosin" based fluxesxe "Fluxes - Soldering" can also be irritating to the lungs and prolonged exposure may cause respiratory damage. Rosinxe "Rosin Hazards" fumes may cause asthma. Precautions Use leadxe "Lead Hazards"-free and antimony-free soft solders and non-acid fluxesxe "Fluxes - Soldering" whenever possible. Flammable alcohol or solvent-based fluxesxe "Fluxes - Soldering" should be stored away from heat or open flames. All soldering should be done with local exhaust ventilationxe "Ventilation" (e.g. slot hood or window exhaust fan at work level 1-2 feet away). Wear protective gloves, protective apron and chemical splash eyexe "Eye Safety" goggles when handling fluxesxe "Fluxes - Soldering". Frequently wet mop or wet wipe and/or HEPAxe "HEPA Vacuums" vacuum all work surfaces and floor to remove toxic dusts. Do not eat, drink or smoke in the studio. Wash hands carefully after work and before eating, drinking, smoking, etc. Lost Wax Castingxe "Lost Wax Casting" Lost wax casting is a process by which a model is made from wax and a mold is cast around it. The molds are typically a casting plaster, which most often contains cristobalitexe "Cristobalite Hazards" and other additives. The casting process usually involves heat in the mold in a container in an oven. After the mold has set, the wax model is heated and burned off leaving the cast. The metal is commonly melted with a torch. Usually, centrifugal casters are used to pour the molten metal into the mold, rather than gravity pouring. Vacuum casting systems are also used. After the metal has cooled, the mold is removed from the jewelry. Hazards The materials used to make up the plaster molds often contain cristobalitexe "Cristobalite Hazards", a highly toxic form of free crystalline silicaxe "Silica Hazards". Inhalation of crystalline silicaxe "Silica Hazards" can cause silicosisxe "Silicosis", a serious lung diseasexe "Lung Disease Hazards" that results in scarring of lung tissue. Silicosis usually takes 10-20 years before symptoms appear. Burning wax can cause burns or a fire and produces fumes from incomplete combustion. Some of these fumes are highly irritating to the respiratory tract. Fumes of gold or silver are not known to be toxic, although silver fumes may cause a skinxe "Skin Hazards" and internal organ discoloration called argyria. However, other metals alloyed with gold or silver may be toxic. Such metals include zincxe "Zinc", copper, nickel or leadxe "Lead Hazards". Exposure to zincxe "Zinc" fumes may cause metal fume fever. All airborne nickel compounds are regarded as carcinogenic by inhalationxe "Inhalation Hazards". Leadxe "Lead Hazards" fumes are also highly toxic. The containers used to heat molds may be insulated with asbestosxe "Asbestos". Heat-resistant gloves used for handling hot objects were also frequently made out of asbestosxe "Asbestos". Some soldering and pounding boards have previously been formed out of asbestosxe "Asbestos"-containing materials. The use of asbestosxe "Asbestos" in these materials has been discontinued. Asbestos can cause lung cancerxe "Cancer", mesothelioma (cancerxe "Cancer" of the lining of the chest cavity) and asbestosis which results in scarring of the lung tissue. Cases of mesothelioma have been found in jewelers. Precautions Use metal alloys that do not contain leadxe "Lead Hazards" or nickel. Replace equipment that is insulated with asbestosxe "Asbestos", especially when the insulation is exposed or damaged. Damaged or exposed insulation and other products may release airborne asbestosxe "Asbestos" fibers, which can then be inhaled. Removal of asbestosxe "Asbestos" must be done by a licensed asbestosxe "Asbestos" contractor or the Office of Physical who also has licensed asbestosxe "Asbestos" workers. Use a non-silicaxe "Silica Hazards" investment plaster, when possible. If a silicaxe "Silica Hazards"-type material is used, mix the investment in a capture Hood. Clean up all debris immediately. Use wet cleaningxe "Clean Up - Wet Cleaning Requirements" methods to control any dusts, or use a vacuum cleaner with a high efficiency (HEPAxe "HEPA Vacuums") filter. Do not dry sweep, which stirs up dust. When melting metals, especially if zincxe "Zinc" is contained in the alloy, use a slot hood or window exhaust fan at work level 1-2 feet away. Paraffin waxxe "Paraffin wax" readily burns. Always store paraffin wax in a cool place away from all ignition sources. Wear clothing and gloves that will protect against burns when handling molten metals. Protective goggles should protect against impact and infrared radiation (shade number at least 4), and should be ANSIxe "ANSI"-approved. When removing the mold work inside a capture hood. Electroplating and Electroformingxe "Electroplating and Electroforming" Electroplating is a process whereby a light buildup of pure metal from an anode occurs on the surface of a metal object to be plated at the cathode. These two electrodes are powered by a low voltage power supply. Electroforming is the same process but involves a heavy buildup of the metal and much higher voltages. Both these processes take place in a plating solution. The plating solution contains an electrolyte consisting of a metal salt of the metal to be applied dissolved in water. The plating solution may also contain other salts, additives and buffers. The common plating metals include copper, gold, nickel, silver and their alloys. Copper plating can be done with copper sulfate and sulfuric acid as the electrolyte; many other plating metals, especially gold and silver, use cyanidexe "Cyanide Hazards" salts as the electrolyte. There are non-cyanidexe "Cyanide Hazards" silver succinimide and gold sulfite electroplating solutions, but at present they have not been used much by artists. Prior to electroplating, the surface of the metal must be cleaned, often with caustic soda. Hazards Gold and silver cyanidexe "Cyanide Hazards" solutions are extremely toxic by ingestionxe "Ingestion Hazards". If metal cyanidexe "Cyanide Hazards" solutions come in contact with an acid, the extremely toxic and poisonous gas, hydrogen cyanidexe "Cyanide Hazards", is released. This also applies to many of the so-called cyanidexe "Cyanide Hazards"-free substitutes, which often contain cyanidexe "Cyanide Hazards" complexes, which also react with acid to release hydrogen cyanidexe "Cyanide Hazards" gas. The electroplating process can produce a mist, which contains cyanidexe "Cyanide Hazards" salts. Gold salts used in electroplating can occasionally cause skinxe "Skin Hazards" sensitization and resulting allergicxe "Allergic Reactions" reactions. The electrolyte usually used in copper plating is copper sulfate in sulfuric acid. Concentrated sulfuric acid is a corrosivexe "Corrosives" material and can cause burns or irritation to the eyesxe "Eye Safety", skinxe "Skin Hazards" or respiratory tract. Electroforming processes often use high electrical currents, and have the potential to cause electrical shocks. Precautions Avoid cyanidexe "Cyanide Hazards" electroplating or electroforming if at all possible by sending the piece out to be electroplated commercially. Only do plating with cyanidexe "Cyanide Hazards" solutions if you are willing to take extremely careful precautions. Electroplating and electroforming with cyanidexe "Cyanide Hazards" plating solutions should only be done in a tested laboratory hood. Other types of electroplating also need local exhaust ventilationxe "Ventilation". Electroplating involves the use of incompatible and reactive materials. Cyanide solutions are incompatible with acids. Cyanide solutions and acids must never be stored near each other. Find out what materials used in the area are acids and separate these from the cyanidexe "Cyanide Hazards" baths. Under no circumstances should the copper plating bath come in contact with the silver or gold baths. Store acids in a separate cabinet of non-metal construction away from all other chemicals. Wear protective gloves, goggles and apron when handling electroplating solutions and concentrated acids. If an acid should come into contact with a cyanidexe "Cyanide Hazards" bath, immediately evacuate the area and seek medical attention. The workspace should have an emergency eyewash and an available source of copious, clean tap water to wash chemicals from the skinxe "Skin Hazards". A shower is recommended. Install a ground fault circuit interrupter. Make sure all electrical wiring is in good condition, and that all special equipment (rectifiers, masking tape for resists, etc.) are approved for the voltages and currents used. Install your electroplating unit on a wooden or nonconducting surface, not on metal. Place a heavy rubber mat on the floor where you would stand. Do not use a metal chair. Wear rubber-soled shoes and insulating rubber gloves. Do not touch electroplating bath, wires or electrodes with bare hands while the current is on to avoid shock. Unplug the power supply before making or undoing connections or making adjustments to the bath. Spent cyanidexe "Cyanide Hazards" solutions must not be poured down the sink. They should be stored in a plastic container and disposed of by Environmental Health and Safetyxe "Environmental Health and Safety" (see waste disposal guidelines). Anodizingxe "Anodizing" Anodizing involves the oxidation of metals such as titanium at the anode of an electrolytic bath, usually using trisodium phosphate as an electrolyte. Water is dissociated, producing hydrogen at the cathode and oxygen at the anode. The oxygen causes a controlled surface oxidation of the anode. Anodizing can be done in an anodic bath, or with anodic painting, where you paint on the anode metal using a paintbrush soldered to the cathode leadxe "Lead Hazards". The titanium must be cleaned before anodizing, often with hydrofluoricxe "Hydrofluoric Acid" acid. Hazards Titanium is a combustible metal like magnesium. Titanium filings and dust will burn. Trisodium phosphatexe "Trisodium Phosphate Hazards" is alkaline and can cause skinxe "Skin Hazards", eyexe "Eye Safety" and respiratory irritation. Hydrofluoric acidxe "Hydrofluoric Acid" is highly corrosivexe "Corrosives" to the skinxe "Skin Hazards", eyesxe "Eye Safety", and lungs. Serious, deep burns can occur without pain warning several hours after exposure. Its vapors may cause severe lung irritation, including chemical pneumonia. Ingestion can be fatal. Hydrofluoric acidxe "Hydrofluoric Acid Hazards" can also cause chronic bone and teeth damage (osteofluorosis), and possibly kidneyxe "Kidney Hazards" damage. Handling concentrated hydrofluoricxe "Hydrofluoric Acid" acid is very dangerous due to the risk of splashes. Anodizing, like electroplating, can involve large electrical currents, which create the hazard of electrical shockxe "Shock - Electric".xe "Electrical Shock. Hazards" Precautions Wear insulating rubber gloves, goggles, and protective apron. Avoid hydrofluoricxe "Hydrofluoric Acid" acid if possible. Instead, wet sand with a very fine grade of emery paper. If hydrofluoricxe "Hydrofluoric Acid" acid is used, do so only in a chemical fume hood. Wear natural or neoprene rubber gloves, protective apron, face shield, and chemical splash goggles when handling concentrated hydrofluoricxe "Hydrofluoric Acid" acid. In case of contact, flush exposed skinxe "Skin Hazards" and eyesxe "Eye Safety" with water for at least 15 minutes. Immerse affected area in 0.13% iced solution of Zephiranxe "Hydrofluoric Acid Burns - Treatment"xe "Zephiran" chloride for 30-60 minutes. Call a physician immediately. Leftover hydrofluoricxe "Hydrofluoric Acid" acid should be handled as hazardous waste. Keep a Class D fire extinguisherxe "Fire Extinguishers - Class D" for potential titanium fires. See Electroplating section above for electrical precautions. Surface Working, Polishing and Finishingxe "Metal Surface Working, Polishing and Finishing" Metals are usually annealed by heating before hammering or chasing. Finishing operations can include sandblasting, polishing, grinding and application of patinas. Hazards Most metals are annealed before hammering or shaping using repoussxe "Infrared Radiation Hazards - Repouss"xe "Repouss". This involves heating the metals to red hot temperatures, creating infrared radiation. Infrared radiationxe "Infrared Radiation Hazards" can damage the eyesxe "Eye Safety". Burns are another potential safety hazard. In repoussxe "Repouss" or chasing, the metal is usually placed into a bowl of pitch before hammering or shaping. The pitch is then burned off using a torch. Pitch is a recognized skinxe "Skin Hazards" carcinogenxe "Carcinogens" and contains hydrocarbons, which are a fire hazard when heated with a torch. The potential for pieces of metal becoming projectiles should be considered when cutting, hammering or engraving. Cleaning of metal surfaces is often done using sandblasting or abrasive blasting. This involves using compressed air to project particles of sand or other materials at the metal and abrading the surface. Sand contains free crystalline silicaxe "Silica Hazards" and its use in sand blasting has caused silicosisxe "Silicosis" within a few years. When using a grinding wheel, there is always the potential for pieces of the metal or the wheel to be projected at the worker. Always maintain the guards on a grinding wheel. Many polishing compounds contain free silicaxe "Silica Hazards" as a main ingredient or as a contaminant. Examples are tripoli and, sometimes, rouge. A variety of toxic chemicals can be used as patinas to color the metal. These can be applied hot or cold. In particular, applying patina chemicals to hot metals can result in the release of hazardous decomposition products (e.g. hydrogen cyanidexe "Cyanide Hazards" from decomposition of potassium ferricyanide). Precautions Do not use sand for abrasive blasting. Instead use glass beads, crushed walnut shells, alumina, or silicon carbide. Abrasive blasting booths should