ࡱ> kmhij :bjbjWW 455W)55555IIII-I=0.67Td7,m|a570.67755\\\\\\755\\7\\\\.XH0>IF@ 0=8F\5h77\\77777\\777=7777777777777 : Chapter 1,2 and 6 ( Do WS 1, 3 and 4, WS 2 and 5 OPTIONAL) Electronic Structure Worksheet 1 Given the following list of atomic and ionic species, find the appropriate match for questions 1-4. (A) Fe2+ (B) Cl (C) K+ (D) Cs (E) Hg+ 1. Has the electron configuration: 1s2 2s2 2p6 3s2 3p6 3d6. 2. Has a noble gas electron configuration. 3. Has electrons in f orbitals. 4. Is isoelectronic with gold. 5. Which of the following combinations of particles represents an ion of net charge -1 and of mass number 82? (A) 46 neutrons, 35 protons, 36 electrons (B) 46 neutrons, 36 protons, 35 electrons (C) 46 neutrons, 36 protons, 36 electrons (D) 47 neutrons, 35 protons, 35 electrons (E) 47 neutrons, 35 protons, 36 electrons 6. One species of element M has an atomic number of 10 and a mass number of 20; one species of element N has an atomic number of 11 and a mass number of 20. Which of the following statements about these two species is true? (A) They are isotopes. (B) They are isomers. (C) They are isoelectronic (D) They contain the same number of neutrons in their atoms. (E) They contain the same total number of protons plus neutrons in their atoms. 7. Which of the following is not a physical property of a substance? (A) density (B) solubility (C) melting point (D) reaction with oxygen (E) boiling point 8. Which of the following could be an isotope of chlorine? (A) 37Cl17 (B) 17Cl17 (C) 37Cl17 (D) 17Cl37.5 (E) 17Cl37 9. For a neutral As atom in the ground state, how many electrons have quantum numbers n = 4, l = 1? (A) 2 (B) 3 (C) 4 (D) 5 10. The electron configuration that is impossible is: (A) 1s2 2s2 2p6 (B) 1s2 2s2 2p3 (C) 1s2 2s2 2p6 3s1 (D) 1s2 2s2 2p6 3s2 (E) 1s2 2s2 2p6 2d2 11. A neutral atom has an atomic number of 30 and a mass number of 62, the atom must contain: (A) 92 neutrons (B) 62 electrons (C) 29 neutrons (D) 30 electrons . 12. Atom X has 12 protons, 12 electrons, and 13 neutrons. Atom Y has 10 protons, 10 electrons, and 15 neutrons. It can therefore be concluded that: (A) atoms X and Y are isotopes. (B) atom X is more massive than atom Y. (C) atoms X and Y have the same mass number. (D) atoms X and Y have the same atomic number. 13. Which set of quantum numbers (n, l, ml , ms ) represents the outermost electron in a gaseous aluminum atom? (A) 2, 1, 0, +1/2 (B) 2, 1, -1, +1/2 (C) 3, 0, 0, +1/2 (D) 3, 1, -1, +1/2 14. Which species is paramagnetic in the gaseous state? (A) Cu (B) Zn2+ (C) Sn2+ (D) Cr3+ 15. A neutral atom which has 42 electrons and a mass number of 93 has (A) an atomic number of 51. (B) a nucleus containing 51 neutrons. (C) a nucleus containing 40 neutrons. (D) a nucleus containing 51 protons. 16. A sodium ion, Na+ , contains the same number of electrons as (A) a sodium atom, Na. (B) a magnesium atom, Mg. (C) a potassium ion, K+ . (D) a neon atom, Ne. Electronic Structure Worksheet 2 1. If two atomic species are isotopes, then (A) both atoms must have identical nuclei. (B) the nuclei of both atoms contain the same number of neutrons. (C) the nuclei of both atoms contain the same number of protons. (D) both atoms must have the same mass. 2. What is the maximum number of electrons that can have a principal quantum number of 3 within one atom? (A) 3 (B) 8 (C) 18 (D) 32 3. Which atom is paramagnetic in the gaseous state? (A) K (B) Ca (C) Zn (D) Kr 4. The partial symbol for a particular ion is 26M2+ . The number of electrons contained in one of these ions is (A) 2 (B) 10 (C) 12 (D) 24 5. How many unpaired electrons are found in the most stable electronic state (ground state) of a sulfur atom? (A) 0 (B) 2 (C) 4 (D) 6 6. The electron configuration for Mn2+ is: (A) [Ar]4s2 3d3 (B) [Ar]3d5 (C) [Ar]4s1 3d5 (D) [Ar]4s1 3d4 7. Which set contains three isoelectronic species? (A) Zn, Cd, Hg (B) Br+ , Kr, Rb- (C) P3- , Se2- , I- (D) F- , Na+ , Mg2+ 8. Which of the following refers to the ground-state electron configuration of an atom? (A) 1s1 2s1 (B) [Kr]5p1 (C) [Ne]3s1 3p2 (D) [Ar]4s2 3d6 9. The maximum number of electrons in an atom that can have quantum numbers n = 2, l = 1 is: (A) 2 (B) 6 (C) 8 (D) 4 10. Which of the following pairs contains isoelectronic species? (A) Na and Mg+ (B) P- and Se (C) N2- and Ne (D) O2- and Na+ 11. Which species is diamagnetic in the ground state? (A) N (B) Zn2+ (C) Cu2+ (D) O- 12. An atom of iron-56, Fe56, contains (A) 26 electrons, 26 protons, 56 neutrons (B) 56 electrons, 26 protons, 26 neutrons (C) 56 electrons, 56 protons, 26 neutrons (D) 26 electrons, 26 protons, 30 neutrons 13. What is the maximum number of electrons that can occupy the 5f subshell? (A) 10 (B) 14 (C) 7 (D) 2 14. Ca40, K39, and Ti 42all have the same (A) number of electrons. (B) atomic number. (C) mass number. (D) number of neutrons. 15. Element X, whose atoms have an outer-shell electron configuration ns2 np3 , is most likely to react chemically to form ions which have a charge of (A) +3 (B) + 1 (C) -3 (D) -2 Electronic Structure Worksheet 3 1. What is the atomic number of the first element in the periodic table to have a filled d orbital? (A) 30 (B) 2 (C) 2 (D) 29 2. Which atom or ion is given with an excited outer electron configuration? (A) Na: 3s1 (B) B: 2p3 (C) He: 1s2 (D) H-1 : 1s2 3. Which of the following represents the ground state electron configuration of the oxygen atom? 1s 2s 2p (A) !! !! ! ! ! (B) !! !! !! !! !! (C) !! !! !! !! ! (D) !! !! !! ! ! 4. What is the wavelength of the radiation emitted from a mercury arc sunlamp if the frequency of the radiation is about 1.2 x 1015 sec-1 ? (c = 3.0 x 1010 cm/sec) (A) 2.0 x 10-5 cm (B) 4.0 x 10-4 cm (C) 2.5 x 10-6 cm (D) 2.5 x 10-5 cm 5. How many unpaired electrons are there in the Ti3+ ion? (A) 0 (B) 2 (C) 1 (D) 4 6. The quantum numbers 3, 1, -1, +1/2 (A) refer to an electron in the p orbital of the 3rd shell. (B) refer to an electron in the p orbital of the 2nd shell. (C) refer to an electron in carbon. (D) refer to an electron in the s orbital of the 3rd shell. 7. The charge on the nucleus of a Mg2+ ion is (A) +2 (B) +10 (C) +12 (D) 2 8. The sublevel that can be occupied by a maximum of 10 electrons is identified by the letter (A) d (B) f (C) p (D) s 9. An orbital may never be occupied by (A) 1 electron (B) 2 electrons (C) 3 electrons (D) 0 electrons 10. Which particle consists of 13 protons, 14 neutrons, and 10 electrons? (A) neon atom (B) sodium atom (C) aluminum ion (D) silicon atom 11. The number of orbitals in the 2nd shell of an atom is (A) 1 (B) 9 (C) 16 (D) 4 12. The first element in the periodic table having the first completed p orbital is (A) He (B) Be (C) O (D) Ne 13. One of the outermost electrons in a strontium atom in the ground state can be described by which of the following sets of four quantum numbers? (A) 5, 2, 0, (B) 5, 1, 1, (C) 5, 1, 0, (D) 5, 0, 1, (E) 5, 0, 0, 14. All of the following attempts to write a ground state electronic configuration are incorrect except for one. The correct one is (A) [Ne]3s2 3p6 3d10 (B) [He]2s2 2p3 (C) [Ne]3p3 (D) [Ne]3s2 3p8 15. The energy levels of the hydrogen atom are related to the principle quantum number by: (A) E = k/n (B) E = k/n2 (C) E = kn (D) E = kn2 16. How many atomic orbital configurations that satisfy Hunds Rule can be written for the 1s2 2s2 2p2 structure of the carbon atom such that all the p electrons have a spin quantum number of +1/2? (A) 1 (B) 2 (C) 3 (D) 4 Electronic Structure Worksheet 4 1. The first line in the hydrogen spectrum is very difficult to see and it's the kind of light that causes skin cancer. It is a dark purple color with a wavelength of 410.18 nm. Calculate: (A) the frequency of this light. (B) the change in energy that produces this color. h = 6.626 x 10-34 Js/particle c = 2.998 x 108 m/s 2. Which of the following would have the higher ionization energy? (A) K+ or Ca (B) S2- or Cl- (C) O or S (D) O or N (E) P or O 3. Which of the following has the more metallic character? (A) Pb or Rb (B) At or Ar (C) Na or Fr 4. Match the species in the left column with the isoelectronic ion or atom from the right. (A) H- ______ I. Ga3+ VIII. Y3+ (B) Se2- ______ II. Al3+ IX. Cu (C) In+ ______ III. Ti2+ X. Te2- (D) Ar ______ IV. Ag+ XI. Mn4+ (E) Zn2+ ______ V. P3- XII. Be2+ (F) Na+ ______ VI. Ni (G) Cs+ ______ VII. Cd 5. Which atom has a ground state p3 electronic configuration? (A) Mg (B) Ga (C) Al (D) P 6. The ion that has the ground state electronic configuration of [Ne]3s2 3p3 is (A) Si+1 (B) Al+3 (C) S+1 (D) Cl1 7. The number of orbitals in a d sublevel is (A) 1 (B) 3 (C) 7 (D) 5 8. What is the correct set of quantum numbers for the highest energy electron of Na? (A) 3, 0, 0, 1/2 (B) 3, 1, 0, 1/2 (C) 3, 1, -1, -1/2 (D) 1,0, 0, -1/2 9. An atom of element X absorbs a photon and an electron is transferred from the ground state to a higher energy level. Which of the following represents such a transition? (A) n = 2 to n = 4. (B) n = 3 to n = 1. (C) n = 1 to n = -5 (D) n = 1 to n = 3. (E) n = 0 to n = 2. 