Theoretical and Percent Yield 2015
Calculating Theoretical and Percent Yield
General Procedure 1) Balance the chemical equation 2) Convert the grams or milligrams of reactants to moles or millimoles. 3) Find the limiting reagent (the reactant that limits the reaction to produce the least amount of product) 4) Calculate the moles of product expected if the reaction goes to 100%. 5) Calculate the grams of product from the moles of product. This is the theoretical yield in grams.
6) Calculate the percent yield: % Yield = Actual yield ? 100% Theoretical Yield
Example
Br Ph Ph Br MW: 340 g/mol
+ 2 KOH MW: 56 g/mol
Ph
Ph
MW: 178 g/mol
Suppose the above reaction uses 300. mg of dibromide and 247 mg of KOH. The reaction yielded 115 mg of diphenylacetylene.
1) The equation written above is already balanced. 2) Calculate the of mmol of each reactant:
Dibromide: 300. mg ? ! !!"# = 0.882 mmol
!"# !"
Potassium Hydroxide: 247 mg ? ! !!"# = 4.41 mmol
!" !"
3) Determine the limiting reagent: Dibromide: 0.882 mmol ? ! !!"# !"#$%&' = 0.882 mmol product (limiting reagent)
! !!"# !"#$%&"!'
Potassium Hydroxide: 4.41 mmol ? ! !!"# !"#$%&' = 2.21 mmol product (excess reagent)
! !!"# !"#
4) Based on the limiting reagent calculation, if the reaction goes to 100% completion, the maximum amount of product that can be formed is 0.882 mmol.
5) Theoretical Yield: 0.882 mmol ? !"# !" = 157 mg
! !!"#
6) Percent Yield: !!" !" ? 100% = 73.2 % yield
!"# !"
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