be properly ventilated. Grinding wheels should have eyeshields. For occasional grinding wear a NIOSH-approved toxic dust respiratorxe "Respirators"; for frequent grinding, equip the grinder with a dust collection system. Use ANSIxe "ANSI"-approved safety goggles, or face shields plus safety goggles when grinding or working metal surfaces. Do not wear ties, loose long sleevesxe "Long Sleeve Hazards", necklaces or other dangling jewelry, or anything which could get caught in the grinders or buffers. Keep long hairxe "Long Hair Hazards" tied backxe "Back Safety" or wear a hair net. Use wet techniques whenever possible to keep down dust levels. Wear gloves and goggles when preparing and using patinas. Highly toxic powders should be mixed in a hood, with exhaust ventilationxe "Ventilation". Dip or brush on patinas, rather than spraying them, whenever possible. Spraying should only be done in a spray booth. Use local exhaust ventilationxe "Ventilation" for applying patinas, especially hot, or when burning off pitch (e.g. slot hood or window exhaust fan at work level 1-2 feet away.) Lithography, Intaglio and Relief Printing Hazardsxe "Lithography, Intaglio and Relief Printing Hazards" This section will introduce both hazards and safety precautions recommended for printmaking. There are many different printmaking processes, including lithography, relief printing, and intaglio. Inksxe "Ink Hazards - Lithography and Printing" Intaglio, lithography and relief inks consist of pigments suspended in either linseed oil or water as a vehicle. There can be additional hazardous binders or preservatives, etc. Hazards Oil-based inks contain treated linseed oilsxe "Linseed Oil Hazards". While linseed oil is not considered a hazard by skinxe "Skin Hazards" contact or inhalationxe "Inhalation Hazards", ingestionxe "Ingestion Hazards" of large amounts of some treated linseed oilsxe "Linseed Oil Hazards" might be hazardous due to presence of small amounts of toxic heavy metals. Oil vehicles are flammable when heated, and rags soaked in these may ignite by spontaneous combustion. Precautions Know what materials are used. Obtain the MSDSs on all products used. Use the least toxic inks possible. Do not use an open flame to heat linseed oil, linseed oil varnishes, or burnt plate oil. Take normal fire prevention measures (e.g. no smoking or open flames in work area). Place oil-soaked ragsxe "Oil-Soaked Rag Hazards" in self-closing disposal cans and remove from the studio each day. An alternative is to place the oil-soaked ragsxe "Oil-Soaked Rag Hazards" in a pail of water. Pigmentsxe "Pigment Hazards - Lithography and Priting" Pigments are the colorants used in lithography, intaglio, and relief printing inks. There are two types of pigments: inorganic pigments, and organic pigments. Hazards Pigment poisoning can occur if pigments are inhaled or ingested. For normal printing with prepared inks, the main hazard is accidental ingestionxe "Ingestion Hazards" of pigments due to eating, drinking or smoking while working, or inadvertent hand to mouth contact. The classic example of a toxic inorganic pigment in printmaking is leadxe "Lead Hazards" chromatexe "Chromate Hazards" (chromexe "Chrome" yellow). Leadxe "Lead Hazards" pigments can cause anemiaxe "Anemia", gastrointestinalxe "Gastrointestinal Hazards" problems, peripheral nervexe "Nerve Damage Hazards" damage (and brainxe "Brain Damage Hazards" damage in children), kidneyxe "Kidney Hazards" damage and reproductivexe "Reproductive Hazards" system damage. Other inorganic pigments may be hazardous also, including pigments based on cobaltxe "Cobalt", cadmiumxe "Cadmium", and manganesexe "Manganese". Some of the inorganic pigments, in particular cadmiumxe "Cadmium" pigments, chromexe "Chrome" yellow and zincxe "Zinc" yellow (zincxe "Zinc" chromatexe "Chromate Hazards") may cause lung cancerxe "Cancer" if inhaled. In addition, lamp blackxe "Lamp Black" and carbon blackxe "Carbon Black" may contain impurities that can cause skinxe "Skin Hazards" cancerxe "Cancer". Chromatexe "Chromate" pigments (chromexe "Chrome" yellow and zincxe "Zinc" yellow) may cause skinxe "Skin Hazards" ulceration and allergicxe "Allergic Reactions" skinxe "Skin Hazards" reactions. The long-term hazards of the modern synthetic organic pigments have not been well studied. Precautions Obtain MSDSs on all pigments. This is especially important because the name that appears on label of the color may or may not truly represent the pigments present. Use the safest pigments possible. Avoid leadxe "Lead Hazards" pigments. Avoid mixing dry pigments whenever possible. Never mix your own chromexe "Chrome" yellow, zincxe "Zinc" yellow, chromexe "Chrome" green, molybdate orange or any other pigments which are known human carcinogensxe "Carcinogens". If possible, do not mix highly toxic pigments such as leadxe "Lead Hazards" white or cadmiumxe "Cadmium" colors. If dry pigments require mixing, do it inside a capture hood to prevent exposure. Solvents In general, organic solvents are one of the most underrated hazards in art materials. Organic solvents are used in printmaking to dissolve and mix with oils, resins, varnishes, and inks; and to clean plates, rollers, tools, and even hands. Hazards Repeated or prolonged skinxe "Skin Hazards" contact with solvents can cause defatting of the skinxe "Skin Hazards" and resultant dermatitis (rashes, drying and cracking of skinxe "Skin Hazards", itching, etc.). Many solvents, for example turpentinexe "Turpentine", methyl alcoholxe "Methyl Alcohol", toluenexe "Toluene", and xylenexe "Xylene", can also be harmful through skinxe "Skin Hazards" absorptionxe "Absorption Hazards". Inhalation of solvent vapors is the major way in which solvents are harmful. High concentrations of most solvents can cause narcosis (dizziness, nausea, fatigue, loss of coordination, coma, etc.). This can also increase the chances for mistakes and accidents. Research during the last 10 years has indicated that chronic occupational exposure to many solvents can cause permanent brainxe "Brain Damage Hazards" damage, with symptoms including loss of memory, behavioral changes, fatigue, spasticity, decreased intelligence, slower reflexes, poor hand-eyexe "Eye Safety" coordination, etc. Most of these studies are on mixed solvents so it is difficult to implicate particular solvents. There is at least one documented case of such brainxe "Brain Damage Hazards" damage affecting a silk screen artist. Solvents can also attack other organ systems besides the nervous system. In particular, turpentinexe "Turpentine" can damage the kidneys, toluenexe "Toluene" and chlorinated hydrocarbonsxe "Chlorinated Hydrocarbons" can affect the liver, and methylene chloridexe "Methylene Chloride" can affect the heart. Many solvents are toxic if ingested. This is particularly a problem with young children swallowing solvents that have been placed in glasses or other food or drink containers, although this has also happened with adults. Swallowing 1/5 ounce of turpentinexe "Turpentine" can be fatal to a 5-year old child. Most solvents, except chlorinated hydrocarbonsxe "Chlorinated Hydrocarbons", are also either flammable or combustible. A solvent is flammable if its vapors can burn below 100o F when a source of ignition is present; if the temperature has to be over 100o F before it will burn, then the solvent is combustible. For example, ethyl alcoholxe "Ethyl Alcohol" and toluenexe "Toluene" are flammable, and kerosenexe "Kerosene" and mineral spiritsxe "Mineral Spirits" (Varsol or paint thinner) are combustible. Precautions Obtain the MSDSxe "MSDS" on all solvent products used. Use the least toxic solvent possible. For example, replace the more toxic methyl alcoholxe "Methyl Alcohol" (methyl hydrate) with denatured alcoholxe "Denatured Alcohol" or isopropyl alcoholxe "Isopropyl Alcohol". Keep minimum amounts of solvents on hand and purchase in smallest practical container size. Large amounts of solvents or solvent-containing materials should be stored in a flammable storage cabinet. Never store solvents or solvent-containing materials in food or drink containers. Always label containers. Do not allow smoking, open flames or other sources of ignition near solvents. Have a class B fire extinguisher in the area. (If ordinary combustible materials are present, you may need a Class ABC fire extinguisher). Wear gloves when handling solvents to avoid skinxe "Skin Hazards" contact In particular do not use solvents to clean ink off hands. Baby oil is a good substitute. Do not induce vomiting if petroleum distillates are swallowed. Give 1-2 glasses of water or milk and contact a regional Poison Control Center. Acidsxe "Acid Hazards - Lithography and Printing" Acids are used in intaglio (acid etching) and in lithography. Strong acids commonly used include nitric acidxe "Nitric Acid", hydrochloricxe "Hydrochloric Acid" acid, and phosphoricxe "Phosphoric Acid" acid, and less commonly carbolic acidxe "Carbolic Acid" (phenolxe "Phenol"), chromic acidxe "Chromic Acid", hydrofluoricxe "Hydrofluoric Acid" and sulfuric acidsxe "Sulfuric Acid". Hazards Concentrated acids are corrosivexe "Corrosives" to the skinxe "Skin Hazards", eyesxe "Eye Safety", respiratory system and gastrointestinalxe "Gastrointestinal Hazards" system. Dilute acids can cause skinxe "Skin Hazards" irritation on repeated or prolonged contact. Chromicxe "Chromic Acid" acid is a skinxe "Skin Hazards" sensitizer, suspect carcinogenxe "Carcinogens", and oxidizer. Phenolxe "Phenol" is highly toxic by skinxe "Skin Hazards" absorptionxe "Absorption Hazards" and ingestionxe "Ingestion Hazards". It may cause severe kidneyxe "Kidney Hazards" damage, central nervous system effects and even death if absorbed in large amounts. Hydrofluoric acidxe "Hydrofluoric Acid Hazards" is highly toxic and can cause severe, deep burns, which require medical attention. There is no immediate pain warning from contact with hydrofluoricxe "Hydrofluoric Acid" acid. Concentrated nitric acidxe "Nitric Acid" is a strong oxidizing agent and can react explosively with other concentrated acids, solvents, etc. Nitric acidxe "Nitric Acid" gives off various nitrogen oxide gases, including nitrogen dioxidexe "Nitrogen Dioxide" which is a strong lung irritant and can cause emphysema. Precautions Know what is used. Obtain the MSDSxe "MSDS" for all acids. Whenever possible avoid concentrated acids. Doing acid etching requires working in a properly ventilated area with exhaust hoods. Store concentrated nitric and chromic acids away from organic materials. Concentrated nitric acidxe "Nitric Acid" should always be stored separately even from other acids. An important safety rule when diluting concentrated acids is to add the acid to the water, never the reverse. Wear appropriate gloves, goggles and protective apron or lab coat when handling acids. An emergency shower and eyewash fountain that is not hand-held should be in studios where concentrated acids are mixed or used. Portable eyewash bottles are not recommended. If acid is spilled on your skinxe "Skin Hazards", wash with lots of water. In case of eyexe "Eye Safety" contact, rinse the eyesxe "Eye Safety" with water for at least 15-20 minutes and contact a physician. Do not induce vomiting if concentrated acids are swallowed. Give 1-2 glasses of water or milk and get medical attention. Lithographyxe "Lithography" Lithography uses either zincxe "Zinc" and aluminum metal plates or stones for printing. It involves use of a variety of chemicals to make the image ink-receptive and non-image areas receptive to water and ink-repellent. Plate and Stone Preparationxe "Plate and Stone Preparation - Lithography"xe "Lithography - Plate and Stone Preparation" A variety of drawing materials with high wax and fatty acid content are used to make the image, including tusche and lithographic crayons. Airbrushing liquid drawing materials or using spray enamel or lacquer is also common. Other materials used in stone or plate processing include etch solution containing acids and gum arabic, counteretch solutions containing acids and sometimes dichromate salts, and fountain solutions containing dichromate salts. Phenolxe "Phenol" (carbolic acidxe "Carbolic Acid") has been used for removing grease from stones, and a variety of solvents including lithotine, gasoline, kerosenexe "Kerosene", and mineral spiritsxe "Mineral Spirits", which are used for diluting drawing materials, washing out images and correction of images. Talcxe "Talc" and rosinxe "Rosin" mixtures are also used. Metal plates are prepared with solvent-based vinyl lacquers. Hazards Acids used include phosphoricxe "Phosphoric Acid", nitric, acetic, hydrochloricxe "Hydrochloric Acid", hydrofluoricxe "Hydrofluoric Acid" and tannic acidsxe "Tannic Acids". The concentrated acids are corrosivexe "Corrosives" and even dilute acid solutions can cause skinxe "Skin Hazards" irritation from prolonged or repeated contact. Hydrofluoric acidxe "Hydrofluoric Acid Hazards" and phenolxe "Phenol" are the most dangerous to use. Lithotinexe "Lithotine", kerosenexe "Kerosene", and mineral spiritsxe "Mineral Spirits" are skinxe "Skin Hazards" and eyexe "Eye Safety" irritants and inhalationxe "Inhalation Hazards" can cause intoxication and respiratory irritation. The solvents contained in vinyl lacquers can include highly toxic isophoronexe "Isophorone" and cyclohexanonexe "Cyclohexanone". Methyl ethyl ketonexe "Methyl Ethyl Ketone" (MEKxe "MEK"), which is moderately toxic, is often used as a thinner. Dichromatexe "Dichromate" salts may cause skinxe "Skin Hazards" and nasal ulceration and allergicxe "Allergic Reactions" reactions, and are suspect cancerxe "Cancer"-causing agents. Rosinxe "Rosin Hazards" dust may cause asthma and allergicxe "Allergic Reactions" dermatitis. There is the hazard of explosion from the buildup of rosinxe "Rosin" dust, in enclosed rosinxe "Rosin" boxes, around an ignition source. Talcs