10. Which of the following sets of quantum numbers is not possible? (A) 3, 1, 0, 1/2 (B) 1, 1, 0, -1/2 (C) 2, 1, 1, 1/2 (D) 4, 2, -2, -1/2 (E) 2, 1, 0, 1/2 11. Ni2+ is isoelectronic with which of the following species? (A) Mn (B) Fe1+ (C) V3+ (D) Co1+ (E) Ar 12. The exceptions to the Aufbau principle are explained by (A) no two electrons can have the same quantum numbers. (B) the merging of orbitals between two sublevels (C) an increase in the stability of the electron configuration. (D) the Bohr model's inability to deal with many-electron systems. Electronic Structure Worksheet 5 1. Explain briefly why the emission spectrum of a hydrogen atom is comprised of discrete lines instead of a continuous broad band of emitted light. 2. List all the possible values of the angular quantum number, l, for a principle quantum number 4. Describe the difference between orbitals for each of the values of l. 3. There are simple mathematical relationships for the number of orbitals in a particular shell and the number of electrons in a shell. Derive them. 4. Elements may be synthetically created and it is theoretically probable that element 120, when created or perhaps discovered, will be more stable than the recent additions to the periodic table, elements103 - 109. Basing your answer on the electronic configuration of the molecule, in which group will element 120 reside? 5. Identify the quantum number that specifies each of the following things. (A) The spatial orientation of the orbital. (B) The spin of the electrons that occupy the orbital. (C) The size of the orbital. (D) The shape of the orbital. 6. Atoms and molecules can emit and absorb light (electromagnetic radiation). Describe both of these processes and how they affect the electronic stability of atoms or molecules. 7. Give the symbols for the element of lowest atomic number whose ground state has: (A) a completed p sublevel. (B) four 4d electrons. (C) five f electrons. (D) two 3s electrons. (E) eight electrons in its valence shell 8. In the photoelectric effect, photons strike the surface of a metal and electrons are emitted from the metal. Describe why the photoelectric effect reinforces quantum theory and calculate the speed of an electron emitted from lithium by a photon with wavelength 420 nm. (h = 6.63 x 10-34 Js work function lithium = 2.3 eV) 9. The hydrogen emission spectrum is characterized by several series of sharp emission lines in the infrared (Paschen series, Brackett series, etc.), visible (Balmer series) and ultraviolet (Lyman series) portions of the electromagnetic spectrum. (A) How is the discrete nature of the emission spectrum of hydrogen explained in terms of the electronic energy levels of the hydrogen atom. (B) Account for the existence of several series of lines in the spectrum. What quantity distinguishes one series of lines from another? (C) Draw an electronic energy level diagram for the hydrogen atom and indicate on it the transition corresponding to the line of lowest frequency in the Lyman series. (D) What is the difference between an absorption spectrum and an emission spectrum? (E) At room temperature the absorption spectrum of the hydrogen atom exhibits only the transitions of the Lyman series. Explain this. 10. The Heisenberg Uncertainty Principle and deBroglie's ideas of the wave-particle duality of matter are two founding concepts for the quantum mechanical picture of electrons in atoms. (A) State the Heisenberg uncertainty principle with respect to its determining the position and momentum of an object. (B) What part of the Bohr theory of the atom is considered unrealistic as a result of the Heisenberg uncertainty principle? (C) Explain why the Heisenberg uncertainty principle or the wave nature of particles is not a practical way of examining the behavior of macroscopic objects, but becomes most significant when describing the behavior of electrons or systems on a very small scale. Electronic Structure Worksheet Answer Key WORKSHEET 1 1) A 2) C 3) E 4) E 5) E 6) E 7) D 8) E 9) B 10) E 11) D 12) C 13) D 14) D 15) B 16) D WORKSHEET 2 1) C 2) C 3) A 4) D 5) B 6) B 7) D 8) D 9) B 10) D 11) B 12) D 13) B 14) D 15) C WORKSHEET 3 1) D 2) B 3) D 4) D 5) C 6) A 7) C 8) A 9) C 10) C 11) D 12) C 13) E 14) B 15) B 16) C WORKSHEET 4 1a) 7.31 x 1014 s-1 , b) 4.843 x 10-19 J 2a) K+ , b) Cl- , c) O, d) N, e) O 3a) Rb, b) At, c) Fr 4a) XII, b) VIII, c) VII, d) V, e) I, f) II, g) X 5) D 6) C 7) D 8) A 9) D 10) B 11) D 12) C WORKSHEET 5 1) Energy is quantized: electrons can only have certain energies. When an electron makes a transition from a higher energy level to a lower energy level, the excess energy may be released in the form of light. The frequency of the light depends on the energy difference between the levels. Since electrons occupy only specific energy levels, only specific differences (and thus only certain frequencies) will result. So you see line spectra corresponding to those frequencies. 2) n = 4 allows for 4 values of L L = 0 corresponds to an s-orbital, the shape is spherical, there is 1 s-orbital L = 1 corresponds to a p-orbital, the shape is dual-lobe along the 3 axes; 3 p-orbitals L = 2 corresponds to a d-orbital, the shape is multi-lobe in the 3 planes; 5 d-orbitals L = 3 corresponds to an f-orbital, the shape is multi-lobe in the 3 planes; 7 f-orbitals 3) n2 , 2n2 4) IIA (Alkaline earth metals) 5a) m l , b) m s , c) n, d) l 6) energy transitions, ionization energy, excited state stability 7a) Ne, b) Mo, c) Pm, d) Mg, e) Ne 8) a) 5.8x106 m/s b) Photon energy is quantized. No electrons are ejected unless the photons have the threshold energy or greater. 9) a) Same answer as question 1. b) In a series, all transitions are from some higher energy level to the same final level. The final energy level distinguishes one series from another. c) The lowest energy transition is equal to the lowest frequency transition. For the Lyman series, the final state is n = 1. d) In an absorption spectrum, energy is absorbed by the system to raise electrons from lower levels to higher levels. The spectrum that results will have some part for the input light subtracted out those frequencies corresponding to the energy level gaps of the system. An emission spectrum is energy being released in the form of light when electrons make transitions from higher levels to lower ones. e) At room temperature, essentially all electrons are in the ground state. Thus they can make transitions from the ground state to higher states (Lyman series). There are no electrons in excited states so there are no transitions from excited state to excited state. 10) a)xp >= h b) Electrons cannot be confined to specific orbits. c) The mass(momentum) of macroscopic particles is so many orders of magnitude larger than that of Planks constant that the uncertainty principle is not relevant (although its still valid). Chapter 3 Stoichiometry (Credit: HYPERLINK "http://www.education.com/study-help/article/stoichiometry-review-questionsanswers-explanations/"http://www.education.com/study-help/article/stoichiometry-review-questionsanswers-explanations/, HYPERLINK "http://misterguch.brinkster.net/practicefinal.pdf"http://misterguch.brinkster.net/practicefinal.pdf) 1. A sample of oxalic acid, H2C2O4, is titrated with standard sodium hydroxide, NaOH, solution. A total of 45.20 mL of 0.1200 M NaOH is required to completely neutralize 20.00 mL of the acid. What is the concentration of the acid? 0.2712 M 0.1200 M 0.1356 M 0.2400 M 0.5424 M 2. __C4H11N(1) + __O2(g) !__CO2(g) + __H2O(l) + __N2(g) When the above equation is balanced, the lowest whole number coefficient for O2is: 4 16 22 27 2 3. When the following equation is balanced, it is found that 1.00 mol of C8H18reacts with how many moles of O2? __C8H18+ __ O2! __ CO2+ __ H2O 1.00 mol 10.0 mol 25.0 mol 37.5 mol 12.5 mol 4. 2CrO42 + 3SnO22 + H2O ! 2 CrO2 + 3 SnO32 + 2 OH How many moles of OH form when 50.0 mL of 0.100 M CrO42 is added to a flask containing 50.0 mL of 0.100 M SnO22 ? 0.100 mol 6.66 103mol 3.33 103mol 5.00 103mol 7.50 103mol 5. Gold(III) oxide, Au2O3, can be decomposed to gold metal, Au, plus oxygen gas, O2. How many moles of oxygen gas will form when 221 g of solid gold(III) oxide is decomposed? The formula mass of gold(III) oxide is 442. 