ࡱ> ILH[ Ebjbj  4Hpa!\pa!\BBT", 2NNNNN)))wyyyyyy$N"%:9)))))NN)bNNw)wNzV6c0 >%>%>%)))))))))) ))))>%)))))))))B> : @9Concepts of Class-XI which are very often used in Class-XII ( Which needs to be mastered in CLASS XI for better performance in Class-XII) by A K PANDA (Stars are degree of importance-Rating scale) 1# Some Basic concepts of Chjemistry( Priority-1) Calculation based on Molarity , Molality , Mass Percentage , Mole Fraction , ppm , (P-1921) Mole concepts and Molar masses (P-15) ** Calculation based on stoichiometry equations . 2# Structure of atom ( Priority-2) ** Idea of writing electronic configuration *** Shape of orbitals *** Degenerate orbitals *** Effective Nuclear Charge *** screening effect *** Penetrating power of different orbitals ** Stability of completely filled and half filled subshell *** Paulis , Hunds , aufbaus Principle 3# Classification of elements and periodicity in properties ( Priority-1) *** Electronic configuration of d-block elements ( first row TM) , Lanthaniods and Actinoids (with At. No.) *** Remembering p-block elements (all groups) *** Characteristics of all four block elements , *** Electronegativity , Electron gain enthalpy , Ionisation energy , Atomic radii / Ionic radii , acidic and basic character of oxides ( and their application questions ) **** trends of periodic properties across a period and down the group (P-88.89,90,91) # *** Anomalous properties of second period elements (P-90)--- [Absence of vacant d-orbital , multiple bond formation , Sigma bond strength of FF , OO , NN , Catenation properties , Electron gain enthalpy of F2 and Cl2 etc. ] 4# Chemical Bonding And Molecular structure : ( Priority-1) ** VSEPR Theory ( Predicting the shape and geometry of various molecules) *** Hybridisation Treatment *** Resonance and Resonating structures -- Understanding the conditions of stability of resonating structure ( various application Questions) ** Polarity of Bonds (P-106-107) -- Polar and non-polar moleculesBond dipole and dipole moment of molecule ( BF3 , H2O , CO2 , NF3 , NH3 ) ** Difference between Sigma bond and Pi bond ** Calculation of no. of Sigma bond and Pi bond ** Hydrogen bonding and its types and various application Questions ** Bond Parameters -- Bond order , Bond enthalpy , Bond Order , bond Length , Bond Angle 5# States of Matter ( Priority-2) ***Intermolecular forces(P-133--136) ** Isotherm , isobar , isochore ** Vapour pressure Boiling point , std. and normal BP ** evaporation and vaporization ** Critical Temperature *** Vapour pressure Vs Temperature Curve *** Ideal Gas Equation 6# Thermodynamics ( Priority-2) ** Enthalpies of different types of reaction s Std. enthalpy of combustion , Std. enthalpy of formation , Std. enthalpy of reaction *** Enthalpy of atomization ,Bond Enthalpy , Lattice enthalpy , Hydration Enthalpy . Enthalpy of solution , *** Spontaneity Enthalpy and entropy , Gibbs Free Energy of reaction 7# Equilibrium ( Priority-2) *** Idea about dynamic equilibrium , Rate law expression , Law of mass action , Relation between Kc and Qc , Kp andc Kc **** Le Chateliers Principle and its application *** Different concepts of Acids and BasesLewis , Bronsted , Arrhenius **** Conjugate Acid Base pair ( PN-206210) ** PH calculation . * knowledge about Ka , Kb , Kw Pka , PKb . Pkw , Ksp ( Solubility Product) , common ion effect 8# REDOX REACTIONS ( Priority-1) *** ** Understanding the concept of Redox Reactions ( both oxidation and Reduction half cell reaction) **Calculation of Oxidation number ( deal some special cases H2O2 , NaH , Cr2O5 , H2S2O5 , CaOCl2 ) ** Identification of oxidizing and reducing agent in a given reaction ** Types of redox reactions Combination , Decomposition , Displacement , Disproportionation Reactions *** Competitive electron transfer reactions -- Metal activity or elctrochemical series *** Balancing of redox reactions -- half reaction method ( Ion electron method ) in acidic and basic medium *** Redox reactions as the basis for Titrations *** Redox reactions and electrode processes -- Feasibility of Redox couple , *** Standard Hydrogen electrode , Standard electrode potential **** Cell Representation , carriers of current , Sign of electrode , Half cell reaction . 9# HYDROGEN ( Priority-2) **Hydrides Ionic , covalent , Interstitial **Hard and soft water temporary and permanent hardness . removal technique , **Effectiveness of soap and detergent 10# The s-BLOCK ELEMENTS ( Priority-2) ** Anomalous properties of Li and Be *** diagonal relationship between Li&Mg , Be & Al *** Ionisation enthalpy , Hydration enthalpy , Polarizing power , Fajans Rule ionic and covalent character Reducing Nature , SolubilityHydroxide , carbonates , sulphates 11# THE p-BLOCK ELEMENTS ( Pn-307325) ( Priority-1) ** Inert pair effect ** Anomalous properties ** Catenation properties ** use of Anhydrous AlCl3 . LiAl H4 Trends in physical and chemical properties . 12# ORGANIC CHEMISTRY -- Some Basic Principles ( Priority-1) *** ** IUPAC Naming and structure including all functional group , ( some common names ) ** Isomerismgeometrical , Structural ** Classification of Organic compounds ** Fundamental concept of Organic reaction mechanism # Homolytic and Heterolytic cleavage # Nucleophiles and electrophiles # Electron movement in organic reactions # Electron Displacement Effect In Covalent Bond (i) Inductive effect ( +I and I effect) *** (ii) Resonance Structure Rules while resonance Structure , Predicting the stable resonating structure , Hybrid Structure Resonance Effect ( + R and - R effect ) *** *** Hyperconjugation *** Reactive Intermediates # Stability of carbocation , Carboanion , free radicals , alkenes *** Types of Organic Reaction and its Mechanism [ Substitution SN1 and SN2 , Addition Reaction - AdE and and , Elimination Reaction alpha and beta , Rearrangement , Polymerisation and Condensation Reaction ] 13# HYDROCARBONS***( Priority-1)- Every concepts mentioned here are repeated in class- xii) # Wurtz Reaction , Dumas Decarboxylation Reaction , Markovnikov Rule , Kharash Effect (Peroxide effect ) #Ozonolysis , Polymerisation and cyclic Polymerisation , Aromatization , Isomerisation , bayers reagent , lindlars catalyst , dehydrohalogenation Reaction -elimination of haloalkanes ( Saytzeff Rule) Aromaticity , Resonance and stability of Benzene # Electrophilic substitution Reactions-- Friedel Craft Reaction  alkylation and Acylation ,. 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