may be contaminated with asbestosxe "Asbestos" and silicaxe "Silica Hazards". Airbrushing drawing materials or using spray enamel paints is more hazardous than drawing with a brush because the inhalationxe "Inhalation Hazards" hazard is higher. Precautions Obtain the MSDSxe "MSDS" for all materials used. See Acids and Solvents sections for the precautions with acids and solvents. Use the least toxic solvents. Gasoline should never be used. Lithotinexe "Lithotine" and mineral spiritsxe "Mineral Spirits" are less toxic than the more irritating kerosenexe "Kerosene". Use asbestosxe "Asbestos"-free talcs such as baby powders. Avoid dichromate-containing counteretches and fountain solutions if possible. Do not use hydrofluoricxe "Hydrofluoric Acid" acid if possible. Air brushing or application of spray paints should only be done in a spray booth. Local exhaust ventilationxe "Ventilation" such as a slot hood, or window exhaust fan 1-2 feet away is needed for vinyl plate lacquers. Dilution ventilationxe "Ventilation" is adequate when working with small amounts of solvents. An emergency shower and eyewash fountain should be installed where concentrated acids are mixed and used. Appropriate gloves, goggles and a protective apron should be worn when mixing or using concentrated acids. Do not use phenolxe "Phenol". Printing and Cleanupxe "Lithography - Printing and Cleanup"xe "Printing and Cleanup - Lithography" Many art lithographic inks contain treated linseed oil as a vehicle, and are thus not solvent-based. However, some lithographers use commercial lithographic inks, which can contain some solvents, such as mineral spiritsxe "Mineral Spirits". For all types of lithographic inks, solvents are used to make image corrections on the press, to remove images, and to clean the press bed and rollers. Hazards Some roller cleaners and glaze cleaners can contain chlorinated hydrocarbonsxe "Chlorinated Hydrocarbons" such as perchloroethylenexe "Perchloroethylene" and methylene chloridexe "Methylene Chloride". Most chlorinated solvents (except 1,1,1-trichloroethane) have been shown to cause liver cancerxe "Cancer" in animals and are therefore suspect human carcinogensxe "Carcinogens". In addition perchloroethylenexe "Perchloroethylene" can cause liver damage, and methylene chloridexe "Methylene Chloride" heart attacks. Precautions Know materials used. Obtain the MSDSxe "MSDS" for all solvents. See Solvents section for the precautions with solvents. Choose products that do not contain chlorinated solvents whenever possible. For small-scale solvent use in correcting images or cleaning the press bed using lithotine or mineral spiritsxe "Mineral Spirits", dilution ventilationxe "Ventilation" is sufficient. For roller and glaze cleaning and larger scale solvent use, local exhaust is recommended. Intaglioxe "Intaglio" Intaglio is a printmaking process in which ink is pressed into depressed areas of the plate and then transferred to paper. These depressed areas can be produced by a variety of techniques, including acid etching, drypoint, engraving and mezzotint. Etchingxe "Etching - Intaglio"xe "Intaglio - Etching" Etching involves use of dilute nitric acidxe "Nitric Acid", Dutch mordant (hydrochloricxe "Hydrochloric Acid" acid plus potassium chlorate) or ferric chloridexe "Ferric Chloride" to etch the zincxe "Zinc" or copper (respectively) metal plate. Unetched parts of the plate are protected with resists such as stopout varnishes containing ethyl alcoholxe "Ethyl Alcohol", grounds containing asphaltum or gilsonite and mineral spiritsxe "Mineral Spirits", rubber cement, and rosinxe "Rosin" or spray paints for aquatinting. Sometimes, soft grounds contain more toxic solvents. Hazards See Solvents section for the hazards of solvents. 1,1,1-trichloroethane found in some soft grounds is moderately toxic by inhalationxe "Inhalation Hazards" under normal conditions. See Acids section for the hazards of acids. In particular nitric acidxe "Nitric Acid" etching releases the respiratory irritant nitrogen dioxidexe "Nitrogen Dioxide" which has poor odor warning properties. Large acute overexposures may cause pulmonary edema (chemical pneumonia), and chronic exposure may cause emphysema. During the etching process, flammable hydrogen gas may also produced. Concentrated nitric acidxe "Nitric Acid" is a strong oxidizing agent and can react with many other chemicals, especially solvents or other organic compounds, to cause a fire. Mixing hydrochloricxe "Hydrochloric Acid" acid with potassium chlorate to make Dutch mordant produces highly toxic chlorine gas. Several years ago, five art students and teachers had chlorine poisoning in Canada from mixing Dutch mordant without proper ventilationxe "Ventilation". Potassium chlorate is a key ingredient in many pyrotechnics, and is a potent oxidizing agent. It can react explosively with organic compounds, sulfur compounds, sulfuric acid or even dirt or clothing. On heating it can violently decompose to oxygen and potassium chloride. Storage and use are very dangerous and require special precautions especially when mixing. Rosinxe "Rosin Hazards" dust (and asphaltum dust which is also sometimes used) is combustible. Sparks or static electricity have caused explosions in enclosed rosinxe "Rosin" and aquatint boxes. Rosinxe "Rosin Hazards" dust may also cause asthma and dermatitis in some individuals. Inhalation of solvents and pigments can result from use of aerosol spray paints. Precautions Obtain the MSDSxe "MSDS" for all materials used. See Solvents and Acids sections for specific precautions. Artists, colleges and universities should use etchants with caution. A safer substitute for etching copper plates is ferric chloridexe "Ferric Chloride" (iron perchloride). This forms acidic solutions so should be handled accordingly, but does not have the dangers of handling concentrated acids. Ferric chloride solution might cause minor skinxe "Skin Hazards" irritation from prolonged contact. Application of grounds or stopouts should be done with local exhaust ventilationxe "Ventilation", (e.g. slot or enclosed hood). Application of spray paints should be done inside a spray booth that exhausts to the outside, or outdoors. Acid etching should be done with local exhaust ventilationxe "Ventilation". See section on precautions for Acids for more information. Note that the acid gases will eventually corrode ordinary fans or galvanized ducts. Rosinxe "Rosin Hazards" (or asphaltum) boxes should be explosion-proof. Use sparkproof metal cranks, explosion-proof motors, or compressed air. Dont use hair dryers to stir up rosinxe "Rosin" dust. Other Techniques Drypoint, mezzotintxe "Mezzotint" and engravingxe "Engraving"xe "Drypoint, Mezzotint and Engraving" use sharp tools to incise lines in metal plates. Hazards One major hazard associated with these types of processes involves accidents with sharp tools. Long-term use of these tools can cause carpel tunnel syndrome, which can cause numbness and pain in the first three fingers. Severe cases can be incapacitating. Precautions Keep tools sharp, store them safely and always cut away from yourself. When possible, clamp down plates to avoid slippage. Minimize the chance of carpel tunnel syndrome by choosing tools with wide handles, avoiding tight grips, and doing hand flexing exercises during regular rest periods. Set worktable height so wrist flexing motions are minimal. Printing and Cleanupxe "Printing and Cleanup - Intaglio"xe "Intaglio - Printing and Cleanup" Intaglio inks contain pigments, treated linseed oil and modifiers. Printing involves placing the ink on the inking slab, inking the plate by hand, and then printing. Cleanup of inking slab, press bed, and cleaning the plate is done with a variety of solvents including mineral spiritsxe "Mineral Spirits", alcohol, lithotine, turpentinexe "Turpentine", etc. Hazards Preparing your own inks from dry pigments can involve inhalationxe "Inhalation Hazards" of toxic pigments. See Pigments section for the hazards of pigments. See Solvents section for the hazards of solvents. Plate cleaning is more hazardous than cleaning inking slabs or press beds because larger amounts of solvents are used. Lithotinexe "Lithotine", turpentinexe "Turpentine", or oil-soaked ragsxe "Oil-Soaked Rag Hazards" can be a spontaneous combustion hazard if improperly stored. Precautions See Pigments and Solvents sections for the specific precautions for pigments and solvents. Dilution ventilationxe "Ventilation" is sufficient for cleaning press beds and inking slabs if small amounts of solvents are used. For cleaning resists off etching plates, use local exhaust ventilationxe "Ventilation", (e.g. slot or enclosed hood). Working immediately in front of a window containing an exhaust fan at work level will also suffice. Oil-soaked rags should be stored in approved, oily waste cans that are emptied each day. Relief and Other Printing Processesxe "Relief Printing" Other printing processes include relief printing, collagraphs, monoprints, and plastic prints. Relief Printing Relief printing techniques include woodcuts, linoleum cuts and acrylic plates for plaster relief. These techniques involve the cutting away of plate areas that are not to be printed. Relief inks can be oil-based or water-based. Hazards Some woods used for woodcuts can cause skinxe "Skin Hazards" irritation and/or allergies. This is particularly true of tropical hardwoods Accidents involving sharp tools can result in cuts. Wood carving and cutting tools can cause carpel tunnel syndrome. Caustic soda (sodium hydroxide) is sometimes used for etching linoleum. It can cause skinxe "Skin Hazards" burns and severe eyexe "Eye Safety" damage if splashed in the eyesxe "Eye Safety". Eating, drinking or smoking while printing can result in accidental ingestionxe "Ingestion Hazards" of pigments. Hazardous solvents are used in stopouts and resists in linoleum etching, and for cleaning up after printing with oil-based inks. Precautions Obtain the MSDSxe "MSDS" for all materials used. See Acids and Solvents sections for precautions with acids and solvents. Water-based inks are preferable to oil-based inks since solvents are not needed. Wear appropriate gloves, goggles and protective apron when handling caustic soda. An emergency shower and eyewash fountain should be available. If the chemical is spilled on your skinxe "Skin Hazards", wash with lots of water. In case of eyexe "Eye Safety" contact, rinse the eyesxe "Eye Safety" with water for at least l5-20 minutes and contact a physician. Vacuum or mop up all wood dust so as to diminish inhalationxe "Inhalation Hazards" of wood dust. Always cut in a direction away from you, with your free hand on the side or behind the hand with the tool. Carpal tunnel syndrome can be minimized or avoided by using tools with wide handles, avoiding tight grips, and rest periods with hand flexing exercises. Linoleum cutting is softer to work, and thus can reduce musculoskeletal injury. Collagraphsxe "Collagraphs" Collagraphs are prints produced by using a collage of different materials glued onto a rigid support. A wide variety of materials and adhesives can be used in making collagraphs. Hazards Rubber cement, a common adhesive used with collagraphs, is extremely flammable and most rubber cements and their thinners contain the solvent n-hexane which can cause damage to the peripheral nervous system (hands, arms, legs, feet) from chronic inhalationxe "Inhalation Hazards" of high levels. Epoxy glues can cause skinxe "Skin Hazards" and eyexe "Eye Safety" irritation and allergies. See the Solvents section for solvent hazards found in adhesives. Spraying fixatives on the backxe "Back Safety" of collagraph plates to seal them can involve risk of inhalationxe "Inhalation Hazards" of the solvent-containing spray mist. Sanding collagraph plates which have been treated with acrylic modeling compounds or similar materials can involve inhalationxe "Inhalation Hazards" of irritating dusts. A wide variety of other materials with varying toxicities can be used in making collagraph plates. Precautions Know the hazards of materials used. Obtain the MSDSs from the manufacturer. Use the least toxic materials available. In particular use water-based glues and mediums (e.g. acrylic medium) whenever possible. Some rubber cements are made with the solvent heptane, which is less toxic than n-hexane, primarily because peripheral neuropathy is not associated with its use. Use ventilationxe "Ventilation" with small amounts of solvents and large amounts of acrylic medium (due to the presence of small amounts of ammoniaxe "Ammonia"). For highly toxic solvents or large amounts of solvents or other toxic chemicals, use local exhaust ventilationxe "Ventilation" (e.g. slot hood, enclosed hood, etc.). Use spray fixatives in a spray booth that exhausts to the outside, or outdoors. Wear gloves when using epoxy glues. Plastic Printsxe "Plastic Prints" Plastic prints can involve making prints from a wide variety of plastic materials and resins. Hazards Plastic prints can involve hazards from inhalationxe "Inhalation Hazards" of plastic resin vapors (e.g. epoxy resins) and also from inhalationxe "Inhalation Hazards" of decomposition fumes from drilling, machining, sawing, etc. of finished plastics. Precautions Obtain the MSDSxe "MSDS" for all materials used. See Solvent section for the precautions with solvents. Use the least toxic material available. Use dilution ventilationxe "Ventilation" with small amounts of solvents and when fabricating finished plastics. For highly toxic solvents or plastics resins, or large amounts of solvents or other toxic chemicals, use local exhaust ventilationxe "Ventilation" such as a slot or enclosed hood. Monoprintsxe "Monoprints" Monoprints involve standard intaglio, lithographic and other printmaking techniques, but only one print is made. Monoprints have the same hazards involved in plate preparation and printing as the