0.250 mol 0.500 mol 1.50 mol 1.00 mol 0.750 mol 6. If we want to make 150 grams of sodium sulfate by reacting ammonia with sulfuric acid, how much ammonia will be needed? a) 19.3 grams b) 38.6 grams c) 77.2 grams d) none of these 7. If the theoretical yield for a reaction was 156 grams and I actually made 122 grams of the product, what is my percent yield? a) 78.2% b) 128% c) 19.0% d) none of these 8. Hydrochloric acid reacts with calcium to form hydrogen and calcium chloride. If 100 grams of hydrochloric acid reacts with 100 grams of calcium chloride, what is the limiting reagent? a) hydrochloric acid b) hydrogen c) calcium chloride d) calcium 9. For the reaction in the previous problem, how much of the nonlimiting reagent will be left over after the reaction is complete? a) 54.8 grams b) 45.2 grams c) 2.74 grams d) none of these 10. How many grams of carbon dioxide will be formed when 100 grams of CH4 is burned in oxygen? a) 122 grams b) 244 grams c) 488 grams d) none of these Chapter 3 Continued Percent Composition (Credit: HYPERLINK "http://www.education.com/study-help/article/stoichiometry-review-questionsanswers-explanations/"http://www.education.com/study-help/article/stoichiometry-review-questionsanswers-explanations/) 1. Manganese, Mn, forms a number of oxides. A particular oxide is 63.2% Mn. What is the simplest formula for this oxide? MnO Mn2O3 Mn3O4 MnO2 Mn2O7 2. Nitrogen forms a number of oxides. Which of the following oxides is 64% nitrogen? N2O5 N2O4 N2O3 N2O2 N2O 3. Sodium sulfate forms a number of hydrates. A sample of a hydrate is heated until all the water is removed. What is the formula of the original hydrate if it loses 43% of its mass when heated? Na2SO4H2O Na2SO42H2O Na2SO46H2O Na2SO48H2O Na2SO410H2O 4. The percent composition of aluminum in aluminum (III) hydroxide is: a. 50% b. 25% c. 14% d. none of these answers is correct Stoichiometry C D E C E B A B B B Percent Composition D E C D Chapter 4 Reactions Worksheet Use appropriate ionic and molecular formulas to show the reactants and the products for the following, each of which results in a reaction occurring in aqueous solution except as indicated. Omit formulas for any ionic or molecular species that do not take part in the reaction. You need not balance. In all cases a reaction occurs. 1. Dilute sulfuric acid is added to a solution of barium acetate. 2. Ammonium chloride crystals are added to excess water. 3. A solution of hydrogen peroxide is catalytically decomposed. 4. Powdered iron is added to a solution of iron III sulfate. 5. Chlorine gas is bubbled into a solution of sodium bromide. 6. A precipitate is formed when solutions of trisodium phosphate and calcium chloride are mixed. 7. A solution containing tin(II) ions is added to an acidified solution of potassium dichromate. 8. Liquid bromine is added to a solution of potassium iodide. 9. An excess of ammonia gas is bubbled through a solution saturated with silver chloride. 10. Water is added to a sample of pure sodium hydride. 11. A dilute solution of sulfuric acid is electrolyzed between platinum electrodes. 12. Excess oxygen gas is mixed with ammonia gas in the presence of platinum. Reactions Answer Key 1) Ba2+ (aq) + 2 C2H3O2 - + 2H+ + SO42- (aq) ( BaSO4(s) + 2 HC2H3O2 ppt. reaction. 2) NH4 + (aq) + H2O (l) ( NH3(aq) + H3O+ (aq) weak acid in water 3) H2O2(aq) ( H2O (l) + O2(q) decomposition 4) Fe3+ (aq) + e- ( Fe2+ (aq) redox reaction. 5) Cl 2(aq) + Br - (aq) ( Cl - (aq) + Br 2(aq) redox reaction. 6) Ca+2(aq) + PO43-(aq) ( Ca3(PO4)2(s) ppt. reaction. 7) 14H+(aq) + 3Sn2+(aq) + Cr2O72- (aq) ( 3Sn 4+ + 2Cr 3+ + 7H 2 O (l) redox reaction. 8) Br2(l) + KI(aq) ( KBr(aq) + I2(aq) substitution reaction. 9) Ag+(aq) + NH3(aq) ( Ag(NH3)2+ complex ion formation 10) NaH(s) + H2O(l) ( Na+ (aq) + OH- (aq) + H2(g) metallic hydride in water forms a basic solution. 11) H2O(l) ( O2(g) + H2(g) (leave this question) decomposition. 12) O2(g) + NH3(g) ( NO2(g) + H2O(g) combustion. Chapter 5 Thermochemistry Thermochemistry (Credit: HYPERLINK "http://www.jasonjones.co/jasonjones.co/tccd/chem1412docs/exam4/Thermo%20Review%20Problems%20answers.pdf"http://www.jasonjones.co/jasonjones.co/tccd/chem1412docs/exam4/Thermo%20Review%20Problems%20answers.pdf) CH4(g) + 2O2(g) ( CO2(g) + 2H2O(l) H = -889.1 kJ Hf H2O(l) = -285.8 kJ Hf CO2(g) = -393.3 kJ What is the standard heta of formation of methane, Hf CH4(g), as calculated from the data above? -210.0 kJ/mole -107.5 kJ/mole -75.8 kJ/mole 75.8 kJ/mole 210.0 kJ/mole A cube of ice is added to some hot water in a rigid, insulated container, which is then sealed. There is no heat exchange with the surroundings. What has happened to the total energy and the total entropy when the system reaches equilibrium? Energy Entropy Remains Constant Remains Constant Remains Constant Decreases Remains Constant Increases Decreases Increases Increases Decreases When solid ammonium chloride, NH4Cl(s), is added to water at 25C, it dissolves and the temperature of the solution decreases. Which of the following is true for the values of H and S for the dissolving process? H S Positive Positive Positive Negative Positive Equals to Zero Negative Positive Negative Negative Which of the following reaction has the largest positive value of S per mole of Cl2? H2(g) + Cl2(g) ( 2HCl(g) Cl2(g) + O2(g) ( Cl2O(g) Mg(s) + Cl2(g) ( MgCl2(s) 2NH4Cl(s) ( N2(g) + 4H2(g) + Cl2(g) Cl2(g) ( 2Cl(g) For which of the following processes would S have a negative value? 2Fe2O3(s) ( 4Fe(s) + 3O2(g) Mg2+ + 2OH- ( Mg(OH)2(s) H2(g) + C2H4(g) ( C2H6(g) I only I and II only I and III only II and III only I, II, and III Which of the following must be true for a reaction that proceeds spontaneously from initial standard state conditions? G > 0 and Keq > 1 G > 0 and Keq < 1 G < 0 and Keq > 1 G < 0 and Keq < 1 G = 0 and Keq = 1 N2(g) + 2H2(g) ( 2NH3(g) The reaction indicated above is thermodynamically spontaneous at 298 K, but becomes non-spontaneous at higher temperatures. Which of the following is true at 298 K? G, H, and S are all positive G, H, and S are all negative G and H are negative, but S is positive G and S are negative, but H is positive G and H are positive, but S is negative C2H4(g) + 3O2(g) ( 2CO2(g) + 2H2O(g) For the reaction of ethylene represented above, H is -1,323 kJ. What is the value of H if the combustion produced liquid water H2O(l), rather than water vapor H2O(g)? (H for the phase change H2O(g) ( H2O(l) is -44 kJ/mol) -1,234 kJ -1,279 kJ -1,323 kJ -1,367 kJ -1,411 kJ For a given reaction, the values for standard free energy change, G, and the equilibrium constant, Keq, are both measures of the extent to which a reaction proceeds. Which is a reasonable value for G in kJ/mol when the corresponding value for Keq = 6.9 x 105 at 298 K? -100 -30 0 +30 +100 The heat of neutralization for a strong acid in dilute water solution is about 60 kJ/mol. What quantity of heat in kJ is produced when 100 mL of 1.0 M H2SO4 is mixed with 100 mL of 1.0 M KOH? 0.10 0.30 0.40 6.0 18 Thermochemistry E C D D D D C E B D Chapter 7 ( Do 1 and 3, 2 and 4 OPTIONAL) Periodic Law Worksheet 1 1. Which of the following atoms would have the highest electron affinity? (A) Ge (B) As (C) Se (D) Sn (E) Sb 2. What is the correct set of quantum numbers for the highest energy electron of yttrium, 39Y? (A) 4, 1, 0, 1/2 (B) 4, 2, -1, 1/2 (C) 4,0,0,-1/2 (D) 3, 2, -2, 1/2 3. Which series is ranked in order of increasing electronegativity? (A) O, S, Se, Te (B) Cl, S, P, Si (C) In, Sn, N, O (D) C, Si, P, Se 4. Given the following: A: Ionization energy B: Electron affinity C: Atomic radius In general, as one moves across a row of the periodic table from the alkali metals to the halogens: (A) A, B, and C will decrease. (B) A, B, and C will increase. (C) A will increase, B and C will decrease. (D) A and B will increase, C will decrease. (E) A will decrease, B and C will increase. 5. In any one period of the periodic table, the element in Group I, as compared to the element in Group VII, has a (A) larger number of valence electrons. (B) lower electron affinity. (C) smaller radius. (D) higher ionization energy. (E) none of the above. 6. Which of the following would have the largest second ionization energy? (A) K (B) Ne (C) Cl (D) Na 7. Which of the following would have the greatest shielding effect? (A) Ba (B) Ca (C) Xe (D) Rb 8. Which series is ranked in order of increasing electronegativity? (A) N, P, As, Sb (B) F, O, N, C (C) I, Br, Cl, F (D) Ga, Si, P, Se 9. Which species is paramagnetic? (A) Cu+ (B) Zn2+ (C) Sn2+ (D) Cr3+ 10. Which gaseous atom has the highest 2nd ionization energy? (A) C (B) Li (C) F (D) Ne 11. Which of the following atoms would have the highest electron affinity? (A) Si (B) P (C) S (D) Ge (E) As 12. Nitrogen has a higher first ionization energy than oxygen. This is principally the result of (A) a nuclear charge effect. (B) greater penetration of the nitrogen p orbitals. (C) a crowding effect of the electrons. (D) the extra neutrons of oxygen. (E) the half-filled subshell of nitrogen. 13. Which of the following sets of quantum numbers represents the highest energy state? (A) 5, 1, 1, -1/ 2 (B) 5, 2, 0, +1/2 (C) 4, 2, -1, +1/2 (D) 6, 0, 0, -1/2 (E) 5, 2, 1, -1/2 14. Which of the following ions is largest in size? (A) O2- (B) Al3+ (C) Na+ (D) F- (E) Mg2+ 15. Which of the following is least metallic? (A) I (B) O (C) Cs (D) K (E) Te Periodic Law Worksheet 2 1. Arrange the following atoms or ions in order of increasing size: (A) Br- , Ca2+ , K+ , Se2- (B) Al3+ , F- , Na+ , Mg2+ , O2- (C) As3- , Ca2+ , Cl- , K+ 2. The following figure shows electron affinity values for the first 20 elements. (A) Define the term electron affinity. Electron affinity can sometimes have negative values. Explain this. (B) Explain why beryllium (A.N.= 4) has a higher value than lithium (A.N.= 3). (C) Explain why chlorine (A.N.= 17) has a lower value than sulfur (A.N.