parent techniques. Photo printmakingxe "Photoprintmaking" Photo printmaking involves exposing a light-sensitive emulsion or film to ultraviolet light through a transparent support containing an opaque image to transfer the image to a plate. The transparency through which the photo emulsions are developed can include drawings on a transparent support such as Mylar or acetate, or photographic images processed on graphic arts film to yield a positive image. Several photo printmaking methods will be discussed. Photolithographyxe "Photolithography" Photolithography involves transferring graphic images to stones or metal plates that are coated with a light-sensitive emulsion. One can coat the stone or metal plate, or use presensitized metal plates. Light-sensitive emulsions used on stone consist of a mixture of powdered albumin, ammonium dichromate, water, and ammoniaxe "Ammonia"; commercial emulsions are usually based on diazo compounds. Developing solutions for these mixtures often contain highly toxic solvents. Diazo-sensitizing solutions, developers with highly toxic solvents, plate conditioners containing strong alkali, and other brand name mixtures are used for metal plates. Hazards Diazo photoemulsions are the least hazardous although they can cause eyexe "Eye Safety" irritation. Ammonium dichromate used for stone is a probable human carcinogenxe "Carcinogens", is moderately toxic by skinxe "Skin Hazards" contact, and may cause allergies, irritation, and external ulcers; it is highly flammable and a strong oxidizer. Ammonia is a skinxe "Skin Hazards" irritant and highly toxic by inhalationxe "Inhalation Hazards". Ammonia is highly corrosivexe "Corrosives" to the eyesxe "Eye Safety". It has good odor-warning properties. Light exposure sources include photoflood lamps, vacuum Poly-Lite units, and carbon arcs. Carbon arcs produce large amounts of ultraviolet radiation, which can cause skinxe "Skin Hazards" and eyexe "Eye Safety" damage and possible skinxe "Skin Hazards" cancerxe "Cancer". Carbon arcs also produce hazardous metal fumes, and ozone and nitrogen dioxidexe "Nitrogen Dioxide" (which can cause emphysema), and toxic carbon monoxide. Screen cleaning solutions include strong caustic solutions, enzyme detergents which can cause asthma, and chlorine bleach. These are skinxe "Skin Hazards" and respiratory irritants. Many solvents used in developing solutions are highly toxic both by inhalationxe "Inhalation Hazards" and skinxe "Skin Hazards" absorptionxe "Absorption Hazards". Plate conditioners contain alkalisxe "Alkalis" that are highly corrosivexe "Corrosives" to skinxe "Skin Hazards" and eyesxe "Eye Safety". Precautions Obtain a MSDSxe "MSDS" for all materials used. See Solvents section for more precautions with solvents. Avoid ammonium dichromate and use presensitized plates if possible. If you cannot substitute, wear gloves and goggles. Store it away from heat, solvents and other organic materials. Use ammoniaxe "Ammonia" solutions or solvent-containing photolithographic solutions inside a chemical fume hood, or in front of a slot exhaust hood, wear gloves and goggles. General exhaust provides the minimum ventilationxe "Ventilation" needed for using bleach. Do not use carbon arcs unless they are equipped with local exhaust ventilationxe "Ventilation" exhausted to the outside. Quartz mercury or metal halide lamps are safer. Paint walls in the darkroom with a zincxe "Zinc" oxide paint, which will absorb ultraviolet radiation. When using the carbon arc, wear welding goggles with as dark a shade number as enables you to see. Wear gloves, goggles and plastic apron or laboratory coat when mixing hazardous chemicals. Use an exhaust hood when mixing toxic powders. Do not spray diazo photoemulsions without a local exhaust spray booth. An eyewash fountain should be available. In case of splashes in the eyesxe "Eye Safety" rinse with water for at least 15-20 minutes and contact a physician. Photoetchingxe "Photoetching" Photoetching is usually done using the KPR products. Photoresist dyes often contain a variety of highly toxic solvents, including ethylene glycolxe "Ethylene Glycol" monomethyl ether acetate (2-ethoxyethyl acetate, cellosolve acetate), ethylene glycolxe "Ethylene Glycol" monoethyl ether, and xylenexe "Xylene", and benzaldehyde. The developers contain xylenexe "Xylene" and ethylene glycolxe "Ethylene Glycol" monomethyl ether acetate (2-methoxyethyl acetate or methyl cellosolve acetate). Developers used for safer presensitized plates also contain solvents. Exposure of the plate is done with ultraviolet sources such as carbon arcs, mercury lamps, or metal halide lamps. Hazards See the Solvents section for the hazards of various solvents. In particular, methyl and ethyl ether acetates of ethylene glycolxe "Ethylene Glycol" are highly toxic by skinxe "Skin Hazards" absorptionxe "Absorption Hazards" and inhalationxe "Inhalation Hazards" and can cause anemiaxe "Anemia", kidneyxe "Kidney Hazards" damage, testicular atrophy and sterility in men, and miscarriages and birth defectsxe "Birth Defects" in pregnant women. Xylene is toxic by skinxe "Skin Hazards" absorptionxe "Absorption Hazards", and toxic by inhalationxe "Inhalation Hazards" and ingestionxe "Ingestion Hazards". It is has narcotic effects upon rexposure. The Photolithography section discusses carbon arc hazards. Precautions See Solvents section for precautions with solvents. Pregnant or nursing women, children, and men trying to conceive should not work with these materials. Use photofloods or other light sources instead of carbon arcs. Precautions with carbon arcs are discussed in the Photolithography section. Use presensitized plates if possible. Use photoresist solutions with local exhaust ventilationxe "Ventilation". Wear butyl rubber gloves when handling KPR solutions. Other Photo printmaking Techniques Rarer techniques include photogravurexe "Photogravure", using rosinxe "Rosin" and ammonium bichromate, and photoimage wood engravingxe "Photoimage Wood Engraving". Hazards Photogravure uses an aquatint technique involving rosinxe "Rosin" dust or asphaltum. See Etching under Intaglio for hazards of rosinxe "Rosin" dust. Potassium dichromatexe "Potassium Dichromate" is used as a developing agent in photogravure. Potassium dichromatexe "Potassium Dichromate" may cause skinxe "Skin Hazards" and nasal ulceration and allergicxe "Allergic Reactions" reactions, and is a suspect cancerxe "Cancer"-causing agent. Photoimage wood engraving uses photoemulsions. Precautions Use sunlight, photofloods or other light sources instead of carbon arcs. Wear gloves, goggles and protective apron when handling potassium dichromate. Use exhaust ventilationxe "Ventilation" to protect against toxic dust exposure when mixing powders. An eyewash fountain should be available. In case of splashes in the eyesxe "Eye Safety" rinse with water for at least 15-20 minutes and contact a physician. Photographic Processingxe "Photographic Processing" Black-And-White Photographic Processingxe "Photographic Processing - Black-and-White"xe "Black-And-White Photographic Processing" A wide variety of chemicals are used in black and white photographic processing. Film developing is usually done in closed canisters. Print processing uses tray processing, with successive developing baths, stop baths, fixing baths, and rinse steps. Other treatments include use of hardeners, intensifiers, reducers, toners, and hypo eliminators. Photochemical can be purchased both as ready-to-use brand name products, or they can be purchased as individual chemicals, which you can mix yourself. Mixing B&W Photographic Chemicalsxe "Photographic Chemicals - Mixing B&W" Photochemical can be bought in liquid form, which only need diluting, or powder form, which need dissolving and diluting. Hazards Developer solutions and powders are often highly alkaline, and glacial acetic acidxe "Glacial Acetic Acid", used in making the stop bath, is also corrosivexe "Corrosives" by skinxe "Skin Hazards" contact, inhalationxe "Inhalation Hazards" and ingestionxe "Ingestion Hazards". Developer powders are toxic by inhalationxe "Inhalation Hazards", and toxic by skinxe "Skin Hazards" contact, due to the alkali and developers themselves (see Developing Baths below). The developers may cause methemoglobinemiaxe "Methemoglobinemia", an acute anemiaxe "Anemia" resulting from converting the iron of hemoglobin into a form that cannot transport oxygen. Precautions Use liquid chemistry whenever possible, rather than mixing developing powders. Pregnant women, in particular, should not be exposed to powdered developer. When mixing powdered developers, use local exhaust ventilationxe "Ventilation". Wear gloves, goggles and protective apron when mixing concentrated photochemical. Always add any acid to water, never the reverse. An eyewash fountain and emergency shower facilities should be available where the photochemical are mixed due to the corrosivexe "Corrosives" alkali in developers, and because of the glacial acetic acidxe "Glacial Acetic Acid". In case of skinxe "Skin Hazards" contact, rinse with lots of water. In case of eyexe "Eye Safety" contact, rinse for at least 15-20 minutes and call a physician. Store concentrated acids and other corrosivexe "Corrosives" chemicals on low shelves so as to reduce the chance of face or eyexe "Eye Safety" damage in case of breakage and splashing. Do not store photographic solutions in glass containers. Label all solutions carefully so as not to ingest solutions accidentally. Developing Bathsxe "Developing Baths - B&W" The most commonly used developers are hydroquinone, monomethyl para-aminophenol sulfate, and phenidone. Several other developers are used for special purposes. Other common components of developing baths include an accelerator, often sodium carbonatexe "Sodium Carbonate" or borax, sodium sulfite as a preservative, and potassium bromide as a restrainer or antifogging agent. Hazards Developers are skinxe "Skin Hazards" and eyexe "Eye Safety" irritants, and in many cases strong sensitizers. Monomethyl-p-aminophenol sulfate creates many skinxe "Skin Hazards" problems, and allergies to it are frequent (although this is thought to be due to the presence of para-phenylene diamine as a contaminant). Hydroquinone can cause depigmentation and eyexe "Eye Safety" injury after five or more years of repeated exposure, and is a mutagen. Some developers also can be absorbed through the skinxe "Skin Hazards" to cause severe poisoning (e.g., catechol, pyrogallic acid). Phenidone is only slightly toxic by skinxe "Skin Hazards" contact. Most developers are moderately toxic by ingestionxe "Ingestion Hazards", with ingestionxe "Ingestion Hazards" of less than one tablespoon of compounds such as monomethyl-p-aminophenol sulfate, hydroquinone, or pyrocatechol being possibly fatal for adults. This might pose a particular hazard for home photographers with small children. Symptoms include ringing in the ears (tinnitus), nausea, dizziness, muscular twitching, increased respiration, headache, cyanosisxe "Cyanosis" (turning blue from lack of oxygen) due to methemoglobinemiaxe "Methemoglobinemia", delirium, and coma. With some developers, convulsions also can occur. Para-phenylene diamine and some of its derivatives are highly toxic by skinxe "Skin Hazards" contact, inhalationxe "Inhalation Hazards", and ingestionxe "Ingestion Hazards". They cause very severe skinxe "Skin Hazards" allergies and can be absorbed through the skinxe "Skin Hazards". Sodium hydroxidexe "Sodium Hydroxide", sodium carbonatexe "Sodium Carbonate", and other alkalisxe "Alkalis" used as accelerators are highly corrosivexe "Corrosives" by skinxe "Skin Hazards" contact or ingestionxe "Ingestion Hazards". This is a particular problem with the pure alkali or with concentrated stock solutions. Potassium bromidexe "Potassium Bromide" is moderately toxic by inhalationxe "Inhalation Hazards" or ingestionxe "Ingestion Hazards" and slightly toxic by skinxe "Skin Hazards" contact. Symptoms of systemic poisoning include somnolence, depression, lack of coordination, mental confusion, hallucinations, and skinxe "Skin Hazards" rashes. It can cause bromide poisoning in fetuses in cases of high exposure of the pregnant woman. Sodium sulfitexe "Sodium Sulfite" is moderately toxic by ingestionxe "Ingestion Hazards" or inhalationxe "Inhalation Hazards", causing gastric upset, colic, diarrhea, circulatory problems, and central nervous system depression. It is not appreciably toxic by skinxe "Skin Hazards" contact. If heated or allowed to stand for a long time in water or acid, it decomposes to produce sulfur dioxide, which is highly irritating by inhalationxe "Inhalation Hazards". Precautions See the section on Mixing Photo chemicals for mixing precautions. Do not put your bare hands in developer baths. Use tongs and gloves instead. If developer solution splashes on your skinxe "Skin Hazards" or eyesxe "Eye Safety" immediately rinse with lots of water. For eyexe "Eye Safety" splashes, continue rinsing for 15-20 minutes and call a physician. Eyewash fountains are important for photography darkrooms. Do not use para-phenylene diamine or its derivatives if at all possible. Stop Baths and Fixerxe "Stop Baths and Fixer - B&W" Stop baths are usually weak solutions of acetic acidxe "Acetic Acid". Acetic acid is commonly available as pure glacial acetic acidxe "Glacial Acetic Acid" or 28% acetic acidxe "Acetic Acid". Some stop baths contain potassium chromexe "Chrome" alum as a hardener. Fixing baths contain sodium thiosulfate (hypo) as the fixing agent, and sodium sulfite and sodium bisulfite as a preservative. Fixing baths also may also contain alum (potassium aluminum sulfate) as a hardener and boric acid as a buffer. Hazards Acetic acid, in concentrated solutions, is highly toxic by inhalationxe "Inhalation Hazards", skinxe "Skin Hazards" contact, and ingestionxe "Ingestion Hazards". It can cause