= 16). (D) Explain why phosphorous (A.N.= 15) has a higher value than silicon (A.N.= 14).  Electron Affinity 300  (kJ/ mol)  200 100   0   -100   -200  -300  2 4 6 8 10 12 14 16 18 20 Atomic Number 3. Which element in the following pairs of elements has the larger atomic (or ionic) radius? Reinforce your answer with a sentence or two. (A) Kr or Br (B) Rb or Br (C) Na+ or F 4. Which element in the following pairs has the higher first ionization energy? Reinforce your answer with a sentence or two. (A) F or O (B) Al or Mg (C) Zn or Ga (D) Xe or Kr 5. Atomic radius generally increases as we go down a group in the periodic table. (A) Explain why. (B) Explain the inconsistency of the atomic radius of hafnium: Atomic radii in Sc 1.57 Ti 1.477 Y 1.693 Zr 1.593 La 1.915 Hf 1.476 Periodic Law Worksheet 3 1. The elements in which of the following have most nearly the same atomic radius? (A) Be, B, C, N (B) Ne, Ar, Kr, Xe (C) Mg, Ca, Sr, Ba (D) C, P, Se, I (E) Cr, Mn, Fe, Co 2. In the periodic chart, where would you look for the most electronegative elements? (A) upper left side (B) lower left side (C) upper right side (D) lower right side (E) the bottom period 3. Atoms generally become smaller with increasing atomic number within a period because (A) of additional electron repulsion. (B) of increased effective nuclear charge. (C) smaller electrons are used later in a period. (D) the nucleus absorbs some of the electrons. (E) of the additional neutrons required for nuclear stability. 4. What is the correct order of increasing first ionization energies for the elements Be, B, and C? (A) Be>B>C (B) B>Be>C (C) B>C>Be (D) C>Be>B (E) Be>C>B 5. In the upper right hand corner of the periodic table are found elements which (A) have low ionization energies. (B) form acidic oxides. (C) form simple ions with positive oxidation states. (D) tend to form ionic bonds with other elements near them. (E) have high boiling points. 6. Which of the following elements would have the smallest first ionization energy? (A) Mg (B) F (C) O (D) Ca (E) Si 7. Which of the following electronic configurations would represent an atom with the smallest electron affinity (negative energy)? (A) ns2 np1 (B) ns2 np2 (C) ns2 (D) ns2 np4 (E) ns2 np5 8. In general, which of the following statements about metals are true? (A) They have large atomic radii. (B) They have large ionization energies. (C) They have large electron affinities. (D) They are found on the left and toward the bottom of the periodic table. 9. Assume that an element has the following ionization energies: 1st IE = 600 kJ/mol 2nd IE = 1,800 kJ/mol 3rd IE = 2,750 kJ/mol 4th IE = 11,600 kJ/mol 5th IE = 15,000 kJ/mol Which of the following is the most probable electron configuration for this element? (A) 1s2 2s2 2p6 (B) 1s2 2s2 2p6 3s2 (C) 1s2 2s2 2p6 3s1 (D) 1s 2 2s 2 2p 6 3s 2 3p 1 (E) 1s 2 2s 2 2p 6 3s 2 3p 3 10. Which chemical species is the smallest in size? (A) Cl (B) Cl- (C) Cl2- (D) Cl3- 11. Of the alkali metals, which group member would you expect to have the highest first ionization energy? (A) Li (B) Na (C) K (D) Rb 12. Out of the halogens, which group member has highest electron affinity? (A) F (B) Cl (C) Br (D) I (E) At Periodic Law Worksheet 4 1. In row 3 of the Periodic Table which element has the lowest first ionization energy? 2. In row 3 of the Periodic Table, which element has the highest first ionization energy? 3. Of all the elements, which one has the highest first ionization energy? 4. What is the element that has the lowest first ionization energy? 5. What is the element with the greatest electronegativity? 6. In row 2, which element has the smallest atomic radius? 7. Which element has the valence configuration 6s2 6p2 ? 8. Which element has the valence configuration 5s2 5p3 ? 9. In Group IA, which element would have the greatest shielding effect? 10. In the halogen family, which element has the largest atomic radius? 11. Given the valence electron configuration of elements a, b, c, and d : a. 4s1 b. 5s1 c. 5s2 d. 5s2 5p3 which element has the lowest first ionization energy? 12. Write the valence electron configuration for Zirconium, atomic number 40. 13. What element in row 3 is classified as a metalloid? 14. The element with the atomic number 118, if discovered, will be in what family? 15. What family of elements consists of soft metals of low melting point, all of which react vigorously with water at room temperature? 16. Which element in Group IVA has the lowest first ionization energy? 17. Predict the formula of a compound containing (A) Ga and O (B) Sc and Cl (C) Ra and O 18. Use the Periodic Table to compare the elements O, F, and Na with respect to (A) Atomic radius (B) Ionization energy 19. The electron affinities of F and of the O- ion are given below: F (g) + e- ( F- (g) H = -332 kJ/mol O- (g) + e- ( O2- (g) H = +710 kJ/mol What is the essential difference in these two processes, and how does it account for the difference in the two energy changes? 20. Explain, in terms of electron configurations, orbital diagrams, or shielding why (A) the atomic radius of sodium is smaller than that of potassium. (B) bromine and iodine have similar chemical properties . (C) sulfur atoms are paramagnetic. 21. Explain, in terms of electron configurations, orbital diagrams, or shielding why (A) in the Periodic table hydrogen can be placed in either Group 1 or 7. (B) the ionization energy Ca+ is greater than that of K even though they both have 19 electrons. (C) Na has a relatively simple atomic spectrum while Cr has a very complex one. Periodic Law Answer Key WORKSHEET 1 1)C 2)B 3)C 4)D 5)B 6)D 7)C 8)C 9)D 10)B 11)C 12)E 13)D 14)A 15)B WORKSHEET 2 1a) Ca2+ < K + < Br- < Se2- 1b) Al3+ < Mg2+ < Na+ < F- < O2- 1c) Ca2+ < K+ < Cl- < As3- 2a) The energy change when an electron is accepted by an atom in the gaseous state. EA are negative when the process is exothermic (i.e. favorable). 2b) Be has a closed 2s 2 shell. 2c) Cl only needs 1 e- to give a closed shell noble gas configuration. 2d) P has a more stable half-filled 3p shell. 3a) K < Br shielding, 3b) Br < Rb increasing shell, 3c) Na+ < F- losing vs. gaining electrons 4a) O < F; F is more electronegative, has a higher electron affinity and the effective nuclear charge is greater for F. 4b) Al < Mg; Mg has a more stable closed shell configuration (3s2 ). 4c) Ga < Zn Zn has a closed 3d10 shell. 4d) Xe < Kr atomic size, Kr is smaller and thus holds its e - more tightly (k/r2 attraction law). 5a) Atomic radii increase as one goes down a group because additional shells of e - 's are added. 5b) Hf has a 4f orbital which is not very effective in shielding the outer electrons from the nuclear charge. This gives Hf a smaller atomic radius. This is referred to as the "lanthanide contradiction." WORKSHEET 3 1)E 2)C 3)B 4)D 5)B 6)D 7)C 8)D 9)D 10)A 11)A 12)A WORKSHEET 4 1)Na 2)Ar 3)He 4)Cs 5)F 6)Ne 7)Pb 8)Sb 9)Fr 10)At 11)B 12) 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d2 13) Al or Si 14) VIII (Noble gases). 15) IA (Alkali metals). 16) At 17a) Ga2O3 b) ScCl c) RaO 18a) F < O < Na b) Na < O < F Chapter 8 Chemical Bonding Bonding (Credit: HYPERLINK "http://misterguch.brinkster.net/practicefinal.pdf"http://misterguch.brinkster.net/practicefinal.pdf, AP Workbook, HYPERLINK "http://danreid.wikispaces.com/AP+Chemistry+Exam+Multiple+Choice+Questions+Separated+by+Topic"http://danreid.wikispaces.com/AP+Chemistry+Exam+Multiple+Choice+Questions+Separated+by+Topic) 1. Which pair of atoms would most likely form an ionic compound when bonded to each other? a) calcium and fluorine b) silicon and nitrogen c) two oxygen atoms d) none of the above would probably form an ionic compound 2. Which of the following molecules is predicted to have the greatest molecular dipole moment? a. CO2 b. HBr c. HCl d. HI e. O2 3. All species below have Lewis dot diagrams that illustrate the octet rule EXCEPT a. NO3- b. NH3 c. NH4+ d. N2 e. NO2 4. Which substance has the greatest ionic character? a. Cl2O b. NCl3 c. PbCl2 d. MgCl2 e. Ch2Cl2 5. Which pair of characteristics is most closely associated with metallic solids? Low melting point High malleability Low thermal conductivity High electrical conductivity a. I and II b. I and III c. II and III d. II and IV e. III and IV 6. Which correctly compares single bonds with equal sharing of electrons to signle bonds with unequal sharing of electrons? Bonds with equal sharing are weaker Bonds with equal sharing have smaller bond energy Bonds with equal sharing are associated with smaller Electronegativity difference between atoms a. I only b. III only c. I and II only d. I and III only e. I, II, and III 7. For which of the following molecules are resonance structures necessary to describe the bonding satisfactorily? a. H2S b. SO2 c. CO2 d. OF2 e.PF3 8. The liquefied hydrogen halides have the normal boiling points given above. The relatively high boiling point of HF can be correctly explained by which of the following? Hydrogen HalideNormal Boiling Point, CHF19HCl"85HBr"67HI"35 a. HF gas is more ideal b. HF is