dermatitis and ulcers, and can strongly irritate the mucous membranes. The final stop bath is only slightly hazardous by skinxe "Skin Hazards" contact. Continual inhalationxe "Inhalation Hazards" of acetic acidxe "Acetic Acid" vapors, even from the stop bath, may cause chronic bronchitisxe "Bronchitis". Potassium chromexe "Chrome" alum or chromexe "Chrome" alum (potassium chromium sulfate) is moderately toxic by skinxe "Skin Hazards" contact and inhalationxe "Inhalation Hazards", causing dermatitis and allergies. In powder form, sodium thiosulfate is not significantly toxic by skinxe "Skin Hazards" contact. By ingestionxe "Ingestion Hazards" it has a purging effect on the bowels. Upon heating or long standing in solution, it can decompose to form highly toxic sulfur dioxide, which can cause chronic lung problems. Many asthmatics are particularly sensitive to sulfur dioxide. Sodium bisulfite decomposes to form sulfur dioxide if the fixing bath contains boric acid, or if acetic acidxe "Acetic Acid" is transferred to the fixing bath on the surface of the print. Alum (potassium aluminum sulfate) is only slightly toxic. It may cause skinxe "Skin Hazards" allergies or irritation. Boric acid is moderately toxic by ingestionxe "Ingestion Hazards" or inhalationxe "Inhalation Hazards" and slightly toxic by skinxe "Skin Hazards" contact (unless the skinxe "Skin Hazards" is abraded or burned, in which case it can be toxic). Precautions All darkrooms require good ventilationxe "Ventilation" to control the level of acetic acidxe "Acetic Acid" vapors and sulfur dioxide gas produced in photography. Kodak recommends at least 10 air changes per hour. The exhaust duct opening should preferably be located behind and just above the stop bath and fixer trays. Wear gloves and goggles. Cover all baths when not in use to prevent evaporation or release of toxic vapors and gases. Intensifiers and Reducersxe "Photographic Intensifiers and Reducers B&W" A common after-treatment of negatives (and occasionally prints) is either intensification or reduction. Common intensifiers include hydrochloricxe "Hydrochloric Acid" acid and potassium dichromate, or potassium chlorochromate. Mercuric chloride followed by ammoniaxe "Ammonia" or sodium sulfite, Monckhovens intensifier consisting of a mercuric salt bleach followed by a silver nitrate/potassium cyanidexe "Cyanide Hazards" solution, mercuric iodide/sodium sulfite, and uranium nitrate are older, now discarded, intensifiers. Reduction of negatives is usually done with Farmers reducer, consisting of potassium ferricyanide and hypo. Reduction has also been done historically with iodine/potassium cyanidexe "Cyanide Hazards", ammonium persulfate, and potassium permanganatexe "Permanganates"/sulfuric acid. Hazards Potassium dichromatexe "Potassium Dichromate" and potassium chlorochromate are probable human carcinogensxe "Carcinogens", and can cause skinxe "Skin Hazards" allergies and ulceration. Potassium chlorochromate can release highly toxic chlorine gas if heated or if acid is added. Concentrated hydrochloricxe "Hydrochloric Acid" acid is corrosivexe "Corrosives"; the diluted acid is a skinxe "Skin Hazards" and eyexe "Eye Safety" irritant. Mercury compounds are moderately toxic by skinxe "Skin Hazards" contact and may be absorbed through the skinxe "Skin Hazards". Uranium intensifiers are radioactive, and are especially hazardous to the kidneys. Sodium or potassium cyanidexe "Cyanide Hazards" is extremely toxic by inhalationxe "Inhalation Hazards" and ingestionxe "Ingestion Hazards", and moderately toxic by skinxe "Skin Hazards" contact. Adding acid to cyanidexe "Cyanide Hazards" forms extremely toxic hydrogen cyanidexe "Cyanide Hazards" gas, which can be rapidly fatal. Potassium ferricyanide, although only slightly toxic by itself, will release hydrogen cyanidexe "Cyanide Hazards" gas if heated, if hot acid is added, or if exposed to strong ultraviolet light (e.g., carbon arcs). Cases of cyanidexe "Cyanide Hazards" poisoning have occurred through treating Farmers reducer with acid. Potassium permanganatexe "Permanganates" and ammonium persulfate are strong oxidizers and may cause fires or explosions in contact with solvents and other organic materials. Precautions Chromiumxe "Chromium Hazards" intensifiers are probably the least toxic intensifiers, even though they are probable human carcinogensxe "Carcinogens". Gloves and goggles should be worn when preparing and using these intensifiers. Do not expose potassium chlorochromate to acid or heat. Do not use mercury, cyanidexe "Cyanide Hazards" or uranium intensifiers, or cyanidexe "Cyanide Hazards" reducers because of their high or extreme toxicity. The safest reducer to use is Farmers reducer. Do not expose Farmers reducer to acid, ultraviolet light, or heat. Tonersxe "Photographic Toners - B&W" Toning a print usually involves replacement of silver by another metal, for example, gold, selenium, uranium, platinum, or iron. In some cases, the toning involves replacement of silver metal by brown silver sulfide, for example, in the various types of sulfide toners. A variety of other chemicals are also used in the toning solutions. Hazards Sulfides release toxic hydrogen sulfide gas during toning, or when treated with acid. Selenium is a skinxe "Skin Hazards" and eyexe "Eye Safety" irritant and can cause kidneyxe "Kidney Hazards" damage. Treatment of selenium salts with acid may release highly toxic hydrogen selenide gas. Selenium toners also give off large amounts of sulfur dioxide gas. Gold and platinum salts are strong sensitizers and can produce allergicxe "Allergic Reactions" skinxe "Skin Hazards" reactions and asthma, particularly in fair-haired people. Thiourea is a probable human carcinogenxe "Carcinogens" since it causes cancerxe "Cancer" in animals. Precautions Carry out normal precautions for handling toxic chemicals as described in previous sections. In particular, wear gloves and goggles. Toning solutions must be used with proper exhaust ventilationxe "Ventilation". Take precautions to make sure that sulfide or selenium toners are not contaminated with acids. For example, with two bath sulfide toners, make sure you rinse the print well after bleaching in acid solution before dipping it in the sulfide developer. Avoid thiourea whenever possible because of its probable cancerxe "Cancer" status. Other Hazards Many other chemicals are also used in black and white processing, including formaldehydexe "Formaldehyde" as a prehardener, a variety of oxidizing agents as hypo eliminators (e.g., hydrogen peroxidexe "Hydrogen Peroxide" and ammoniaxe "Ammonia", potassium permanganatexe "Permanganates", bleaches, and potassium persulfate), sodium sulfide to test for residual silver, silver nitrate to test for residual hypo, solvents such as methyl chloroform and freons for film and print cleaning, and concentrated acids to clean trays. Electrical outlets and equipment can present electrical hazards in darkrooms due to the risk of splashing water. Hazards Concentrated sulfuric acid, mixed with potassium permanganatexe "Permanganates" or potassium dichromate, produces highly corrosivexe "Corrosives" permanganic and chromic acids. Hypochlorite bleaches can release highly toxic chlorine gas when acid is added, or if heated. Potassium persulfate and other oxidizing agents used as hypo eliminators may cause fires when in contact with easily oxidizable materials, such as many solvents and other combustible materials. Most are also skinxe "Skin Hazards" and eyexe "Eye Safety" irritants. Precautions See previous sections for precautions in handling photographic chemicals. Cleaning acids should be handled with great care. Wear gloves, goggles and acid-proof, protective apron. Always add acid to the water when diluting. Do not add acid to, or heat, hypochlorite bleaches. Keep potassium persulfate and other strong oxidizing agents separate from flammable and easily oxidizable substances. Install ground fault interrupters (GFCIs) whenever electrical outlets or electrical equipment (e.g. enlargers) are within six feet of the risk of water splashes. Color Processingxe "Photo Processing - Color" Color processing is much more complicated than black and white processing, and there is a wide variation in processes used by different companies. Color processing can be either done in trays or in automatic processors. Developing Bathsxe "Photo Developing Baths - Color" The first developer of color transparency processing usually contains monomethyl-p-aminophenol sulfate, hydroquinone, and other normal black and white developer components. Color developers contain a wide variety of chemicals including color coupling agents, penetrating solvents (such as benzyl alcohol, ethylene glycolxe "Ethylene Glycol", and ethoxydiglycol), amines, and others. Hazards See the developing section of black and white processing for the hazards of standard black and white developers. In general, color developers are more hazardous than black and white developers. Para-phenylene diamine, and its dimethyl and diethyl derivatives, are known to be toxic by skinxe "Skin Hazards" contact and absorptionxe "Absorption Hazards", inhalationxe "Inhalation Hazards", and ingestionxe "Ingestion Hazards". They can cause skinxe "Skin Hazards" irritation, allergies and poisoning. Color developers have also been linked to lichen planus, an inflammatory skinxe "Skin Hazards" disease characterized by reddish pimples, which can spread to form rough scaly patches. Recent color developing agents such as 4-amino-N-ethyl-N-[P-methane-sulfonamidoethyl]-m-toluidine sesquisulfate monohydrate and 4-amino-3-methyl-N-ethyl-N-[,3-hydroxyethyl]-aniline sulfate are supposedly less hazardous, but still can cause skinxe "Skin Hazards" irritation and allergies. Most amines, including ethylene diamine, tertiary-butylamine borane, the various ethanolamines, etc. are sensitizers, as well as skinxe "Skin Hazards" and respiratory irritants. Although many of the solvents are not very volatile at room temperature, elevated temperatures used in color processing can increase the amount of solvent vapors in the air. The solvents are usually skinxe "Skin Hazards" and eyexe "Eye Safety" irritants. Precautions Wear gloves and goggles when handling color developers. According to Kodak, barrier creams are not effective in preventing sensitization due to color developers. Color processing needs more ventilationxe "Ventilation" than black and white processing due to the use of solvents and other toxic components at elevated temperatures Bleaching, Fixing, and Other Stepsxe "Photo Bleaching, Fixing, and Other Steps - Color" Many of the chemicals used in other steps of color processing are essentially the same as those used for black and white processing. Examples include the stop bath and fixing bath. Bleaching uses a number of chemicals, including potassium ferricyanide, potassium bromide, ammonium thiocyanate, and acids. Chemicals found in prehardeners and stabilizers include succinaldehyde and formaldehydexe "Formaldehyde"; neutralizers can contain hydroxylamine sulfate, acetic acidxe "Acetic Acid", and other acids. Hazards Formaldehyde is moderately toxic by skinxe "Skin Hazards" contact, and toxic by inhalationxe "Inhalation Hazards" and ingestionxe "Ingestion Hazards". It is a skinxe "Skin Hazards", eyexe "Eye Safety" and respiratory irritant, and strong sensitizer, and is a probable human carcinogenxe "Carcinogens". Formaldehyde solutions contain some methanol, which is toxic by ingestionxe "Ingestion Hazards". Succinaldehydexe "Succinaldehyde" is similar in toxicity to formaldehydexe "Formaldehyde", but is not a strong sensitizer or carcinogenxe "Carcinogens". Hydroxylamine sulfatexe "Hydroxylamine Sulfate" is a suspected teratogenxe "Teratogen" in humans since it is a teratogenxe "Teratogen" (causes birth defectsxe "Birth Defects") in animals. It is also a skinxe "Skin Hazards" and eyexe "Eye Safety" irritant. Concentrated acids, such as glacial acetic acidxe "Glacial Acetic Acid", hydrobromic acid, sulfamic acid and p-toluenesulfonic acids are corrosivexe "Corrosives" by skinxe "Skin Hazards" contact, inhalationxe "Inhalation Hazards" and ingestionxe "Ingestion Hazards". Acid solutions, if they contain sulfites or bisulfites (e.g., neutralizing solutions), can release sulfur dioxide upon standing. If acid is carried over on the negative or transparency from one step to another step containing sulfites or bisulfites, then sulfur dioxide can be formed. Potassium ferricyanide will release hydrogen cyanidexe "Cyanide Hazards" gas if heated, if hot acid is added, or if exposed to strong ultraviolet radiation. Precautions Local exhaust ventilationxe "Ventilation" is required for mixing of chemicals and color processing. See previous section for discussion of ventilationxe "Ventilation". Use premixed solutions whenever possible. For powders, use an exhaust hood. Avoid color processes using formaldehydexe "Formaldehyde", if possible. Wear gloves, goggles and protective apron when mixing and handling color processing chemicals. When diluting solutions containing concentrated acids, always add the acid to the water. An eyewash and emergency shower should be available. A water rinse step is recommended between acid bleach steps and fixing steps to reduce the production of sulfur dioxide gas. Do not add acid to solutions containing potassium ferricyanide or thiocyanate salts. Control the temperature carefully according to manufacturers recommendations to reduce emissions of toxic gases and vapors. Index  INDEX \e " " \h " " \c "2"  Absorption Hazards 53, 60, 74, 76, 87, 88, 97 Acetic Acid 53, 92, 93, 98 Acetone 24, 26, 60 Acid Hazards - Lithography and Printing 75 Acids and Bases 23 Acids and Bases - Diluting 23 Airbrush, Spray Cans and Spray Guns 45 Alkalis 87, 91 Allergic Reactions 47, 49, 67, 73, 77, 89, 95 Ammonia 49, 50, 85, 86, 87, 93, 96 Anemia 35, 47, 64, 73, 88, 90 Anodizing 69 ANSI 