the strongest acid c. HF molecules have a smaller dipole moment d. HF is much less soluble in water e. HF molecules tend to form hydrogen bonds 9. This is used to explain the fact that the four bonds in methane are equivalent. a. Hydrogen Bonding b. Hybridization c. Ionic Bonding d. Resonance e. van der waals forces (London dispersion forces) 10. Which of the following compounds is ionic and contains both sigma and pi covalent bonds? a. Fe(OH)3 b. HClO c. H2S d. NO2 e. NaCN Chemical Bonding A C E D D E B E B E Chapter 9 VSEPR VSEPR Bonding (Credit: HYPERLINK "http://www.education.com/study-help/article/bonding-review-questionsanswers-explanations/"http://www.education.com/study-help/article/bonding-review-questionsanswers-explanations/) 1. The shortest bond would be present in which of he following substances? a. I2 b. CO c. CCl4 d. O22 e. SCl2 2. Which of the following is polar? SF4 XeF4 CF4 SbF5 BF3 3. What is the expected hybridization of the central atom in a molecule of TiCl4? sp3d2 sp3d sp sp2 sp3 4. The species in the following set do not include which of the following geometries? SiCl4, BrF4, C2H2, TeF6, NO3 square planar tetrahedral octahedral trigonal pyramidal linear 5. The only substance listed below that contains ionic, , and  bonds is: Na2CO3 HClO2 H2O CO2 NaCl 6. Regular tetrahedral molecules or ions include which of the following? CH4 SF4 NH4+ a. I, II, and III b. I and III only c. I only d. I and II only e. II only 7. What types of hybridization of carbon are in the compound 1,4-butadiene, CH2CHCHCH2? sp3 sp2 sp a. I and II b. I, II, and III c. I and III d. I only e. II only 8. Which of the following molecules is the least polar? PH3 CH4 H2O NO2 HCl 9. Which of the following does not have one or more  bonds? H2O HNO3 O2 N2 NO2 10. Which of the following has more than one unshared pair of valence electrons on the central atom? BrF5 NF3 IF7 ClF3 CF4 VSEPR Bonding: B A E D A B E B A D Chapter 10 Gases Gas Laws (Credit: HYPERLINK "http://www.bluedevilchem.com/apchem/apch10/unitD-docs/files/practest-D1.pdf"http://www.bluedevilchem.com/apchem/apch10/unitD-docs/files/practest-D1.pdf) 1. Two flexible containers for gases are at the same temperature and pressure. One holds 14 g of nitrogen and the other holds 22 g of carbon dioxide. Which of the following statements about these gas samples is true? a. The volume of the carbon dioxide container is the same as the volume of the nitrogen container. b. The number of molecules in the carbon dioxide container is greater than the number of molecules in the nitrogen container. c. The density of the carbon dioxide sample is the same as that of the nitrogen sample. d. The average kinetic energy of the carbon dioxide molecules is greater than the average kinetic energy of the nitrogen molecules. e. The average speed of the carbon dioxide molecules is greater than the average speed of the nitrogen molecules. 2. A sample of 0.010 mole of nitrogen dioxide gas is confined at 127C and 2.5 atmospheres. What would be the pressure of this sample at 27C and the same volume a. 0.033 atm b. 0.33 atm c. 0.53 atm d. 1.25 atm e. 1.88 atm 3. Equal numbers of moles of CO2(g), N2(g), and NH3(g) are placed in a sealed vessel at room temperature. If the vessel has a pinhole-size leak, which of the following will be true after some of the gas mixture has effused? I. The mole fraction of CO2 in the sample will increase. II. The N2 will effuse the fastest since it is the lightest. III. All gases will effuse at the same rate since the temperature is held constant. a. I only b. III only c. I and II d. II and III e. I, II, and III 4. The ratio of the average velocities of SO2(g) to CH4(g) at 300 K is a. 1:4 b. 1:2 c. 4:1 d. 2:1 e. 8:1 5. A sealed flask at 20C contains 1 molecule of carbon dioxide, CO2 for every 3 atoms of helium, He. If the total pressure is 800 mmHg, the partial pressure of helium is a. 200 mmHg b. 300 mmHg c. 400 mmHg d. 600 mmHg e. 800 mmHg 6. If 2.0 moles of gas in a sealed glass flask is heated from 25C to 50C. Select the conditions that are true [kinetic energy, pressure, number of moles]. a. increases, increases, stays the same b. stays the same, increases, stays the same c. decreases, increases, stays the same d. increases, increases, increases e. stays the same, increases, increases 7. A gas sample contains 0.1 mole of oxygen and 0.4 mole of nitrogen. If the sample is at standard temperature and pressure, what is the partial pressure due to nitrogen? a. 0.1 atm b. 0.2 atm c. 0.5 atm d. 0.8 atm e. 1.0 atm 8. Consider the combustion of 6.0 g of ethane. What volume of carbon dioxide will be formed at STP? a. 0.20 L b. 0.40 L c. 2.2 L d. 9.0 L e. 22.4 L 9. A ballon occupies a volume of 1.0 liter when it contains 0.16 g of helium at 37C and 1 atm pressure. If helium is added to the balloon until it contains 0.80 grams while pressure and temperature are kept constant, what will be the new volume of the balloon? a. 0.50 liter b. 1.0 liter c. 2.0 liters d. 4.0 liters e. 5.0 liters 10. Which of the following assumption(s) is (are) valid based on kinetic molecular theory. I. Gas molecules have negligible volume. II. Gas molecules have no attractive forces on each other. III. The temperature of a gas is directly proportional to its kinetic energy. a. I only b. III only c. I and III only d. II and III only e. I, II, and III Gases: A E A B D A D D E E Chapter 11 IMFs ( Do WS 1 and 3, 2 OPTIONAL) Intermolecular Forces Worksheet 1 1. In which of the following processes are covalent bonds broken? (A) melting benzene (B) melting quartz (C) boiling C2H5OH (D) evaporating water (E) dissolving bromine in water 2. Which of the following is insoluble in water? (A) KI (B) CO2 (C) NaBr (D) CHCl3 (E) Mg(OH)2 3. Which of these solids is the best conductor of electricity? (A) tungsten (B) carbon dioxide, dry ice (C) sodium chloride (D) ice (E) quartz 4. Which of the following will be highest melting? (A) naphthalene, C8H10 (B) methane CH4 (C) Hg (D) SiO2 (E) C2H5OH 5. Which of the following is an example of a substance held together by dispersion forces that melts far below room temperature? (A) sodium (B) germanium (C) neon (D) calcium chloride (E) water 6. Which of the following will be most soluble in water? (A) C8H10 (B) Br2 (C) NaI (D) SiC (E) Cr 7. Which of the following choices is an example of a high melting, network solid consisting of covalently bonded atoms? (A) sodium (B) germanium (C) neon (D) calcium chloride (E) water 8. Which of the following would have the lowest melting point? (A) iron (B) BaCl2 (C) Cl2 (D) water (E) I2 9. Which of the following molecules is not capable of hydrogen bonding? (A) H2NCN (B) H2O2 (C) H2F+ (D) HCN (E) [NH3F]+ 10. A student is given a sample of a solid to test in the lab. He tests solubility of the sample in H2O and then in CCl4. Both tests are negative. He then tests the volatility of the sample and discovers it to be very volatile. The solid vaporizes as soon as it touches the hot spatula. What can the student conclude? (A) The sample must be metallic. (B) The sample is a covalent network solid. (C) The sample is a molecular compound. (D) The sample is ionic. (E) None of the above. The results of the tests are contradictory. 11. Which of these solvents will dissolve salt, NaCl? (A) carbon tetrachloride (B) acetone, (CH3)2CO (C) benzene, C6H6 (D) carbon disulfide, CS2 (E) bromine 12. Which of these tests would best distinguish between sodium chloride and diamond dust, both of which are finely divided clear crystals? (A) volatility-NaCl is volatile while diamond is not. (B) solubility in benzeneNaCl will dissolve in a nonpolar solvent. (C) conductivityNaCl is ionic and will conduct electricity in the solid form. (D) solubility in wateronly NaCl will dissolve. (E) heat samplesNaCl will decompose. Intermolecular Forces Worksheet 2 1. Which of the following will have the highest melting point? (A) benzene, C6H6 (B) CF4 (C) Hg (D) silicon (E) C2H5OH 2. Which of the following substances melts far below room temperature and is held together by dispersion forces? (A) potassium (B) quartz (C) magnesium oxide (D) argon (E) water 3. Which of the following would be lowest melting? (A) gold (B) BaO (C) Br2 (D) ice (E) I2 4. Which of the following is a polar molecular compound? (A) CH4 (B) SO2 (C) SiO2 (D) hydrogen (E) BH3 5. Which of the following processes would require the most energy? (A) melting iodine (B) boiling SiH4 (C) dissolving Br2 in CCl4 (D) vaporizing H2O2 (E) melting KMnO4 6. Out of the following molecules, which would you expect to have the largest lattice energy: (A) NaCl (B) KCl (C) RbCl (D) KBr (E) CaO 7. Salts dissolve in water to give solutions that boil at a higher temperature than pure water. Alcohol dissolves in water to give a solutions that boil at a lower temperatures than pure water. Explain these facts in terms of vapor pressure and intermolecular forces. 