39, 54, 62, 63, 66, 71 Antimony Hazards 36, 64 Asbestos 32, 33, 40, 56, 57, 66, 78 Back Safety 33, 34, 56, 58, 71, 84 Birth Defects 35, 64, 88, 98 Black-And-White Photographic Processing 89 Bleeding 18 Brain Damage Hazards 35, 43, 47, 73, 74 Breathing - First Aid 18 Bronchitis 38, 57, 64, 93 Burns - Chemical 19 Burns - Thermal 18 Cadmium 36, 38, 43, 47, 48, 51, 61, 62, 73 Cadmium Hazards 61 Cancer 47, 51, 56, 61, 66, 73, 77, 79, 87, 89, 95, 96 Carbolic Acid 75, 77 Carbon Black 47, 48, 73 Carbon monoxide 38 Carcinogens 36, 37, 51, 70, 73, 76, 79, 86, 94, 95, 98 Carpal Tunnel Syndrome 34 Casting Stones 56 Ceramic Art and Pottery 32 Chemical Disposal - Acids and Bases Drain Disposal 26 Chemical Disposal - Collection by EHS 26 Chemical Disposal - Department Procedures 27 Chemical Disposal - Drain Disposal 25 Chemical Disposal - Solvent Drain Diposal 26 CHEMICAL HAZARDS 23 Chemical Information - Material Safety Data Sheets 16 CHEMICAL SAFETY - Acids and Bases 23 CHEMICAL SAFETY - Toxic Hazards 23 CHEMICAL SAFETY PROCEDURES 23 Chemical Storage 22 Chemical Transport 22 CHEMICAL WASTE DISPOSAL 25 Chemical Waste Disposal - Request for EHS Pick-up 27 Chlorinated Hydrocarbons 35, 74, 79 Chromate 47, 73 Chromate Hazards 44, 47, 48, 50, 51, 73 Chrome 44, 47, 48, 51, 73, 92, 93 Chromic Acid 75, 76 Chromium Hazards 94 Clay 32 Clean Up - Wet Cleaning Requirements 66 Clean up - Wet Methods to Prevent Dust Exposure 34, 49 Clothing - Safety Precauations 21 Cobalt 36, 43, 44, 47, 48, 73 Collagraphs 84 College Safety Officer 2 Conjunctivitis 25 Container Labeling 21 Corrosives 21, 53, 57, 62, 67, 69, 75, 77, 86, 87, 90, 91, 94, 96, 98 CPR Training 18 Cristobalite Hazards 65 Cyanide Hazards 67, 68, 69, 71, 94, 95, 99 Cyanosis 91 Cyclohexanone 77 Denatured Alcohol 75 Departmental Safety Officer 2 Developing Baths - B&W 91 Dichromate 77 Drawing Hazards - Dry Drawing Media 50 Drawing Hazards - General 50 Drawing Hazards - Liquid Drawing Media 51 Drypoint, Mezzotint and Engraving 81 Ear Protection 58 EHS 1, 15, 16, 17, 20, 22, 23, 26, 27, 29, 34, 40 EHS - Web Page 21 ELECTRICAL HAZARDS AND SAFETY PROCEDURES 27 Electrical Shock. Hazards 70 Electroplating and Electroforming 67 Emergencies - 911 Procedures 17 EMERGENCIES - FIRST AID 17 Emergency Equipment 17 EMERGENCY PHONE NUMBERS 2 Emergency Reporting 16 Emergency Response 16 Engraving 81 E H S 2 EHS..1, 15, 18, 20, 26, 29, 40, 69 Ergonomics 34 Etching - Intaglio 79 Ethyl Alcohol 74, 80 Ethylene Glycol 88, 97 Eye Protection 20 Eye Safety 15, 17, 19, 20, 23, 25, 39, 41, 45, 49, 50, 52, 53, 56, 57, 62, 63, 65, 67, 69, 70, 74, 75, 76, 77, 83, 84, 86, 87, 88, 89, 90, 91, 92, 94, 95, 96, 98 Ferric Chloride 79, 81 Finishing Stone 59 Fire Emergency Procedures 29 Fire Extinguishers 29 Fire Extinguishers - Class D 70 FIRE SAFETY 28 FIRST AID 17 First Aid - CPR Training 18 Flammable liquids - Storage 22 Flammable Vapors 24 Fluoride Hazards 24, 50, 62 Fluxes - Soldering 35, 36, 42, 62, 64, 65 Food and Beverages - Safety Precautions 21 Formaldehyde 49, 96, 98, 99 Gastrointestinal Hazards 25, 35, 47, 73, 75 Glacial Acetic Acid 90, 92, 98 Glazes 35 Glazing - Salt 40 Hand Protection 21 Handling of Waste - Chemicals 25 Hard Stones 55 Hazardous Material Response Team - EHS 22 Hearing Loss 20, 56 Hearing Protection 20 Hearing Protection - "Rule of Thumb" 20 Hearing Protection - Earmuffs 20 Hearing Protection - Earplugs 20 HEPA Vacuums 34, 37, 49, 53, 54, 57, 63, 65, 66 Hydrochloric Acid 26, 41, 75, 77, 79, 80, 93, 94 Hydrofluoric Acid 24, 69, 70, 75, 76, 77, 78 Hydrofluoric Acid Burns - Treatment 70 Hydrofluoric Acid Hazards 69, 76, 77 Hydrogen Peroxide 96 Hydroxylamine Sulfate 98 Infrared Radiation Hazards 70 Infrared Radiation Hazards - Repouss 70 Ingestion Hazards 23, 32, 35, 36, 37, 43, 44, 46, 47, 49, 51, 53, 54, 55, 60, 67, 72, 73, 76, 83, 88, 90, 91, 92, 93, 94, 97, 98, 99 Inhalation Hazards 23, 26, 32, 33, 35, 36, 37, 38, 41, 43, 44, 46, 47, 49, 50, 51, 52, 53, 54, 55, 56, 57, 59, 60, 64, 65, 72, 77, 78, 80, 82, 84, 85, 86, 87, 88, 90, 91, 92, 93, 94, 97, 98, 99 Ink Hazards - Lithography and Printing 72 Intaglio 79 Intaglio - Etching 79 Intaglio - Printing and Cleanup 82 Isophorone 77 Isopropyl Alcohol 75 Jewelry Making Hazards 61 Kerosene 74, 77, 78 Kidney Hazards 35, 43, 47, 51, 61, 64, 69, 73, 76, 88, 95 Kilns 37 Lamp Black 73 Lapidary 58 Leachable Metals 42 Leaching of Finished Ceramic Ware 42 Lead Hazards 24, 25, 35, 36, 37, 38, 39, 42, 43, 44, 46, 47, 48, 50, 51, 63, 64, 65, 66, 69, 73 Linseed Oil Hazards 72 Lithography 77 Lithography - Plate and Stone Preparation 77 Lithography - Printing and Cleanup 79 Lithography, Intaglio and Relief Printing Hazards 72 Lithotine 77, 78, 82 Long Hair Hazards 58, 71 Long Sleeve Hazards 71 Loose Clothing Hazards 20, 58 Lost Wax Casting 65 Lung Disease Hazards 65 Manganese 36, 43, 47, 48, 73 Material Safety Data Sheets 16 Material Safety Data Sheets - Sources 16 MEK 77 Metal Jewelry 61 Metal Surface Working, Polishing and Finishing 70 Methanol 24, 25 Methemoglobinemia 90, 91 Methyl Alcohol 55, 74, 75 Methyl Ethyl Ketone 77 Methylene Chloride 74, 79 Mezzotint 81 Mineral Spirits 35, 43, 44, 74, 77, 78, 79, 80, 82 Monoprints 86 MSDS 16, 21, 23, 24, 25, 75, 76, 78, 79, 81, 83, 85, 87 Nerve Damage Hazards 47, 73 Nitric Acid 61, 75, 76, 79, 80 Nitrogen Dioxide 38, 76, 80, 87 Noise Hazards 56 Office of Physical Plant 2 Oil Painting 43 Oil-Soaked Rag Hazards 72, 82 Organic Solvents 24 Painting and Drawing Hazards 43 Paraffin wax 66 Perchloroethylene 79 Permanganates 94, 96 Phenol 50, 75, 76, 77, 78 PHONE NUMBERS 2 Phosphoric Acid 26, 75, 77 Photo Bleaching, Fixing, and Other Steps - Color 98 Photo Developing Baths - Color 97 Photo Processing - Color 97 Photoetching 88 Photographic Chemicals - Mixing B&W 89 Photographic Intensifiers and Reducers B&W 93 Photographic Processing 89 Photographic Processing - Black-and-White 89 Photographic Toners - B&W 95 Photogravure 89 Photoimage Wood Engraving 89 Photolithography 86 Photoprintmaking 86 Physical Plant 2 Pigment Hazards - Lithography and Priting 72 Pigments 46 Plaster Finishing 54 Plaster Hazards 52 Plaster Molds 54 Plastic Prints 85 Plate and Stone Preparation - Lithography 77 Police 2 Potassium Bromide 91 Potassium Dichromate 89, 94 Powders - Safety Hazards 25 Prevention 16 PRINCIPLES OF SAFETY 15 Printing and Cleanup - Intaglio 82 Printing and Cleanup - Lithography 79 Protective Equipment 21, 37 Protective Equipment - EHS Assistance 21 Raku 41 REFERENCES - Safety Related 31 Relief Printing 83 Reporting Emergencies 16 Repouss 70 Reproductive Hazards 47, 64, 73 Repsonding to an Emergency 16 Respirators 59, 71 Respiratory Protection 20 Respiratory Protection - EHS Assistance 20 Rosin 60, 64, 77, 80, 81, 89 Rosin Hazards 64, 77, 80, 81 Safety Council 15 SAFETY INFORMATION - GENERAL 17 Safety of Others 16 Safety Officer 2 Safety Practices 15 SAFETY RULES - General Practices 20 SAFETY RULES - Studio Practices 21 Salt Glazing 40 Sculpture Hazards 52 Shock - Electric 18, 27, 57, 70 Shock - Traumatic 19 Silica - Safety Hazards 25, 32, 35, 53 Silica Hazards 32, 33, 34, 35, 36, 56, 57, 59, 65, 66, 71, 78 Silicosis 25, 32, 36, 53, 65, 71 Silver Soldering 61 Skin Hazards 21, 23, 24, 32, 33, 34, 36, 41, 43, 44, 47, 49, 53, 54, 55, 57, 60, 62, 63, 65, 67, 68, 69, 70, 72, 73, 74, 75, 76, 77, 81, 83, 84, 86, 87, 88, 89, 90, 91, 92, 93, 94, 95, 96, 97, 98, 99 Sodium Carbonate 41, 91 Sodium Hydroxide 91 Sodium Sulfite 92 Soft Soldering 63 Soft Stones 55 Soldering 61 Soldering - Silver 61 Soldering Flux Hazards 61, 62 Solvents 24 Sparex 61, 62, 63 Spills - Clean Up 22 Spills - EHS Assistance 22 Stone Finishing 59 Stones and Lapidary 55 Stop Baths and Fixer - B&W 92 Succinaldehyde 98 Sulfuric Acid 75 Talc 77 Tannic Acids 77 Teratogen 98 Toluene 26, 74 Toxic Hazards 23 Toxic Pigments - Table 1 47, 48 Transporting Chemicals 22 Trisodium Phosphate Hazards 69 Turpentine 43, 44, 45, 60, 74, 82 University Safety Council 15 Ventilation 15, 16, 24, 25, 33, 37, 39, 44, 45, 46, 50, 52, 53, 54, 55, 58, 59, 62, 64, 68, 71, 72, 78, 79, 80, 81, 82, 85, 86, 87, 88, 89, 90, 93, 95, 98, 99 Vibration Hazards 56 Water-Based Paints 49 Wax - Sculpture Hazards 60 Xylene 52, 74, 88 Zephiran 70 Zinc 47, 48, 64, 65, 66, 73, 77, 80, 87 APPENDIX A FACT SHEETS EMERGENCY RESPONSE TRAINING FACT SHEET Based on Title 29 of the Code of Federal Regulations (29 CFR) 1910.120, Hazardous waste operations and emergency response. ____________________________________________ CHEMICAL SPILLS YOU CAN HANDLE YOURSELF Principal investigators, employees, and students working in Visual Arts areas should be aware that required safety training for workers includes emergency response training Emergency training applies to building evacuation procedures during fires and explosions, recognition of system alarms, and appropriate action in the event of spills of hazardous material. Workers must receive training to distinguish between the types of spills they can handle on their own and those spills that are classified as MAJOR. Major spills dictate the need for outside help. Workers are qualified to clean-up spills that are minor. A minor spill is defined as a spill that does not pose a significant safety or health hazard to employees in the immediate vicinity nor does it have the potential to become an emergency within a short time frame. Workers can handle minor spills because they are expected to be familiar with the hazards of the chemicals they routinely handle during an average workday. If the spill exceeds the scope of the workers experience, training or willingness to respond, the workers must be able to determine that the spill cannot be dealt with internally. Emergency assistance is provided by EHS and the University Hazardous Materials Team. Spills requiring the involvement of individuals outside the area are those exceeding the exposure one would expect during the normal course of work. Spills in this category are those which have truly become emergency situations in that workers are overwhelmed beyond their level of training. Their response capability is compromised by the magnitude of the incident. Emergencies such as this involve: the need to evacuate employees in the area the need for response from outside the immediate release area the release poses, or has potential to pose, conditions that are immediately dangerous to life and health the release poses a serious threat of fire and explosion the release requires immediate attention due to imminent danger the release may cause high levels of exposure to toxic substances there is uncertainty that the worker can handle the severity of the hazard with the personal protective equipment (PPE) and equipment that has been provided and the exposure limit could be exceeded easily the situation is unclear or data is lacking regarding important factors. Depending on the circumstances, what begins as a minor spill could at some point escalate into a major emergency. Responding workers must monitor changing conditions. Again, unit-specific training must cover how to tell the difference! EHS employees have received in-depth training qualifying them for emergency response beyond the level of minor spills. They are prepared to answer calls which exceed the training scope of workers. Workers are encouraged to play it safe and contact EHS for clean-up assistance when in doubt about the status of a spill. EHS assistance is available 24 hours a day, seven days a week. EHS: 865-6391 ____________________________________________ ALL SPILLS THAT REQUIRE OUTSIDE INTERVENTION A. Emergency Response Procedures. Call 911 to report fires, explosions, medical emergencies, and hazardous material spills. Dispatch will contact EHS and appropriate emergency response personnel at anytime to respond to hazardous material spills. An Incident Report form must be completed for each emergency incident. Following a MAJOR incident, EHS responders may determine, based on the circumstances of the spill or release, that clean-up of the site can be handled workers or other University employees (under the direction of the unit supervisor or EHS In the event that EHS is called to a minor spill (i.e., workers have been conservative in assessing hazard and assumed worst case), EHS representatives will participate in or oversee the clean-up to support the workers. In both of these cases where clean-up becomes a unit responsibility, EHS can provide clean-up supplies and equipment, personal protective equipment (to the level of training of the workers), and safety instructions. ____________________________________________ GENERAL UNIVERSITY EMERGENCY INFORMATION A. Building Emergency and Evacuation. In the event of a fire, hazardous material release, or other hazardous situation requiring emergency, the person who discovers the emergency will: evacuate the zone activate the fire alarm, if needed call 911 and report the incident assist emergency personnel by providing information regarding location of the incident, origin, and persons involved. The person who discovers the emergency shall not be placed in imminent danger. C. Incident (Accident) Reporting. All incidents shall be reported to EHS, including minor spills, fires, or injuries and shall be investigated. The supervisor shall be responsible for implementing corrective action to prevent repeat incidents. In the event of worker injury, the immediate supervisor of the injured employee must fill out the  HYPERLINK "http://www.ohr.psu.edu/workerscomp/injury.cfm" First Report of Injury D. Signs. The following signs and labels are required for all laboratories in University facilities: A Laboratory Information sign shall be posted outside all laboratories, either on the outside of the door or on the wall beside the door. This sign provides information on specific hazards in the lab and telephone numbers of responsible faculty and staff. The information shall be updated as necessary. An Emergency and Laboratory Safety Phone numbers sign shall be posted in a prominent