8. The normal freezing and boiling points of oxygen are 54.75 K and 90.19 K, respectively. The triple point is at 54.3 K. (A) Use these data to draw a phase diagram for oxygen. Label the axes and label the regions in which the solid , liquid, and gas phases are stable. On the phase diagram, show the position of the normal boiling point. (B) What changes will be observed in a sample of oxygen when the temperature is increased from 40 K to 150 K at a constant pressure of 1.00 atm. Intermolecular Forces Worksheet 3 1. Select the highest boiling member of each pair and indicate which intermolecular forces are involved. (A) K2CrO4 or HNO3 (B) NH3 or CH4 (C) H2O2 or H2S (D) PH3 or SbH3 2. Indicate the strongest attractive forces that must be overcome to (A) Vaporize Hg (B) Melt NaNO3 (C) Boil C3H7OH (D) Dissolve (CH3)2CO in H2O 3. State TRUE or FALSE accordingly and provide an explanation if false. (A) KBr is higher melting than IF. (B) C2H5OH is higher boiling than C2H5Cl. (C) Dry Ice (solid CO2) melts readily at room temperature. (D) Iodine is more volatile than bromine. 4. A 10.0 g sample of napthalene (C10H8 ) is added to 50.0 ml of benzene (C6H6 ) of density 0.879 g/ml. What is the boiling point of the solution? (Kb for benzene = 2.53 C/m and the normal boiling point of benzene is 80C) 5. Use the principles of intermolecular forces and/or chemical bonding to explain each of the following. (A) Neon has a lower boiling point than krypton. (B) Solid silver chloride is not a good conductor of electricity though solid silver metal is an excellent conductor of electricity. (C) At room temperature silicon dioxide, SiO2 , is a solid. If you move up in group IV to carbon and look at the analogous molecule, carbon dioxide, CO2 , you will see that it is a gas at room temperature. Explain how oxides of members of the same family can have widely varying physical properties. (D) Molecules of BF3 are nonpolar while PF3 is polar. 6. Within the group I metals, the boiling points decrease from Lithium to Cesium. In contrast, the boiling points of the halogens increase as you go down the family. (A) Account for the decrease in the boiling points of the group I metals in terms of bonding principles. (B) Account for the increase in the boiling points of the halogens in terms of bonding principles. (C) What trend is expected in the boiling points of the compounds LiF, NaCl, KBr and CsI? Use bonding principles to explain. Intermolecular Forces Answer Key WORKSHEET 1: 1) B 2) E 3) A 4) D 5) C 6) C 7) B 8) C 9) E 10) E 11) B 12) D WORKSHEET 2: 1) D 2) D 3) C 4) B 5) E 6) E 7) Salt lowers the vapor pressure of water because it has strong polar interactions with water. Alcohol is miscible in water, but interferes with water's ability to bond with itself, thus raising the vapor pressure. 8)Phase diagram for O2 9) Begins as a solid, becomes a liquid at 54.75 K, remains a liquid until 90.19 K at which point it becomes a gas. It's still a gas at 150 K. WORKSHEET 3: 1a) K2CrO4 ionic, b) NH3 H-bonding, c) H2O 2 H-bonding, d) SbH3 dispersion 2a) Hg is a metal so there are a lot of free electrons being exchanged between individual atoms. At room temperature it is a liquid so the typical metallic forces are not strong enough to bind it together a regular lattice. If we think about the liquid Hg in terms of simple kinetic theory, an atoms ability to reach an escape velocity via thermal energy will determine how easily it vaporizes. The electrostatic interactions between the atoms decrease their ability to reach the escape velocity. (This explanation could be nonsense but is was the best one we could think of given the fact that Hg has high surface tension and high vapor pressure). b) The molecule dissociates into the ions and you have to overcome the ionic bond of the molecule. c) The -OH group gives the molecule polarity and thus you have to overcome dipole interactions that occur at the vapor-liquid interface. d) There isn't a strong dipole on acetone so the polar properties of water make it(water) more likely to want to be surrounded by other water molecules. You'd have to overcome the hydrogen-bonding properties of water to get acetone to dissolve in it. 3a) True, b) True, c) False: dry-ice sublimes at room temperature, d) False, since Iodine is more massive that Bromine it has greater inertia and a harder time reaching a terminal velocity (assuming that the electrostatic interaction for the elements is about the same). 4)--- 5) a) Ne and Kr are both held together by dispersion forces. But since Ne is smaller than Kr, it has weaker dispersion forces and thus boils at a lower temperature. b) Solid silver chloride has ionic bonds; since silver metal has metallic bonds. With ionic bonding, electrons are very localized whereas with metallic bonding the electrons are free to move throughout the lattice. c)--- d) BF3 is trigonal planar and thus the charge separation is symmetric. The molecule is non-polar. PH3 is trigonal pyramidal and thus the charge separation is asymmetric. The molecule is polar. Chapter 13 Solutions Worksheet 1. As the temperature of water increases, the rate at which most solids dissolve in water: (A) Increases (B) Decreases (C) Remains the same (D) May either increase or decrease 2. When a nonvolatile solute is dissolved in water to form a solution, the vapor pressure of the solution (compared to pure water): (A) Increases (B) Decreases (C) Remains the same (D) May either increase or decrease 3. Which of the following is most soluble in water? (A) SiO2 (B) CH3-O-CH3 (C) CaCO3 (D) NaCH3CO2 (E) CO2 4. Which of the following will have the lowest freezing point? (A) 0.15 M glucose (B) 0.30 M sucrose (C) 0.15 M NaCl (D) 0.30 M CH3COOH 5. Which of the following will have the highest boiling point? (A) 0.25 M NaCl (B) 0.50 M glucose (C) 0.25 M NaCH3CO2 (D) 0.50 M MgBr2 (E) 0.10 M CaCl2 Short Answer 6. Explain why the concentration of solutions used for intravenous feeding must be controlled carefully. 7. Explain why, when making fudge (a supersaturated mixture), care must be taken to prevent it from getting "grainy." 8. Explain why fish in a lake seek deep, shaded places during summer afternoons. 9. Explain what causes the "bends" in divers. 10. Explain why champagne fizzes when poured into a glass. Solutions Answer Key WORKSHEET 1) A 2) B 3) D 4) D 5) D 6) If a concentration that is too high is used, water from body tissues would pass into the veins to dilute the feeding solution, dehydrating the body and causing the blood pressure to rise dramatically. 7) Supersaturated solutions are unstable; under proper conditions, the solute (sugar) will crystallize from the solution to give a saturated solution. Thus care must be taken to prevent the supersaturated fudge mixture from crystallizing out the sugar, making grainy fudge (a saturated mixture). 8) Solubility of oxygen in water decreases with increasing water temperature. Thus fish seek cool water so that they can breath more oxygenated water. 9) The solubility of N2 in blood (water) increases with increasing pressure. When a diver is in deep water, they are under tremendous hydrostatic pressure. In order to not be crushed, the insides of the diver must be at the same pressure as the outside. Thus divers breath pressurized gas. If a diver rises to the surface too quickly, the N2 that dissolved in the blood stream at high pressures will not have a chance to escape; bubbles of N2 form in the veins. 10) The fizzing is due to the escaping CO2. Inside the sealed bottle, the solubility of CO2 in champagne was increased by the very large over-pressure of CO2. At atmospheric pressure, CO2 has a much lower solubility in champagne. It begins to leave the champagne (as bubbles) as soon as the pressure over the liquid decreases. Chapter 14 Kinetics Kinetics (credit: HYPERLINK "http://ap.kmacgill.com/wp%20content/uploads/2013/01/ch_12_prac_test_kinetics1.pdf"http://ap.kmacgill.com/wp content/uploads/2013/01/ch_12_prac_test_kinetics1.pdf) 1. A burning splint will burn more vigorously in pure oxygen than in air because nitrogen is a reactant in combustion and its low concentration in pure oxygen catalyzes the combustion. oxygen is a reactant in combustion and the concentration of oxygen is higher in pure oxygen than it is in air. oxygen is a product of combustion. nitrogen is a product of combustion and the system reaches equilibrium at a lower temperature. oxygen is a catalyst for combustion. 2. Of the following, all are valid units for a reaction rate except __________. a. mol/L b. M/s c. mol/hr d. mol/L-hr e. g/s 3. If the rate law for the reaction 2A + 3B products is first order in A and second order in B, then the rate law is rate = __________. a. k[A]2[B]3 b. k[A]2[B]2 c. k[A][B] d. k[A]2[B] e. k[A][B]2 The kinetics of the reaction below were studied and it was determined that the reaction rate increased by a factor of 9 when the concentration of B was tripled. The reaction is __________ order in B. A + B P zero first second third one-half The rate law for a reaction is rate = k [A][B]2 Which one of the following statements is false? a. If [B] is doubled, the reaction rate will increase by a factor of 4. b. The reaction is second order in B. c. The reaction is first order in A. d. k is the reaction rate constant e. The reaction is second order overall. 6. The half-life of a first-order reaction __________. a. is constant b. is the time necessary for the reactant concentration to drop to half its original value c. can be calculated from the reaction rate constant d. does not depend on the initial reactant concentration e. All of the above are correct. The reaction CH3-NC CH3-CN is a first-order reaction. At 230.3eC, k = 6.29 x 10-4 s-1. If [CH3-NC] is 1.00 x 10-3 initially, [CH3-NC] is __________ after 1.000 x 103 s. a. 4.27 x 10-3 b. 2.34 x 10-4 c. 5.33 x 10-4 d. 1.88 x 10-3 e. 1.00 x 10-6 8. A first-order reaction has a rate constant of 0.33 min-1. It takes __________ min for the reactant concentration to decrease from 0.13 M to 0.088 M. a. 1.2 b. 1.4 c. 0.13 d. 0.85 e. 0.51 9. The rate constant for a second-order reaction is 0.13 M-1s-1. If the initial concentration of reactant is 0.26 mol/L, it takes __________ s for the concentration to decrease to 0.13 mol/L. a. 1.0 b. 4.4 x 10-3 c. 0.017 d. 0.50 e. 30 10. The rate constant of a first-order process that has a half-life of 225 s is __________ s-1. a. 3.08 x 10-3 b. 12.5 c. 1.25 d. 4.44 x 10-3 e. 0.693 Kinetics B A E C E E C A E A Chapter 15 and 17 (Do WS 1 and 4, 2 and 3 OPTIONAL) Solubility, Ksp Worksheet 1 1. How many milliliters of 0.20 M AlCl3 solution would be necessary to precipitate all of the Ag+ from 45ml of a 0.20 M AgNO3 solution? AlCl3(aq) + 3AgNO3(aq) ( Al(NO3)3(aq) + 3AgCl(s) (A) 15 ml (B) 30 ml (C) 45 ml (D) 60 ml 2. Which of the following salts has the greatest molar solubility in pure water? (A) CaCO3 ( Ksp = 8.7 x 10-9) (B) CuS (Ksp = 8.5 x 10-45) (C) Ag2CO3 ( Ksp = 6.2 x 10-12) (D) Pb(IO3)2 ( Ksp = 2.6 x 10-13) 3. The solubility product of CaF2 is 4.3 x 10-11. What is the molar solubility of CaF2 in a 0.050 M solution of Ca(NO3)2? (A) 2.2 x 10-4 M (B) 1.0 x 10-5 M (C) 1.5 x 10-5 M (D) 8.4 x 10-10 M 4. Silver oxalate Ag2(C2O4) is dissolved in pure water. The concentration of Ag+ ion in a saturated solution is 2.2 x 10-4 M. What is the Ksp of Ag2(C2O4)? (A) 5.3 x 10-12 (B) 1.1 x 101 (C) 5.0 x 10-8 (D) 2.4 x 10-8 (E) 2.2 x 10-4 5. What weight of silver chromate (Ag2CrO4) will dissolve in 1.0 liter of a solution that is 0.010 M in Ag+? Ksp Ag2CrO4 = 1.9 x 10-12 MW Ag2CrO4 = 332 g/mol. (A) 1.9 x 10-12 g (B) 1.9 x 10-8 g (C) 1.4 x 10-6 g (D) 6.3 x 10-6 g (E) 4.7 x 10-4 g 6. The solubility of CaF2 in 1 x 10-3 M KF (A) is equal to the solubility of CaF2 in pure water. (B) is less than the solubility of CaF2 in pure water. (C) is greater than the solubility of CaF2 in pure water. 7. A solution has the following concentrations: [Cl-] = 1.5 x 10-1 M [Br-] = 5.0 x 10-4 M [CrO42-] = 1.9 x 10-2 M A solution of AgNO3 (100% dissociated) is added to the above solution, drop by drop. Which silver salt will precipitate first? Ksp AgCl = 1.5 x 10-10 Ksp AgBr = 5.0 x 10-13 Ksp Ag2CrO4 = 1.9 x 10-12 (A) AgCl (B) AgBr (C) Ag2CrO4 (D) AgCl and AgBr together (E) none of the above 8. Suppose that CaF2 is to be used as a fluoridation agent in a municipal water system. What is the [F-] if extremely hard water ([Ca2+] = 0.070 M) is saturated with CaF2? (Ksp CaF2 = 1.7 x 10-10) (A) 1.3 x 10-5 M (B) 2.5 x 10-5 M (C) 5.0 x 10-5 M (D) 1.0 x 10-4 M (E) 0.070 M 9. Which of the following salts is most soluble in water? (A) Mg(OH)2 (B) CaS (C) (NH4)2CO3 (D) PbCl2 10. A 2.00 g sample of a compound requires 268.0 ml of 0.100 M AgNO3 to precipitate all of the chloride ion in the compound. What is the percent of Cl- in the compound? (AW of Cl = 35.45 g/mol) (A) 47.6% (B) 95.1% (C) 23.8 % (D) 4.75 % 11. Predict what effect each of the following has on the position of the equilibrium. PbCl2 ( Pb2+(aq) + 2Cl-(aq) H = +23.4 KJ (A) The addition of Pb(NO3)2 solution. (B) Increase the temperature. (C) The addition of Ag+. (D) The addition of HCl. 12. Which salt is the least soluble in water? (A) Hg2CrO4 (Ksp = 2.0 x 10-9) (B) BaF2 (Ksp = 1.7 x 10-6 ) (C) CaF2 (Ksp = 4.0 x 10-11) (D) AgOH (Ksp = 1.5 x 10-8) (E) BaCO3 (Ksp = 8.0 x 10-9) Solubility, Ksp Worksheet 2 1. Determine the water solubility of lead phosphate (K sp = 1 x 10-54). 2. Calculate the Ksp value for barium phosphate, Ba3(PO4)2, which has a water solubility of 6.5 x 10-7 grams per liter. 3. Calculate the solubility of manganese hydroxide, Mn(OH)2 , which has a Ksp = 4.5 x 10-14 in (A) water. (B) 0.50 M NaOH. 4. If 500.0 ml of 4.2 x 10-3 M Ce(NO3)3 is mixed with 800.0 ml of 5.6 x 10-3 M NaIO3 , will the precipitate Ce(IO3)3 (Ksp = 1.9 x 10-10) form? 5. What mass of NaOH must be added to one liter of 0.010 M Mg(NO3)2 in order to produce the first trace of Mg(OH)2 , Ksp = 1.5 x 10-11? 6. The solubility products of Fe(OH)2 and Fe(OH)3 are 10-17 and 10-38 respectively. If the concentrations of Fe2+ and Fe3+ are each 10-5, at what pH will each hydroxide just begin to precipitate? 7. A compound containing chlorine is titrated with a solution of 0.075 M Ag2SO4 . If 0.250 g of the sample requires 22.07 ml of Ag2SO4 to reach the endpoint, what is the mass percent of chlorine in the sample? 8. A solution is 0.10 M in Fe2+ and 0.10 M in Co2+ . (A) When H2S is added slowly, what precipitate first forms? (Ksp of FeS = 1 x 10-17 and Ksp of CoS = 1 x 10-20) (B) What is the concentration of the first cation when the second cation starts to precipitate? Solubility, Ksp Worksheet 3 1. The solubility of Ag2CrO4 is 4.3 x 10-5 g/L. Calculate the value of the solubility constant, Ksp. 2. A solutions is 0.01 M in KI and 0.10 M in KCl. AgNO3 is gradually added to the solution. Which will precipitate first, AgI or AgCl. (the Ksp for AgI = 1.5 x 10-16 , the Ksp for AgCl = 1.8 x 10-10) 3. If a solution contains 0.001 moles of CrO42- per liter of solution, what [Ag+] must be exceeded by adding AgNO3 to the solution before Ag2CrO4 will begin to precipitate? (Ksp for Ag2CrO4 = 9 x 10-12) 4. To a 0.10 M solution of Pb(NO3)2 is added enough HF to make [HF] = 0.10 M. (Ksp of PbF2 = 3.7 x 10-5) (A) Will PbF2 precipitate from this solution? (B) What is the minimum pH at which PbF2 will precipitate? 5. Calculate the [Tl+] when TlCl (Ksp = 1.9 x 10-4) just begins to precipitate from a solution that is 0.025 M in Cl-. 6. 50.0 ml of 0.01 M Cd(NO3)2 is added to 50.0 ml of 0.1 M H2S. Will a precipitate form? (K sp of CdS = 1 x 10-6 ). 7. Find the pH at which a solution of 0.1 M NiCl2 and 0.1 M H2S begins to precipitate NiS. (K sp of NiS = 1 x 10-21) (H2S = HS- + H+ Ka ( 1 x 10-7) (HS- ( S2- + H+ Ka = 1 x 10-13) 8. Calculate the solubility in g/L of magnesium phosphate (Ksp = 1 x 10-24) in: (A) pure water. (B) 0.01 M Mg(NO3)2 (C) 0.02 M Na3PO4 9. What is the [I-] just as AgCl begins to precipitate if 1.0 M AgNO3 is slowly added to a solution containing 0.02 M Cl- and 0.02 M I-. (Ksp for AgCl = 1.8 x 10-10 and Ksp for AgI = 1 x 10-16) Solubility, Ksp Worksheet 4 l. When excess solid SrCrO4 is shaken with water at 25oC, it is found that 6 x 10-3 mol dissolves per liter. Use this information to calculate the solubility product constant for SrCrO4. 2. The Ksp of BaF2 is 1.8 x 10-7, what is its water solubility in moles per liter. 3. Taking the Ksp of CaCO3 to be 4.9 x 10-9, estimate its solubility (moles per liter) in 0.01 M Na2CO3 solution. 4. CaF2 (Ksp = 1.5 x 10-10) is formed when solutions of Ca(NO3)2 and NaF are mixed. Will a precipitate form if 10.00 ml of 0.002 M Ca(NO3)2 is added to 25 ml of 0.0100 M NaF? 5. CrO42- is added to a solution in which the original concentration of Sr2+ is 1.0 x 10-3 . Assuming the concentration of Sr2+ stays constant, will a precipitate of SrCrO4 (Ksp = 3.6 x 10-5) form when [CrO42-] = 3.0 x 10-5 M? 6. Write balanced net ionic equations for the precipitation reactions that occur when the following solutions are mixed. If no reaction occurs, write "no reaction" (A) lead nitrate and hydrochloric acid (B) silver nitrate and lithium hydroxide (C) ammonium sulfide and cobalt (II) bromide (D) copper (II) sulfate and potassium carbonate (E) barium sulfide and copper (II) sulfate 7. A chemist analyzes an alloy for silver. A 7.56 gram sample of the alloy is first dissolved in nitric acid. This brings the silver into solution as the silver(I) ion. The solution is titrated with 39.7 ml of 0.50 M BaCl2, to completely precipitate the silver as silver chloride, AgCl. What is the mass percent of silver in the alloy? 8. Calculate the Ksp value for calcium phosphate, Ca3(PO4)2 , which has a solubility of 9.8 x 10-8 M in pure water. 9. Calculate the solubility of arsenic sulfide, As2S3, which has a Ksp = 1.0 x 10-16 (A) in pure water. (B) in 0.20 M AsNO3. 