location inside the lab, near the door or telephone. This sign provides emergency numbers in case of an emergency. A label bearing the University Police emergency number shall be placed on each telephone in the lab. CHEMICAL SAFETY FACT SHEET University Safety Policies  HYPERLINK "http://guru.psu.edu/policies/SY08.html" Storage, Dispensing and Use of Flammable Liquids Policy (SY08)  HYPERLINK "http://guru.psu.edu/policies/SY20.html" Hazardous Waste Disposal (SY20) Based on 29 CFR 1910.1450, Occupational exposure to hazardous chemicals in laboratories. ____________________________________________ EXPOSURE This section describes remedies for personal exposure to chemicals by inhalation, ingestion, inoculation, or dermal or eye contact. Additional first aid information for specific chemicals is available from EHS. General procedures are as follows. POISON CONTROL Phone (800) 942-5969 Inhalation: Get to a source of fresh air. Seek immediate medical assistance. Ingestion: Seek immediate medical assistance. Never give an unconscious person anything to drink. Do not neutralize acids or bases. Do not induce vomiting of acid or bases or other solvents unless advised by Poison Control. Injection: Obtain medical treatment immediately. Dermal Contact: Obtain immediate medical treatment. Remove the victim from the source of the contamination. Remove contaminated clothing, cutting it away if necessary. The first aid kit should contain scissors with blunted shear tips for this purpose. Immediately wash affected areas with water for at least 15 minutes. Eye Contact: Obtain immediate medical treatment. Wash eye(s) with water until medical help arrives. Keep the affected eye lower than the unaffected eye to prevent the spread of contamination. Sterile eyewash cups or irrigator loops are commercially available to assist in opening the eyelids without prying or traumatizing the injured eye and causing excess pain. These devices can augment washing of the central portion of the cornea and the superior cul-de-sac where particulate materials may become lodged (thus forming a solid mass). ____________________________________________ SPILLS This section describes the procedures for decontamination in the event of a minor chemical spill onto surfaces, materials, instruments, or equipment. Please address handling of spills of solids and liquids if both are stored in your area. Workers are responsible for the clean-up of releases that are clearly minor, i.e., do not pose a significant safety or health hazard to workers in the immediate vicinity or to the worker cleaning the release. Workers should not handle spills that have the potential to become an emergency within a short time. Minor spills are of limited quantity, exposure potential, or toxicity. 911 should be called in the event of an emergency. Workers shall be properly trained to recognize emergency conditions and to notify appropriate responders for situations that are beyond their own capacity. When a spill occurs, first cordon off the spill area to prevent inadvertently spreading the contamination over a much larger area. Pick up small spills of solids with paper towels wetted with water or an appropriate solvent. Solids may be swept up, if harmful aerosols will not be generated. Place wastes in compatible, sealable containers and dispose of through EHS. Clean instruments or large areas contaminated with solids with an HEPA filter vacuum cleaner to prevent aerosolization of the contaminant. EHS is available to provide information and equipment or supervise clean-up. Wipe up small spills of liquids with paper towels. Use vermiculite or spill pillows to absorb spills. Select and wear the appropriate protective gear during clean-up. Basic gear includes lab coat, gloves, and eye protection. Thicker gloves or double layers may be necessary in some cases. EHS may provide spill equipment if none is present in the lab. ____________________________________________ PROPER WORK AND HANDLING PRACTICES The following practices are considered standard for use or storage of hazardous chemicals, including carcinogens and reproductive toxins. A. Personnel Practices. Eye protection is worn. Gloves are worn for handling hazardous chemicals, including carcinogens, or reproductive toxins. Gloves used are appropriate for the chemicals handled. Workers wash their hands immediately after removing gloves, after handling chemical agents, and before leaving the area. Lab coats are worn, fully fastened. Lab coats and gloves are worn only in the work area. They are not taken outside the area to lunch rooms or offices nor are they worn outdoors. Following a significant chemical exposure to skin or clothing, workers are instructed to use the safety shower immediately. Eating, drinking, smoking, gum chewing, or applying of cosmetics are prohibited in the work areas where chemicals are used. Food storage is prohibited in the work area where chemicals are used. Food is stored in cabinets or refrigerators designated for such use only. B. Operational Practices. All volatile hazardous chemicals are used in a chemical fume hood. All containers of hazardous chemicals are labeled with name of chemical. Abbreviations or formula are not sufficient. Chemical storage is by hazard class. Chemicals are not stored merely by alphabetical order. Chemicals are dated on receipt and opening. Chemicals are removed when the expiration date is exceeded, especially in the case of peroxide-formers. Incompatible materials are physically separated. Flammable materials in amounts exceeding 10 gallons are stored in a flammables storage cabinet. Acids and bases are stored on low shelves or in an acid/base cabinet. Plastic-coated bottles and plastic trays are used to minimize the effects of leaks. Shock-sensitive, detonable compounds (such as sodium azide, dry picric acid) or extremely poisonous materials (such as cyanides, osmium tetroxide, cacodylic acid, tetrodotoxin, picrotoxin, ricin) are stored in locked cabinets. Designated work areas are established for handling materials with a high degree of acute toxicity (such as chemicals with corrosive effects, e.g., nitric, sulfuric and hydrochloric acids, hydrofluoric acid, sodium hydroxide; or chemical asphyxiants such as carbon monoxide and hydrogen sulfide). C. Waste Management. A Waste Management Logbook (Appendix B) containing weekly checks, training records, self inspections, chemical inventories and any other waste records and documentation is maintained in all areas where waste is accumulated. All employees and students working with or supervising those working with chemicals or chemical waste must receive training annually and within 90 days of hire. A waste accumulation area must be designated near the point of waste generation and posted with the sign available in the Waste Management Logbook. An individual working in the area must be assigned the responsibility for oversight of the accumulation area. Weekly when waste is present in the area, the area must be checked for the following Chemicals are not leaking Chemicals are labeled with red labels provide by EHS. Information on the label includes generator name; chemical name, amount and concentration; and room and building where generated. Chemicals are in secondary containment Chemicals are segregate so that incompatible chemicals are not next to each other. The total volume of chemicals in the accumulation area does not exceed 55 gal. Wastes are collected in compatible containers which are sealed. Sharps (razors, needles, thin pipettes) are collected in puncture-resistant, leakproof containers. Waste pump oil is collected for disposal as hazardous waste. Empty solvent bottles are rinsed 3 times with water and then vented in a chemical fume hood for at least 24 hours. After this procedure, the bottles may be recycled or thrown in regular trash. All labels must be defaced prior to disposal of the bottle. D. Specific Practices for Use with Carcinogens and Reproductive Toxins. Work surfaces are covered with plastic-backed paper or its equivalent. Procedures involving volatile, powdered, or aerosolized carcinogens are performed in a chemical fume hood that is exhausted to the outside. Designated work and storage areas are established for carcinogens and reproductive toxins. These areas, including chemical fume hoods and refrigerators, are labeled Chemical Carcinogen. Unbreakable outer (secondary) containers are used for transportation of carcinogens. Access procedures are used if work involves moderate or greater amounts of carcinogens or moderate to lengthy procedures. These procedures may include: closed doors restricted accessonly authorized personnel permitted written access procedures posted on the outer door. Dry sweeping and mopping are prohibited if powdered carcinogens or mutagens (e.g., acrylamide and ethidium bromide) are used. Waste containers for carcinogens are labeled as follows: Cancer Hazard, compound name, concentration, and amount. Solid wastes (e.g., pipette tips, gloves, lab paper) are collected in plastic bags, which are sealed and enclosed in a second bag. The bags are labeled as follows: Cancer Hazard, compound name, concentration, and amount. E. OSHA-Specified Cancer-Causing Agents, alpha-Naphthylamine Methyl chloromethyl ether 3,3-Dichlorobenzidine (and its salts) bis-Chloromethyl ether beta-Naphthylamine Benzidine 4-Aminodiphenyl Ethyleneimine beta-Propiolactone 2-Acetylaminofluorene 4-Dimethylaminoazobenzene N-Nitrosodimethylamine Vinyl chloride Inorganic arsenic Lead Cadmium Benzene 1,2-dibromo-3-chloropropane Acrylonitrile Ethylene oxide Formaldehyde Methylenedianiline 1,3-Butadiene Methylene chloride Asbestos F. Explanation of Medical Surveillance Provisions. If exposure to an OSHA-specified carcinogen is measured to be above the action level or the short-term exposure limit (STEL), certain specific regulatory requirements come into play, one of which is a medical surveillance program. Medical surveillance is intended to determine whether employees are experiencing adverse health effects from exposure to contaminants. It is to be provided without cost to employees and at a reasonable time and place. The parameters of the medical examination are contaminant-specific and primarily determined by or under the supervision of a licensed physician. For example, following a workers potential exposure to lead, the occupational physician will order biological monitoring for blood lead level, as required in the OSHA Lead Standard, but the other exam elements are left to the physicians discretion. The OSHA Formaldehyde Standard requires medical questionnaires to be completed by workers with possible formaldehyde exposure. The physician discerns who needs a physical from reviewing the questionnaires. COMPRESSED GAS CYLINDERS FACT SHEET Based on 29 CFR 1910.1450, Occupational exposure to hazardous chemicals in laboratories, by reference to Prudent Practices in the Laboratory, National Research Council.  HYPERLINK "http://guru.psu.edu/policies/SY25.html" University Safety Policy SY-25 Compressed Gas Cylinders ____________________________________________ PROPERTIES AND HAZARDS Handling compressed gases may be more hazardous than handling solid and liquid materials because of the unique properties of gases. These properties and their associated hazards are: pressure hazards causing equipment failure and leakage rapid diffusion, causing dangerous toxic or anesthetic effects, asphyxiation, and rapid formation of explosive concentrations low boiling-point materials, cryogenic materials, or liquefied gases causing frostbite the same hazards as those associated with solid or liquid chemicals, including corrosion, irritation, flammability, and high reactivity. ____________________________________________ PROPER WORK AND HANDLING PRACTICES A. Storage Practices. The regulator is removed and the valve protection cap is in place when cylinders are stored. Cylinders are situated away from heat and ignition sources. Flammable gases (e.g., hydrogen, carbon monoxide) are stored away from other gases, especially oxidizers (e.g., oxygen and nitrous oxide). Cylinders are situated away from major traffic flow. Cylinders are maintained in an environment at near-room temperatures. They are not subjected to a temperature greater than 125o F or lower than -21o F. Flames never come into contact with any part of a compressed gas cylinder. A valve protection cap is left on each cylinder until it has been properly secured in the lab and when it is not in use (after having been secured). Cylinders are secured in accordance with local fire codes. Cylinders must be secured against a wall or bench with cylinder clamps, chains, or straps, or are placed in a cylinder stand. B. Transportation. Large cylinders are transported only on a wheeled cylinder cart. Cylinders are not slid or rolled, since even practiced handlers can lose control of them. Small cylinders are transported in a manner that protects them from potential damage from falling or striking objects. C. Use of Cylinders. Workers wear eye protection when changing regulators or manipulating tubing or equipment potentially under pressure. Cylinders are situated away from heat and ignition sources. Cylinders are situated away from major traffic flow. Cylinders are maintained in an environment at near-room temperatures. They are not subjected to a temperature greater than 125o F or lower than -21o F. Flames never come into contact with any part of a compressed gas cylinder. Cylinders are used only with a regulator. Cylinders contain pressures greater than most lab equipment can withstand. Cylinder users are aware that inadvertent closing of a valve or stop cock or plugging of a line could result in a violent failure of the apparatus. A regulator and gauge shall be installed at the point of use to show the outlet pressure when the source cylinder is outside of the lab. Cylinder valves are closed when not in use, if feasible. They