10. Lead chloride, PbCl2 , has a Ksp value of 1.7 x 10-5. Will a precipitate form when 140.0 ml of 0.010 M Pb3(PO4)2 is mixed with 550.0 ml of 0.055 M NaCl? 11. A solution contains 1.0 x 10-4 M Pb2+ and 2.0 x 10-3 M Sr2+. If a source of S042- is added to this solution, will PbSO4 (K sp = 1.8 x 10-8) or SrSO4 (Ksp = 3.4 x 10-7) precipitate first? Specify the concentration of S042- necessary to begin precipitation of each salt. Solubility, Ksp Answer Key WORKSHEET 1 1) A 2) A 3) C 4) A 5) D 6) B 7) C 8) C 9) C 10) A 11) a) drives rxn to the left b) drives rxn to the right c) drives rxn to the right d) drives rxn to the left 12) C WORKSHEET 2 1) 6.21 x 10-12 M 2) 1.6 x 10-43 liter 3) a) 2.24 x 10-5 M b) 1.8 x 10-13 M 4) No 5) 0.00155g 6) pH = 8 for Fe2+, pH = 3 for Fe3+ 7) 47.01% 8) a) CoS b) 1 x 10-4 M WORKSHEET 3 1) 8.8 x 10-21 2) AgI 3) 9.5 x 10-5 M 4) a) yes b) 1.72 5) 7.6 x 10-5 M 6) yes 7) 5.25 8) a) 1.63 x 10-3 g/L b) 3.6 x 10-3 g/L c) 1.2 x 10-8 g/L 9) {Ag+] = 9.0 x 10-9 M [I-] = 10-8 M WORKSHEET 4 1) 3.6 x 10-5 2) 3.6 x 10-3 3) 4.9 x 10-7 M 4) yes 5) No 6) --- 7)18.6 % 8) 9.76 x 10-34 M 9 a) 2.5 x 10-4 M b) 4.5 x 10-6 M 10) no 11) SrSO4 ppt first. [SO42-] = 1.8 x 10-4 M for PbSO4 [SO42-] = 1.7 x 10-4 M for SrSO4 Chapter 16: ACID BASES WORKSHEET 1. A 5.00 gram sample of a dry mixture of potassium hydroxide, potassium carbonate, and potassium chloride is reacted with 0.100 liter of 2.00 molar HCl solution (a) A 249 milliliter sample of dry CO2 gas, measured at 22C and 740 torr, is obtained from this reaction. What is the percentage of potassium carbonate in the mixture? (b) The excess HCl is found by titration to be chemically equivalent to 86.6 milliliters of 1.50 molar NaOH. Calculate the percentages of potassium hydroxide and of potassium chloride in the original mixture. 2. A sample of 40.0 milliliters of a 0.100 molar HC2H3O2 solution is titrated with a 0.150 molar NaOH solution. Ka for acetic acid = 1.8(105 (a) What volume of NaOH is used in the titration in order to reach the equivalence point? (b) What is the molar concentration of C2H3O2 at the equivalence point? (c) What is the pH of the solution at the equivalence point? 3. The value of the ionization constant, Ka, for hypochlorous acid, HOCl, is 3.1108. (a) Calculate the hydronium ion concentration of a 0.050 molar solution of HOCl. (b) Calculate the concentration of hydronium ion in a solution prepared by mixing equal volumes of 0.050 molar HOCl and 0.020 molar sodium hypochlorite, NaOCl. (c) A solution is prepared by the disproportionation reaction below. Cl2 + H2O ! HCl + HOCl Calculate the pH of the solution if enough chlorine is added to water to make the concentration of HOCl equal to 0.0040 molar. 4. Predict whether solutions of each of the following salts are acidic, basic, or neutral. Explain your prediction in each case (a) Al(NO3)3 (b) K2CO3 (c) NaBr 5. A solution of hydrochloric acid has a density of 1.15 grams per milliliter and is 30.0% by weight HCl. (a) What is the molarity of this solution of HCl? (b) What volume of this solution should be taken in order to prepare 5.0 liters of 0.20 molar hydrochloric acid by dilution with water? (c) In order to obtain a precise concentration, the 0.20 molar hydrochloric acid is standardized against pure HgO (molecular weight = 216.59) by titrating the OH produced according to the following quantitative reaction. HgO(s) + 4 I + H2O ! HgI42 + 2 OH In a typical experiment 0.7147 grams of HgO required 31.67 milliliters of the hydrochloric acid solution for titration. Based on these data what is the molarity of the HCl solution expressed to four significant figures. ACID BASE WORKSHEET ANSWERS 1. (a) K2CO3 + 2 HCl ! CO2 + 2 KCl + H2O mol CO2 =  EMBED Equation.DSMT4 =  EMBED Equation.DSMT4 = 0.0100 mol CO2 0.10 mol CO2 (  EMBED Equation.DSMT4  (  EMBED Equation.DSMT4  = 1.38 g K2CO3  EMBED Equation.DSMT4 ( 100% = 27.6% K2CO3 (b) orig. mol HCl = 0.100 L ( 2.00M = 0.200 mol reacted with K2CO3 = 0.020 mol excess HCl = 0.0866L ( 1.50M = 0.130 mol mol HCl that reacted w/KOH = 0.050 mol 0.050 mol KOH = 2.81 g = 56.1% of sample the remaining KCl amounts to 16.3% 2. 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(a) HOCl + H2O ! H3O+ + OCl 3.2(10-8 =  EMBED Equation.DSMT4  X = [H3O+] = 4.0(10 5M (b) HOCl + H2O ! H3O+ + OCl  EMBED Equation.DSMT4 = 3.2(10-8 ; X << 0.010 X = [H3O+] = 8.0(10-8M (c) Cl2 + H2O ! HCl + HOCl [HOCl] = [HCl] = 0.0040M HCl as principal source of H3O+ pH =  log[H3O+] = 2.40 4. (a) acidic; Al3+ + H2O ! AlOH2+ + H+; hydrolysis of Al3+; Al(OH2)n3+ as Brnsted acid, etc. (b) basic; CO32 + H2O ! HCO3 + OH ; or hydrolysis of CO32 as conjugate to a weak acid, etc. (c) neutral; Na+ from strong base; Br from strong acid 5. (a)  EMBED Equation.DSMT4 = 9.45 M (b) MfVf = MiVi (0.20M)(5.0L) = (9.5M)(V) V = 0.11 L (c)  EMBED Equation.DSMT4 = 0.003300 mol HgO mol OH prod. = 2 (mol HgO) = 0.006600 mol mol HCl req. = mol OH prod. = 0.006600 mol molarity HCl =  EMBED Equation.DSMT4 = 0.2084 M Chapter 20 Electrochemistry Worksheet 1 l. For the reaction: 2Fe + 3CdCl2 ( 2 FeCl3 + 3Cd, which statement is true? (A) Fe is the oxidizing agent (B) Cd undergoes oxidation (C) Cd is the reducing agent (D) Fe undergoes oxidation 2. What is the potential in volts for the spontaneous reaction between the Ag/Ag+ and Zn/Zn2+ half-cells? Zn2+ + 2e- ( Zn Eo = -0.763 V Ag+ + e- ( Ag Eo = 0.799 V (A) -2.361 V (B) -1.562 V (C) 1.562 V (D) 2.361 V 3. What is the oxidation state of arsenic in H3AsO3? (A) +1 (B) +3 (C) +5 (D) +7 4. When the reaction below is balanced, what is the coefficient of H+ ? MnO4- + NO2- + H+ ( MnO2 + NO3 + H2O (A) 2 (B) 4 (C) 6 (D) 8 5. What is the [Cu2+] in the cell Zn / Zn2+ (O.O5M) // Cu2+ (? M) / Cu if the cell voltage is 1.03V? Zn2+ + 2e- ( Zn Eo = -0.763 V Cu 2+ + 2 e - ( Cu Eo = 0.337 V (A ) 0.12 M (B) 0.0002 M (C) 0.05 M (D) 0.0035 M 6. 10 amps are passed through molten aluminum chloride for 5.5 hours. How many grams of aluminum metal could be produced by this electrolysis? (A) 18.5g (B) 55.4g (C) 91.2g (D) 273g 7. Select the set of coefficients which balances the chemical equation: B3N3H12 + O2 ( N2O5 + B2O3 + H2O (A) 1,5,1,1,2 (B) 1,15,3,3,6 (C) 2,5,3,3,3 (D) 2,15,3,3,6 8. In the electroplating of silver from cyanide solution, the cathode reaction is: Ag(CN)2+ + e- ( Ag(s) + 2CN- How many grams of silver should be deposited by a current of 4.5 A in 28.0 minutes? (A) 0.141 g (B) 4.23 g (C) 8.45 g ( D) 12.53 g 9. Given the standard electrode potentials: Cu2+ + 2e- ( Cu (s) Eo = 0.337V Al 3+ + 3e- ( Al (s) Eo = -1.66V The voltage of the cell: Cu / CuSO4 (O.5M) // Al2(SO4)3 (0.1 M) / Al would be: (A) 0.00 V (B) 0.72 V (C) 2.01 V (D) 5.70 V 10. In the reaction: SO2 + 2H2S ( 3S + 2H2O (A) S is oxidized and H is reduced. (B) S is reduced and there is no oxidation. (C) S is reduced and H is oxidized. (D) S is both reduced and oxidized. 11. Which ion can be oxidized by appropriate chemical means but also can be reduced by a different chemical reaction? (A) Fe2+ (B) F (C) CO32- (D) NO3 12.Given the standard electrode potentials: Ni2+ + 2e- ( Ni (s) Eo = -0.23 V; Cr3+ + 3e- -----> Cr (s) Eo = -0.74 Which pair of substances will react spontaneously? (A) Ni2+ with Cr3+ (B) Ni with Cr3+ (C) Ni2+ with Cr (D) Ni with Cr 13. Aluminum oxide may be electrolyzed at 1000C to furnish aluminum metal. The cathode reaction is: Al 3+ + 3e- ( Al. To prepare 5.12 kg of aluminum metal by this method would require how many coulombs of electricity? (A) 5.49 x 10 7 C (B) 1.83 x 10 7 C (C) 5.49 x 10 4 C (D) 5.49 x 10 1 C Electrochemistry Worksheet 2 1. The electrolysis of molten sodium chloride is carried out in an electrochemical cell. (A) Write the balanced half-cell reactions that occur at each electrode, indicating whether each takes place at the anode or cathode. (B) If a current of 1.06 amps is used, how long will it take to produce 1.00 L of Cl2(g) at 25oC and 742mm Hg? (C) Calculate K and Go for this system. 2. A voltaic cell is designed using the following reaction: Zn + 2Ag+ ( Zn2+ + 2Ag (A) Determine the standard voltage, Eotot , for this reaction. (B) Suppose the concentration of Zn2+ in the Zn/Zn2+ half-cell is maintained at l.00 M. Excess hydrochloric acid is added to the Ag/Ag+ half-cell, precipitating AgCl and making the concentration of Cl- = 0.100 M. Under these conditions, the cell voltage is found to be 1.04 V. Calculate the concentration of Ag+ in the Ag/Ag+ half-cell. (C) Use the information in (B) to calculate the Ksp of AgCl. 3. 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(A) Write an equation for the half-cell reaction occurring at each electrode. Indicate whether each reaction occurs at the anode or the cathode. (B) Write a net ionic equation for the overall spontaneous cell reaction that occurs when the circuit is complete. Calculate the standard voltage, Eo, for this reaction. (C) Calculate the change in voltage when the cell described above has initial concentrations of 0.500 molar Ni(NO3)2 and 0.750 molar AlCl3 . 4. Eo = 1.101 volt at 25oC. for the reaction: M(s) + Cu2+(aq) ( M2+(aq) + Cu(s) (A) Determine the standard electrode potential for the reduction half-reaction M2+(aq) + 2e- ( M(s). (B) A cell is constructed in which the reaction above occurs. All substances are initially in their standard states, and equal volumes of the solutions are used. The cell is then discharged. Calculate the value of the cell potential, E, when [Cu2+] has dropped to 0.20 molar. 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