are never tampered with, forced, lubricated, or modified. Cylinder leaks are attended to immediately. If a leak persists and/or cannot be controlled by simple adjustment, the supplier and EHS are contacted immediately. The cylinder is removed to a chemical fume hood or location where the leakage can be exhausted or diluted and left there until the contents can be disposed of according to manufacturers directions. When discharging a gas into a liquid, a trap or suitable check valve is used to prevent liquid from backflowing into the cylinder or regulator. Cylinders are used only with fittings, valves, regulators, and tubing designated by the manufacturer for the gas being used. Connections are not forced or used with homemade adapters. Incompatible gases linked by a direct potential pathway are protected by check valves or other safety devices appropriate for the gases being used. Ventilation in the use location is adequate to exhaust potential asphyxiant (e.g., carbon dioxide, helium, nitrogen) releases. D. Empty Cylinders. Note: Cylinders are never truly "empty." Empty cylinders shall be handled in the same manner as full and partially full cylinders. Full and empty cylinders are not manifolded together. Empty cylinders are promptly removed from manifolded systems. (Hazardous suckback can occur when an empty cylinder is mistakenly attached to a pressurized system.) Empty cylinders are labeled "Empty" or "MT." Valves are closed on empty cylinders, leaving a positive pressure. (This prevents the interior from becoming contaminated.) Valve outlets and protective caps received with the cylinder are replaced on empty cylinders. E. Specific Procedures for Corrosive Gases. Corrosive gases are stored only for short periods before use, preferably less than three months. Using small cylinders ensures a reasonable turnover. Corrosive gases are removed from areas containing instruments or other devices sensitive to corrosion. Storage areas for corrosive gases are as dry as possible. A supply of water is available in case of emergency leaks in corrosive gas cylinders. (Most corrosive gases can be absorbed in water.) Cylinder valve stems on corrosive gases are manipulated frequently to prevent "freezing." Regulators and valves are closed when corrosive gas cylinders are not in use. Regulators and valves are detached from the cylinder except when it is in frequent use (weekly or daily). When corrosive gases are in use, eyewash is immediately adjacent to the work area. When corrosive gases are in use, a shower is available in close proximity to the work area. The shower must be within 10 seconds travel time of the gas cylinder. Appropriate gloves are worn by lab workers handling corrosive gases. F. Specific Procedures for Using Acetylene Gas. Acetylene cylinders are stored upright (because they are partially filled with acetone). Acetylene cylinders that have not stood upright are used only after they have been upright for at least 30 minutes. The outlet line of acetylene cylinders contains a flash arrestor. Pressures are always maintained below the limit indicated by the red warning line on an acetylene pressure gauge. Appropriate tubing is used with acetylene gas. (Copper tubing forms explosive acetylides and shall not be used.) G. Specific Procedures for Use with Oxygen. When oxygen is used, the cylinder valve is opened momentarily and then closed to blow dirt from the outlet. The valve outlet of an oxygen cylinder valve is never wiped or touched; this avoids leaving organic residues that might be ignited by exposure to high oxygen pressure. Oil or grease is never used on the high-pressure side of oxygen and chlorine cylinders or other cylinders containing oxidizing material. (Otherwise a fire or explosion could result.) H. Specific Procedures for Use with Toxic, Flammable, and Pyrophoric Gases. Toxic gases are purchased and stored in the smallest sizes possible. During use and storage, highly toxic gases are located in continuously ventilated gas cabinets or mechanical spaces. A continuous gas monitoring system is available for signaling releases of highly toxic gases. Lecture bottles of highly toxic gases are used in a chemical fume hood. Flash arrestors are present on the cylinder lines leading from flammable gases. When flammable gases are used in conjunction with oxygen, the flammable gas lines are equipped with backflow protection to prevent mixing of oxygen with the fuel. Fires of pyrophoric or highly combustible gases are not considered extinguished until the source of gas is closed off; otherwise, it can reignite and cause an explosion. APPENDIX B WASTE MANAGEMENT LOGBOOK WASTE MANAGEMENT LOGBOOK ____________________________________________ GENERAL INSTRUCTIONS A. Background Proper handling of surplus and waste chemicals, and contaminated materials is an important part of safety procedures. Each worker is responsible for ensuring that wastes are handled in a manner that minimizes personal exposure and potential for environmental contamination. Each area that generates chemical waste must maintain a Waste Management Logbook where chemical waste is stored. Below is a listing of the required forms that are to be included in the Logbook; copies of those forms immediately follow this list. B. The Waste Management Logbook Contents: Location, Supervisor and Person Responsible for Oversight Acknowledgement of Workers Instructions Lists all people trained to handle hazardous waste Weekly Chemical Waste Review Log Print-out of CHIMS inventory Annual Self Inspection Satellite Accumulation Area Sign  Waste Management Log Book Web address: www.ehs.psu.edu Designated Accumulation Area:  Building & Room Number  Location in Room Supervisor: E-mail  Individual designated to ensure procedures are followed: E-mail  Chemical Storage and Waste Management Acknowledgement of Worker Instructions I hereby acknowledge having received instructions on the safety procedures for chemical storage and waste management, including: log book documentation proper labeling proper segregation non-leaking chemicals chemical containers kept closed when not in use storage limits under 55 gal. chemical review and inventory    safety self audit secondary containment waste disposal procedure policy (SY 20) spill/emergency response procedures use/selection of PPE (Personal Protective Equipment) Chemical Waste Accumulation Area: Weekly Review Log Date CheckedNo Waste in Accumulation area Not currently generating wasteLabeled ProperlySegregated ProperlyNot LeakingSecondary Containment in Place55 Gal Storage Limit Not Exceeded Signature  Print out copy of CHIMS Inventory All chemicals stored must be reviewed annually. Any retained chemicals must be non-leaking, labeled and confirmed to be in good condition with plans to be used in upcoming research.    APPENDIX C UNIT SPECIFIC PLAN UNIT SPECIFIC PLAN ____________________________________________ GENERAL INSTRUCTIONS A. Background. At PSU, two documents comprise the PSU Visual Arts Safety Plan the Safety Manual and the Unit Specific Plan. Together they cover the most salient information needed by workers to protect themselves from workplace hazards. Should you have difficulty preparing the Unit Specific Plan, Please refer to EHS for guidance. Please complete the Visual Arts  HYPERLINK "http://www.ehs.psu.edu/occhealth/unit_specific_plan_form.pdf" Unit Specific Plan Form available on the EHS website. The plan will be reviewed by EHS during routine safety inspections to evaluate whether the types of hazards in your area have been addressed in the plan. EHS has developed a Web site to inform faculty, staff, and students of the safety and compliance programs and the policies and procedures with which they should become familiar while at PSU. This Web site is accessible at HYPERLINK "C:\\Documents and Settings\\kxl3\\Local Settings\\Temporary Internet Files\\sapanski\\My Documents\\chp\\www.ehs.psu.edu"www.ehs.psu.edu. All other EHS documents and programs referred to in this Unit Specific Plan are available through the EHS Web site. B. Specifics for Completion. The Unit Specific Plan Form consists of the follow sections: Activities Overview Safety Infrastructure Chemical Safety Safety Precautions in Place Certification of Agreement Appendices The Activities Overview and Certification of Agreement sections are required from every principal investigator who supervises or has responsibility for a visual arts area or group of areas. Workers must read the Unit Specific Plan as an element of initial safety training. Section V must be signed by everyone working in the area group. New workers who join the group after the Unit Specific Plan has been finalized must read and sign the form as an element of initial safety training. The first segment of the Unit Specific Plan should consist of Fact Sheets (located in Appendix A) for the various safety topics of concern. The Fact Sheets summarize standard University guidelines for prudent practice within visual arts areas. Faculty, staff, and students shall familiarize themselves with the guidelines contained on the following Fact Sheets: Emergency Response Training Fact Sheet Chemical Safety Fact Sheet Compressed Gas Cylinders Fact Sheet Please answer all questions and do not leave any blanks. If a question has no connection to the work in your area(s), please write NA or not applicable next to the answer. You are not confined to the boxes for your responses. If you wish to add additional information, attach separate sheets for elaboration. The Unit Specific Plan shall be formally reviewed by the PI on an annual basis. Annually you must complete the Annual Review form. The Unit Specific Plan shall be kept current between Annual Reviews. Whether seen by EHS or not, the Unit Specific Plan shall reflect new or modified tasks and procedures which affect occupational exposure and new or revised employee positions with occupational exposure. The Unit Specific Plan and its component Fact Sheets shall be made available to workers and must be readily available at all times. Please call EHS with any questions or comments regarding the Unit Specific Plan process. Thank you for your time and effort in supporting this important safety tool. EHS will be glad to meet with you if you have difficulty with the plan. C. Information for Contacting EHS. 6 Eisenhower Parking Deck University Park, PA 814-865-6391 FAX 814-863-7427  HYPERLINK http://www.ehs.psu.edu www.ehs.psu.edu   PAGE 21 Emergency Response Training Fact Sheet, Rev. 1-2000 Chemical Safety Fact Sheet, Rev. 1-2000 Chemical Safety Fact Sheet, Rev. 1-2000 Compressed Gas Cylinders Fact Sheet, Rev. 1-2000   EMBED Word.Document.8 \s Specific training topics: Plan to designate specific location of waste accumulation Ensure documentation is maintained; check labeling, non-leaking chemicals, storage, and containment limits weekly How to fill out chemical disposal form and proper procedure for disposal of chemicals Segregation of chemicals into categories: flammable, bases, and acids in separate storage pans Chemicals are labeled and closed when not in use Storage limit (55 gallons) not exceeded Spill/ emergency response procedures Use/selection of PPE (Personal Protective Equipment) Maintain inventory in CHIMS, review chemicals annually: document date reviewed, whether chemical is retained or disposed of, and explanation Self-audit established by your research group. ______________________________________________ ___________________________________________ Name (Last, First, Middle Initial) Signature ______________________________________________ ___________________________________________ Date of Training Trainer SATELLITE ACCUMULATION AREA Please Post Do you know your responsibilities for proper handling of hazardous waste? Please review the following requirements to ensure that you comply with environmental regulations and safe handling procedures. TRAINING: Environmental regulations require training of people who generate or handle hazardous waste. Training must take place within 90 days of date-of-hire; and annually thereafter. Training is offered on a regular schedule by Environmental Health and Safety (EHS). Check EHS Homepage www.ehs.psu.edu for available dates and times. ______________________________________________________________________________________ CONTAINER LABELING AND SECONDARY CONTAINMENT: All hazardous waste containers must have a red waste tag at the time waste is first placed into the container. The red Chemical Disposal Label must accurately identify the content of the container. All containers must also be stored in plastic bins to catch any leakage. EHS supplies secondary containers and red tags. Call EHS if you need supplies or additional information. ______________________________________________________________________________________ CONTAINER CLOSURE: Hazardous waste containers must be closed at all times during storage, except when waste is being added or removed. Keep containers closed. Regulations do not permit open funnels in waste Containers when not in use. ______________________________________________________________________________________ STORAGE: For safety and environmental reasons, hazardous waste must be stored in a designated "Satellite Accumulation Area". These areas must be inspected weekly for container leakage, labeling, chemical compatibility and to determine that total volume does not exceed 55 gallons. If you have full waste containers, please fill out a Chemical pick up request available on our web page, www.ehs.psu.edu. _`ky # ) * - . ? 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__________________________________________________________________________________________ OPERATE MOST FIRE EXTINGUISHERS 1. PULL Pull the pin (Some units may require pressing a puncture lever) 2. AIM Aim the nozzle or horn at the base of the flames 3. SQUEEZE Squeeze or press the handle 4. 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